Engineering Process of Polymer for Thermoelectric Applications

Min Wang; Xiao Zhang; Li-Yao Liu; Ye Zou; Chong-An Di

doi:10.1007/s10118-026-3622-9

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Engineering Process of Polymer for Thermoelectric Applications

REVIEW | Updated：2026-03-26

- Engineering Process of Polymer for Thermoelectric Applications
- Engineering Process of Polymer for Thermoelectric Applications
- Chinese Journal of Polymer Science 2026年44卷第4期页码：906-921
- Affiliations：
  
  a.Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  b.School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China
- Author bio：
  
  liuliyao@iccas.ac.cn (L.Y.L.)
  dicha@iccas.ac.cn (C.A.D.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China grant (Nos. 22305253, 22125504, U25A20570 and T2441002), Strategic Priority Research Program of the Chinese Academy of Sciences grant XDB0520202, and Beijing National Laboratory for Molecular Sciences (No. BNLMS-CXXM-202402).;Li-Yao Liu received her Ph.D. degree from Institute of Chemistry, Chinese Academy of Sciences (ICCAS). She joined the CAS Key Laboratory of Organic Solids, ICCAS in 2019. She mainly engaged in research on organic thermoelectric materials and devices.Chong-An Di is a professor of the Organic Solids Laboratory in ICCAS. He ﬁnished his Ph.D. study in chemistry from ICCAS in 2008 and was appointed as a professor in 2016 at ICCAS. Currently, his research focuses on the investigation of organic thin ﬁlm transistors and organic thermoelectrics.The authors declare no interest conflict.
- DOI：10.1007/s10118-026-3622-9
  中图分类号：
- 收稿：2026-01-08，
  
  录用：2026-02-11，
  
  网络首发：2026-03-10，
  
  纸质出版：2026-04-05
- Accepted：
Scan QR Code
Wang, M.; Zhang, X.; Liu, L. Y.; Zou, Y.; Di, C. A. Engineering process of polymer for thermoelectric applications. Chinese J. Polym. Sci. 2026, 44, 906–921

Min Wang, Xiao Zhang, Li-Yao Liu, et al. Engineering Process of Polymer for Thermoelectric Applications[J]. Chinese Journal of Polymer Science, 2026, 44(4): 906-921.
Wang, M.; Zhang, X.; Liu, L. Y.; Zou, Y.; Di, C. A. Engineering process of polymer for thermoelectric applications. Chinese J. Polym. Sci. 2026, 44, 906–921 DOI： 10.1007/s10118-026-3622-9.

Min Wang, Xiao Zhang, Li-Yao Liu, et al. Engineering Process of Polymer for Thermoelectric Applications[J]. Chinese Journal of Polymer Science, 2026, 44(4): 906-921. DOI： 10.1007/s10118-026-3622-9.

摘要

This review systematically summarizes the latest advances in polymer processing techniques for thermoelectric applications and explores the intrinsic relationships among the processing methods

microstructure

and thermoelectric performance. Finally

future perspectives are presented for the industrialization of high-performance organic thermoelectric devices.

Abstract

Thermoelectric (TE) materials

which are capable of direct conversion between heat and electricity

offer a promising solution for sustainable energy harvesting. Conjugated polymers have emerged as compelling candidates for flexible TE devices owing to their intrinsic flexibility

low cost

and low thermal conductivity. The performance of polymer-based organic thermoelectrics (OTEs) is profoundly influenced by the processing methods

which dictate molecular packing

crystallinity

and film morphology. This review systematically summarizes recent advances in polymer processing techniques for TE applications

including solution processing

patterning techniques

and large-area fabrication. We discuss the interrelationships among processing techniques

polymer microstructure

and TE performance

concluding with the current challenges and future perspectives for industrializing high-performance OTE devices.

关键词

Keywords

references

Shi, X. L.; Zou, J.; Chen, Z. G. Advanced thermoelectric design: from materials and structures to devices. Chem. Rev. 2020 , 120 , 7399−7515..

Ma, Z. L.; Ma, Z. Z.; Zhao, L. M.; Zhang, J. L.; Guo, P. F.; Li, Q.; Wang, H. Q. Integration and application of solar-responsive energy storage systems. Adv. Energy Mater . 2025 , 15 , e03128..

Cao, J. L.; Chen, Z. X.; Kong, S.; Liu, L.; Wang, R. X. Towards urban wind utilization: the spatial characteristics of wind energy in urban areas. J. Clean. Prod. 2024 , 450 , 141981..

Zhang, X. W.; Ji, R. W.; Sun, K.; Zhang, J. H.; Zhang, X. J.; Yin, M. W.; Kong, M.; Reabroy, R. A review of ocean tidal current energy technology: advances, trends, and challenges. Phys. Fluids. 2025 , 37 , 071308..

Ji, Z.; Li, Z. Y.; Liu, L. Y.; Zou, Y.; Di, C. A.; Zhu, D. B. Organic thermoelectric devices for energy harvesting and sensing applications. Adv. Mater. Technol. 2024 , 9 , 2302128..

Zhao, Y.; Liu, L. Y.; Zhang, F. J.; Di, C. A.; Zhu, D. B. Advances in organic thermoelectric materials and devices for smart applications. SmartMat 2021 , 2 , 426−445..

Tang, H. R.; Liang, Y. Y.; Liu, C. C.; Hu, Z. C.; Deng, Y. F.; Guo, H.; Yu, Z. D.; Song, A.; Zhao, H. Y.; Zhao, D. K.; Zhang, Y. Z.; Guo, X. G.; Pei, J.; Ma, Y. G.; Cao, Y.; Huang, F. A solution-processed n-type conducting polymer with ultrahigh conductivity. Nature 2022 , 611 , 271−277..

Wang, D. Y.; Ding, J. M.; Ma, Y. Q.; Xu, C, L.; Li, Z. Y.; Zhang, X.; Zhao, Y.; Zhao, Y.; Di, Y. Q.; Liu, L. Y.; Dai, X. J.; Zou, Y.; Kim, B. S.; Zhang, F. J.; Liu, Z. T.; Mcculloch, I.; Lee, M.; Chang, C.; Yang, X.; Wang, D.; Zhang, D. Q.; Zhao, L. D.; Di, C. A.; Zhu, D. B. Multi-heterojunctioned plastics with high thermoelectric figure of merit. Nature 2024 , 632 , 528−535..

[Zhao, Y. R.; Li, Y. M.; Yang, R. H.; Song, Z. Y.; Sun, M. Y.; Fan, N.; Zhong, W. K.; Ye, L.; Yuan, Y.; Jiao, F.; Wang, Y. X.; Hu, W. P. Environmentally stable n-type conducting polymer with high intrinsic stretchability. Adv. Mater . 2026 , DOI: 10.1002/adma.202518190..

Liu, K.; Wang, J. Y.; Pan, X. R.; Tian, S. Y.; Liu, Y. D.; Zhang, Z.; Di, Y. Q.; Chen, J. P.; Wu, C. W.; Deng, C. Y.; Wang, D. Y.; Li, P. Y.; Pan, C, K.; Qi, F. L.; Liu, J. H.; Hua, J.; Pei, J.; Di, C. A.; Guo, Y. L.; Liu, Y. Q.; Lei, T. N-type thermoelectric elastomers. Nature 2025 , 644 , 920−926..

Jo, G.; Jeong, W. J.; Choi, S.; Kim, H.; Park, J. J.; Jung, J.; Chang, M. Large-scale alignment of polymer semiconductor nanowires for efficient charge transport via controlled ev aporation of confined fluids. ACS APPL. Mater. Interfaces 2019 , 11 , 1135−1142..

Zhang, X.; Ding, J. M.; Wang, D. Y.; Dai, X. J.; Ma, Y. Q.; Zhao, Y.; Guan, B.; Liu, L. Y.; Zou, Y.; Zhang, F. J.; Di, C. A. Waterborne paints based on polymeric semiconductor for attachable thermoelectric generators. Small Struct. 2022 , 4 , 2200278..

Zhao, W. R.; Ding, J. M.; Zou, Y.; Di, C. A.; Zhu, D. B. Chemical doping of organic semiconductors for thermoelectric applications. Chem. Soc. Rev. 2020 , 49 , 7210−7228..

Song, Y. L.; Ding, J. M.; Dai, X. J.; Li, C.; Di, C. A.; Zhang, D. Q. Enhancement of the thermoelectric performance of n-type naphthalene diimide-based conjugated polymer by engineering of side alkyl chains. ACS Mater. Lett. 2022 , 4 , 7210−7228..

Ding, J. M.; Liu, Z. T.; Zhao, W. R.; Jin, W. L.; Xiang, L. Y.; Wang, Z. J.; Zeng, Y.; Zou, Y.; Zhang, F. J.; Yi, Y. P.; Diao, Y.; Mcneill, C. R.; Di, C. A.; Zhang, D. Q.; Zhu, D. B. Selenium-substituted diketopyrrolopyrrole polymer for high-performance p-type organic thermoeletric materials. Angew. Chem. Int. Ed. 2019 , 58 , 19170−19175..

Shirakawa, H.; Louis, E. J.; Macdiarmid, A. G.; Chiang, C. K.; Heeger, A. J. Synthesis of electrically conducting organic polymers: halogen derivatives of polyacetylene, (CH) x . J. C. S. Chem. Comm . 1977 , 578−580..

Reghu, M.; Cao, Y.; Moses, D.; Heeger, A. J. Counterion-induced processibility of polyaniline: transport at the metal-insulator boundary. Phys. Rev. B 1993 , 47 , 1758−1764..

Bubnova1, O.; Khan, Z. U.; Malti, A.; Braun, S.; Fahlman, M.; Berggren, M.; Crispin, X. Optimization of the thermoelectric figure of merit in the conducting polymer poly(3, 4-ethylenedioxythiophene). Nat. Mater. 2011 , 10 , 429−733..

Søndergaard, R. R.; Hösel, M.; Espinosa, N.; Jørgensen, M.; Krebs, F. C. Practical evaluation of organic polymer thermoelectrics by large-area R2R processing on flexible substrates. Energy Sci. Eng. 2013 , 1 , 81−88..

Hong, C. T.; Kang, Y. H.; Ryu, J.; Cho, S. Y.; Jang, K. S. Spray-printed CNT/P3HT organic thermoelectric films and power generators. J. Mater. Chem. A 2015 , 3 , 21428..

Sun, Y. H.; Qiu, L.; Tang, L. P.; Geng, H.; Wang, H. F.; Zhang, F. J.; Huang, D. Z.; Xu, W.; Yue, P.; Guan, Y. S.; Jiao, F.; Sun, Y. M.; Tang, D. W.; Di, D. A.; Yi, Y. P.; Zhu, D. B. Flexible n-type high-performance thermoelectric thin films of poly(nickel-ethylenetetrathiolate) prepared by an electrochemical method. Adv. Mater. 2016 , 28 , 3351−3358..

Hamidi-Sakr, A.; Biniek, L.; Bantignies, J. L.; Maurin, D.; Herrmann, L.; Leclerc, N.; Lévêque, P.; Vijayakumar, V.; Zimmermann, N.; Brinkmann, M. A versatile method to fabricate highly in-plane aligned conducting polymer films with anisotropic charge transport and thermoelectric properties: the key role of alkyl side chain layers on the doping mechanism. Adv. Funct. Mater. 2017 , 27 , 1700173..

Brus, V. V.; Gluba, M.; Rappich, J.; Lang, F.; Maryanchuk, P. D.; Nickel, N. H. Fine art of thermoelectricity. ACS Appl. Mater. Interfaces 2018 , 10 , 4737−4742..

Wang, D. Y.; Ding, J. M.; Dai, X. J.; Xiang, L. Y.; Ye, D. L.; He, Z. H.; Zhang, F. J.; Jung, S. H.; Lee, J. K.; Di, C. A.; Zhu, D. B. Triggering ZT to 0.40 by engineering orientation in one polymeric semiconductor. Adv. Mater. 2022 , 35 , 2208215..

Zhao, Y.; Li, Z. Y.; Wang, D. Y.; Zhang, X.; Ji, Z.; Niu, L. X.; Di, Y. Q.; Guan, Y.; Liu, L. Y.; Zou, Y.; Li, C.; Zhang, F. J.; Zhang, D. Q.; Zhu, D. B.; Di, C. A. High performance and colorful polymer thermoelectrics with imprinted porous film. Adv. Mater. 2024 , 36 , 2407692..

Wang, X. Y.; Ding, Y. F.; Zhang, X. Y.; Zhou, Y. Y.; Pan, C. K.; Li, Y. J.; Liu, N. F.; Yao, Z. F.; Chen, Y. S.; Xie, Z. H.; Huang, Y. F.; Xu, Y. F.; Wu, H. T.; Huang, C. X.; Xiong, M.; Ding, L.; Yu, Z. D.; Li, Q. Y.; Zheng, Y. Q.; Wang, J. Y.; Pei, J. Light-triggered regionally controlled n-doping of organic semiconductors. Nature 2025 , 642 , 599−605..

Diao, Y.; Shaw, L.; Bao, Z. N.; Mannsfeld, S. C. B. Morphology control strategies for solution-processed organic semiconductor thin films. Energy Environ. Sci. 2014 , 7 , 2145−2159..

Huq, A. F.; Ammar, A.; Al-Enizi A. M.; Karim, A. In-situ orientation and crystal growth kinetics of P3HT in drop cast P3HT: PCBM films. Polymer 2017 , 113 , 200−213..

Chen, L.; Chi, S. J.; Zhao, K. F.; Liu, J. G.; Y u, X. H.; Han, Y. C. Aligned films of the DPP-based conjugated polymer by solvent vapor enhanced drop casting. Polymer 2016 , 104 , 123−129..

Li, H.; Liang, Y.; Liu, Y. L.; Liu, S. Q.; Li, P. C.; He, C. B. Engineering doping level for enhanced thermoelectric performance of carbon nanotubes/polyaniline composites. Compos. Sci. Technol. 2021 , 210 , 108797..

Li, H.; Liu, Y. L.; Li, P. C.; Liu, S. Q.; Du, F. P.; He, C. B. Enhanced thermoelectric performance of carbon nanotubes/polyaniline composites by multiple interface engineering. ACS Appl. Mater. Interfaces 2021 , 13 , 6650−6658..

Yoo, D.; Son, W. Y.; Kim, S. Y.; Lee, J. J.; Lee, S. H.; Choi H. H.; Kim, J. H. Gradual thickness-dependent enhancement of the thermoelectric properties of PEDOT:PSS nanofilms. RSC Adv. 2014 , 4 , 58924−58929..

Zhang, F. J.; Di, C. A.; Berdunov, N.; Hu, Y. T.; Hu, Y. B.; Gao, X. K.; Meng, Q.; Sirringhaus H.; Zhu, D. B. Ultrathin film organic transistors: precise control of semiconductor thickness via spin-coating. Adv. Mater. 2012 , 25 , 1401−1407..

Feng, K.; Yang, W. L.; Jeong, S. Y.; Ma, S. X.; Li, Y. C.; Wang, J. W.; Wang, Y. M.; Woo, H. Y.; Chan, P. K. L.; Wang, G.; Guo, X. G.; Zhu, M. F. Cyano-functionalized fused bithiophene imide dimer-based n-type polymers for high-performance organic thermoelectrics. Adv. Mater. 2023 , 35 , 2408716..

Xu, J.; Wu, H. C.; Zhu, C. X.; Ehrlich, A.; Shaw, L.; Nikolka, M.; Wang, S. H.; Molina-Lopez, F.; Gu, X. D.; Luo, S. C.; Zhou, D. S.; Kim, Y. H.; Wang, G. J. N.; Gu, K.; Feig, V. R.; Chen, S. C.; Kim, Y.; Katsumata, T.; Zheng, Y. Q.; Yan, H.; Chung, J. W.; Lopez, J.; Murmann, B.; Bao, Z. N. Multi-scale ordering in highly stretchable polymer semiconducting films. Nat. Mater. 2019 , 18 , 594−601..

Yang, X. F.; Sun, M. L.; Du, L.; Wu, F. Y.; Kim, H. H.; Woo, H. Y. L; Chen, L.; Chen, Y. W. Co-solvent strategy enables high-performance printing organic thermoelectric via synergistic modulation of crystallinity and film homogeneity. Small 2025 , 21 , e10495..

Perry, S. C.; Akbar, S.; Clarke, R.; Shah, S. Z. H.; Nandhakumar, I. Electrodeposition of thermoelectric materials. Chem. Electro. Chem. 2025 , 12 , e202500052..

Teixeira, H. J.; Dias, C.; Veloso, R. C.; Apolinário A.; Ventura, J. Tuning PEDOT: PSS low-impedance thin films with high charge injection for microelectrodes applications. Prog. Org. Coat. 2022 , 168 , 106894..

Su, L. S.; Gan, Y. X. Experimental study on synthesizing TiO 2 nanotube/polyaniline (PANI) nanocomposites and their thermoelectric and photosensitive property characterization. Compos. Part B: Eng. 2012 , 43 , 170−182..

[Culebras, M.; Igual-Muñoz, A. M.; Rodríguez-Fernández, C.; Gómez-Gómez, M. I.; Gómez C.; Cantarero, A. Manufacturing Te/PEDOT films for thermoelectric applications. ACS Appl. Mater . Interfaces 2017 , 9 , 20826-20832..

Li, Y.; Chen, Z. P.; Gao, C. Y.; Li, H. P.; Fan, X. H.; Cao, X. B.; Yang, L. M. Electrochemical assembly of flexible PPy/Bi-Te alloy/PPy thermoelectric composite films with a sandwich-type structure. New J. Chem. 2024 , 48 , 1634−1641..

Liu, L. Y.; Sun, Y. H.; Li, W. B.; Zhang, J. J.; Huang, X.; Chen, Z. J.; Sun, Y. M.; Di, C. A.; Xu, W.; Zhu, D. B. Flexible unipolar thermoelectric devices based on patterned poly[K x (Ni-ethylenetetrathiolate) ] thin films. Mater. Chem. Front. 2017 , 1 , 2111−2116..

Codau, T. C.; Codau, E. Synthesis of ultra-stretchable thermoelectric nanofibrous membrane based on wet-electrospun polyurethane/MWCNTs composites. Mater. Today Sustain. 2024 , 27 , 100831..

Liu, H. R.; Liu, D.; Yang, J. C.; Gao, H. F.; Wu, Y. C. Flexible electronics based on organic semiconductors: from patterned assembly to integrated applications. Small 2023 , 19 , 2206938..

Li, Y.; Chen, R. Z. Photolithographic patterning of organic semiconductors for organic field-effect transistors. Chem. Rev. 2025 , 125 , 4933−4973..

Qiu, M. J.; Du, W. W.; Zhou, S. Y.; Cai, P. Z.; Luo, Y. W.; Wang, X. X.; Yang R.;Zhao, J. J. Recent progress in non-photolithographic patterning of polymer thin films. Prog. Polym. Sci. 2023 , 142 , 101688..

Choi, W.; Kim, Y. E.; Yoo, H. Patterning of organic semiconductors leads to functional integration: from unit device to integrated electronics. Polymers 2024 , 16 , 2613..

Park, T.; Kim, M.; Lee, E. K.; Hur, J.; Yoo, H. Overcoming downscaling limitations in organic semiconductors: strategies and progress. Small 2023 , 20 , 2306468..

Ji, Z.; Li, Z. Y.; Dai, X. J.; Xiang, L. Y.; Zhao, Y.; Wang, D. Y.; Zhang, X.; Liu, L. Y.; Han, Z. Y.; Niu, L. X.; Di, Y. Q.; Zou, Y.; Di, C. A.; Zhu, D. B. Organic photoexcitation-assisted molecular doping for high-performance polymeric thermoelectric materials. JACS Au 2024 , 4 , 3884−3895..

Xue, X.; Li, C.; Zhou, Q.; Yu, X. B.; Gao, C. Y., Chenchai, H. Y., Liao, J. C.; Shangguan, Z. C.; Zhang, X. S.; Zhang, G. X.; Zhang, D. Q. Conjugated polymer-based photo-crosslinker for efficient photo-patterning of polymer semiconductors. Adv. Mater. 2024 , 36 , 2407305..

Zhu, X. C.; Ekinci, H.; Pan, A.; Cui, B.; Zhu, X. L. Electron beam lithography on nonplanar and irregular surfaces. Microsyst. Nanoeng. 2024 , 10 , 52..

Lee, H.; Lee, S.; Cha, S.; Anoop, G.; Shin, H. Nanoscale electron beam patterning of PEDOT: PSS free-standing films for enhanced thermoelectric performance. Energy Environ. Mater. 2024 , 8 , e12824..

Xiang, L. Y.; He, Z. H.; Yan, C. Y.; Zhao, Y.; Li, Z. Y.; Jia, L. X.; Jiang, Z. L.; Dai, X. J.; Lemaur, V.; Ma, Y. Q.; Liu, L. Y.; Meng, Q.; Zou, Y.; Beljonne, D.; Zhang, F. J.; Zhang, D. Q.; Di, C. A.; Zhu, D. B. Nanoscale doping of polymeric semiconductors with confined electrochemical ion implantation. Nat. Nanotechnol. 2024 , 19 , 1122−1129..

[Choudhary, K.; Chen, A. X.; Pitch, G. M.; Runser, R.; Urbina, A.; Dunn, T.; Kodur, M.; Kleinschmidt, A.; Wang, B.; Bunch. J.; Fenning, D.; Ayzner, A.; Lipomi, D.; Comparison of the mechanical properties of a conjugated polymer deposited using spin coating, interfacial spreading, solution shearing, and spray coating. ACS Appl. Mater. Interfaces 2021 , 13 , 51436-51446..

Ren, W. B.; Yang, M. Z.; Zhou, L.; Fan, Y. J.; He, S.; Pan, J. Y.; Tang, T. X.; Xiao, Y.; Nan, C. W.; Shen, Y. Scalable ultrathin all-organic polymer dielectric films for high-temperature capacitive energy storage. Adv. Mater. 2022 , 34 , 2207421..

Lin, Y. T.; Lee, C. Y.; Wu, C. Y.; Lin, J. M.; Lee, T. C.; Tung, S. H.; Liu, C. L. High thermoelectric performance of spray-coated poly(3, 4-ethylenedioxyt hiophene): poly (styrenesulfonate) films enabled by two-step post-treatment process. J. Power Sources 2023 , 556 , 232516..

Darabi, S.; Yang, C, Y.; Li, Z. R.; Huang, J. D.; Hummel, M.; Sixta, H.; Fabiano, S.; Müller, C. Polymer-based n-type yarn for organic thermoelectric textiles. Adv. Electron. Mater. 2023 , 9 , 2201235..

Sun, T. T.; Zhou, B. Y.; Zheng, Q.; Wang, L. J.; Jiang, W.; Snyder, G. J. Stretchable fabric generates electric power from woven thermoelectric fibers. Nat. Commun. 2020 , 11 , 572..

[Chang, T. H.; Akin, S.; Cho, S. S.; Lee, J. S.; Lee, S. A.; Park, T. W.; Hong, S. K.; Yu, T. H.; Ji, Y. Y.; Yi, J. H.; Gong, L. S; Kim, D. R.; Kim, Y. L.; Jun, M. B.; Lee, C. H. In situ spray polymerization of conductive polymers for personalized e-textiles. ACS Nano . 2023 , 1 7 , 22733-22743..

Hossain, M. S.; Li, T. Z.; Yu, Y.; Yong, J.; Bahk, J. H.; Skafidas, E. Recent advances in printable thermoelectric devices: materials, printing techniques, and applications. RSC Adv. 2020 , 10 , 8421−8434..

Ferhat, S.; Domain, C.; Vidal, J.; Noël, D.; Ratiera, B.; Lucas, B. Organic thermoelectric devices based on a stable n-type nanocomposite printed on paper. Sustain. Energ. Fuels 2018 , 2 , 199−208..

Jing, J.; Chopplet, L.; Battaglini, N.; Noël, V.; Piro, B.; Leydecker, T.; Wang, Z. M.; Mattana, G.; Orgiu, E. The role of substrates and electrodes in inkjet-printed PEDOT: PSS thermoelectric generators. J. Mater. Chem. A 2024 , 12 , 6185−6192..

Zheng, C. Z.; Xiang, L. Y.; Jin, W. L.; Shen, H. G.; Zhao, W. R.; Zhang, F. J.; Di, C. A.; Zhu, D. B. A flexible self-powered densing element with integrated organic thermoelectric generator. Adv. Mater. Technol. 2019 , 4 , 1900247..

Wei, Q. S.; Mukaida, M.; Kirihara, K.; Naitoh, Y.; Ishida, T. Polymer thermoelectric modules screen-printed on paper. RSC Adv. 2014 , 4 , 28802−28806..

He, X.; He, R. H.; Lan, Q. M.; Wu, W. J.; Duan, F.; Xiao, J. D.; Zhang, M.; Zeng, Q. G.; Wu, J. H.; Liu, J. Y. Screen-printed fabrication of PEDOT: PSS/Silver nanowire composite films for transparent heaters. Materials 2017 , 10 , 200..

Nayak, R.; Shetty, P.; Selvakumar, M.; Rao, A.; Sriram K. V.; Wagle, S.; Nayak, S.; Kamath, V.; Shetty, N.; Saquib, M. Formulation and optimization of copper selenide/PANI hybrid screen printing ink for enhancing the power factor of flexible thermoelectric generator: a synergetic approach. Ceram. Int. 2024 , 50 , 25779−25791.

Zhang, B.; Yu, T. B.; Meulemans, A.; Naenen, V.; Rosenthal, M.; Escudero, D.; Molina-Lopez, F. Brush and dry: a posttreatment-free simple process to pattern PEDOT: PSS films with enhanced thermoelectric performance via shear flow-induced morphology tuning. ACS Appl. Mater. Interfaces 2025 , 17 , 20236−20247..

Zhang, Z. M.; Qiu, J. J.; Wang, S. R. Roll-to-roll printing of flexible thin-film organic thermoelectrics devices. Manuf. Lett. 2016 , 8 , 6−10..

Zhang, Z. M.; Wang, B. R.; Qiu, J. J.; Wang, S. R. Roll-to-roll printing of spatial wearable thermoelectrics. Manuf. Lett. 2019 , 21 , 28−34..

Zhang, Z.; Li, P. Y.; Xiong, M.; Zhang, L.; Chen, J. P.; Lei, X.; Pan, X. R.; Wang, X.; Deng, X. Y.; Shen, W. Y.; Mei, Z.; Li u, K. K.; Liu, G. C.; Huang, Z.; Lv, S. X.; Shao, Y. L.; Lei, T. Continuous production of ultratough semiconducting polymer fibers with high electronic performance. Sci. Adv. 2024 , 10 , 1−11..

Sun, T. T.; Liang, Y. F.; Ning, N. Y.; Wu, H. G.; Tian, M. Strain-insensitive stretchable conductive fiber based on helical core with double-network hydrogel. Adv. Fiber Mater. 2025 , 7 , 882−893..

Wang, W. B.; Guo, W. J.; Zhu, J. H.; Li, H.; Liu, S. Q.; Erden, F.; Li, P. C.; Yang, M.; He, C. B. Highly conductive wet-spun PANI/CNTs fibers for wearable energy harvesting and thermal sensing. J. Colloid Interface Sci. 2026 , 704 , 139289..

Zhang, C.; Liu, Y. L.; Li, H.; Liu, S. Q.; Li, P. C.; Zhang, H.; He, C. B. Enhanced thermoelectric properties of carbon nanotubes/polyaniline fibers through engineering doping level and orientation. Compos. Sci. Technol. 2024 , 253 , 110660..

Xu, C.; Yang, S. W.; Li, P. C.; Wang, H.; Li, H.; Liu, Z. T. Wet-spun PEDOT: PSS/CNT composite fibers for wearable thermoelectric energy harvesting. Compos. Commun. 2022 , 32 , 101179..

Liu, L.; Chen, J.; Liang, L. R.; Deng, L.; Chen, G. M. A PEDOT: PSS thermoelectric fiber generator. Nano Energ. 2022 , 102 , 107678..

Lee, H. J.; Anoop, G.; Lee, H. J.; Kim, C.; Park, J. W.; Choi, J.; Kim, H.; Kim, Y. J.; Lee, E.; Lee, S. G.; Kim, Y. M.; Lee, J. H.; Jo, J. Y. Enhanced thermoelectric performance of PEDOT:PSS/PANI-CSA polymer multilayer structures. Energy Environ. Sci. 2016 , 9 , 2806−2811..

Hanus, R.; Agne, M. T.; Rettie, A. J. E.; Chen, Z. W.; Tan, G. J.; Chung, D. Y.; Kanatzidis, M. G.; Pei, Y. Z.; Voorhees, P. W.; Snyder, G. J. Lattice softening significantly reduces thermal conductivity and leads to high thermoelectric efficiency. Adv. Mater. 2019 , 31 , 1900108..

Venkatasubramanian, R.; Siivola, E.; Colpitts, T.; O'Quinn, B. Thin-film thermoelectric devices with high room-temperature figures of merit. Nature 2001 , 413 , 597−602..

Weinbach, Q.; Nielsen, C. B.; Biniek, L. Multi length scale porosity as a playground for organic thermoelectric applications. J. Mater. Chem. C 2021 , 9 , 10173−10192..

Chen, M. Y.; Zhu, J.; Zhang, K.; Zhou, H. K.; Gao, Y. F.; Fan, J.; Chen, R. X.; Wang, H. L. Carbon nanofiber/polyaniline composite aerogel with excellent electromagnetic interference shielding, low thermal conductivity, and extremely low heat release. Nano-Micro Lett. 2024 , 17 , 80..

Zuo, G. Z.; Liu, X. J.; Fahlman, M.; Kemerink, M. High seebeck coefficient in mixtures of conjugated polymers. Adv. Funct. Mater. 2017 , 28 , 173280..

Villalva, D. R.; Derewjanko, D.; Zhang, Y. C.; Liu, Y.; Bates, A.; Sharma, A.; Han, J. H.; Gibert-Roca, M.; Arteaga, O. Z.; Jang, S.; Moro, S.; Costantini, G.; Gu, X. D.; Kemerink M.; Baran, D. Intermolecular-force-driven anisotropy breaks the thermoelectric trade-off in n-type conjugated polymers. Nat. Mater. 2025 , 24 , 1236−1244..

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