Synthesis of Polydicyclopentadiene Thermosets with High Stretchability and Self-healing Properties <italic style="font-style: italic">via</italic> Ring-opening Metathesis Polymerization

Wu Li; Cheng-Yang Ban; Yu-Hao Xiong; Da-Wei Zhang; You-Gui Li; Meng-He Xu; Gui-Fu Si

doi:10.1007/s10118-026-3577-x

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Synthesis of Polydicyclopentadiene Thermosets with High Stretchability and Self-healing Properties via Ring-opening Metathesis Polymerization

RESEARCH ARTICLE | Updated：2026-03-26

- Synthesis of Polydicyclopentadiene Thermosets with High Stretchability and Self-healing Properties via Ring-opening Metathesis Polymerization
- Synthesis of Polydicyclopentadiene Thermosets with High Stretchability and Self-healing Properties via Ring-opening Metathesis Polymerization
- Chinese Journal of Polymer Science 2026年44卷第4期页码：1083-1089
- Affiliations：
  
  a.School of Environmental and Chemical Engineering, Wuyi University, Jiangmen 529020, China
  b.School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei 230009, China
  c.Hefei National Laboratory for Physical Sciences at the Microscale, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei 230026, China
- Author bio：
  
  liyg@wyu.edu.cn (Y.G.L.)
  mhxu@ustc.edu.cn (M.H.X.)
  siguifu@ustc.edu.cn (G.F.S.)
- Funds：
  
  This work was financially supported by the Strategic Priority Research Program of the Chinese Academy of Sciences (No. XDA0540000), the National Natural Science Foundation of China (Nos. 22301294, 52025031 and 22261142664), and the USTC Research Funds of the Double First-Class Initiative (No. YD9990002030).;The authors declare no interest conflict.Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-026-3577-x.The data supporting the findings of this study are available from the corresponding author upon reasonable request. Author contact information: siguifu@ustc.edu.cn.
- DOI：10.1007/s10118-026-3577-x
  中图分类号：
- 收稿：2025-12-18，
  
  录用：2026-01-14，
  
  网络首发：2026-03-10，
  
  纸质出版：2026-04-05
- Accepted：
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Li, W.; Ban, C. Y.; Xiong, Y. H.; Zhang, D. W.; Li, Y. G.; Xu, M. H.; Si, G. F. Synthesis of polydicyclopentadiene thermosets with high stretchability and self-healing properties via ring-opening metathesis polymerization. Chinese J. Polym. Sci. 2026, 44, 1083–1089

Wu Li, Cheng-Yang Ban, Yu-Hao Xiong, et al. Synthesis of Polydicyclopentadiene Thermosets with High Stretchability and Self-healing Properties via Ring-opening Metathesis Polymerization[J]. Chinese Journal of Polymer Science, 2026, 44(4): 1083-1089. DOI: 10.1007/s10118-026-3577-x.
Li, W.; Ban, C. Y.; Xiong, Y. H.; Zhang, D. W.; Li, Y. G.; Xu, M. H.; Si, G. F. Synthesis of polydicyclopentadiene thermosets with high stretchability and self-healing properties via ring-opening metathesis polymerization. Chinese J. Polym. Sci. 2026, 44, 1083–1089 DOI： 10.1007/s10118-026-3577-x.

Wu Li, Cheng-Yang Ban, Yu-Hao Xiong, et al. Synthesis of Polydicyclopentadiene Thermosets with High Stretchability and Self-healing Properties via Ring-opening Metathesis Polymerization[J]. Chinese Journal of Polymer Science, 2026, 44(4): 1083-1089. DOI: 10.1007/s10118-026-3577-x. DOI：

摘要

A robust yet healable material is fabricated

via

ring-opening metathesis polymerization (ROMP) of commercial chelating norbornenes. The dynamic metal-ligand coordination crosslinks confer high stress and Shore hardness

while enabling efficient damage recovery. This simple st

rategy offers a new paradigm for designing durable and sustainable polymeric materials.

Abstract

Thermosetting polymers exhibit outstanding mechanical properties

thermal stability

and chemical resistance due to their permanently cross-linked network structures. However

the irreversible nature of covalent cross-linking renders these materials non-reprocessable and non-recyclable

posing significant environmental challenges. Although healable polymers based on dynamic covalent bonds and supramolecular interactions have emerged as promising alternatives

a broadly applicable strategy utilizing metal-ligand coordination in thermoset systems remains underexplored. In this work

we present a robust and healable thermoset system fabricated

via

ring-opening metathesis polymerization (ROMP) of commercially available chelating norbornene comonomers. Cross-linking is accomplished through O-donor coordination to Lewis acidic metal centers

yielding polydicyclopentadiene (PDCPD)-based networks that demonstrate high mechanical strength (up to 60.8 MPa) and effective self-healing performance. This methodology offers a simple and scalable approach to developing high-performance

sustainable thermosetting materials.

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Synthesis of Polydicyclopentadiene Thermosets with High Stretchability and Self-healing Properties via Ring-opening Metathesis Polymerization

Synthesis of Polydicyclopentadiene Thermosets with High Stretchability and Self-healing Properties via Ring-opening Metathesis Polymerization

DOI：10.1007/s10118-026-3577-x

摘要

Abstract

关键词

Keywords

references