Monitoring the Interfacial Polymerization and Membrane Fouling of Selective Layer with Boronate Ester Linkages <italic style="font-style: italic">via</italic> Aggregation-induced Emission

Meng-Yao Zhao; Xin-Zhao Luo; Die Li; Ya-Qi Dong; Qian Wang; Xiao-Ling Xu; Qiang Zhang

doi:10.1007/s10118-025-3352-4

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Monitoring the Interfacial Polymerization and Membrane Fouling of Selective Layer with Boronate Ester Linkages via Aggregation-induced Emission

RESEARCH ARTICLE | Updated：2025-08-25

- Monitoring the Interfacial Polymerization and Membrane Fouling of Selective Layer with Boronate Ester Linkages via Aggregation-induced Emission
- Monitoring the Interfacial Polymerization and Membrane Fouling of Selective Layer with Boronate Ester Linkages via Aggregation-induced Emission
- 高分子科学（英文） 2025年43卷第9期页码：1505-1515
- Affiliations：
  
  a.Key Laboratory of New Membrane Materials, Ministry of Industry and Information Technology, School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
  b.Institute of Polymer Ecomaterials, School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
- Author bio：
  
  lidie_njust@163.com (D.L.)
  zhangqiang@njust.edu.cn (Q.Z.)
- Funds：
  
  This work was financially supported by the Fundamental Research Funds for Central Universities (No. 30922010811).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-025-3352-4.
- DOI：10.1007/s10118-025-3352-4
  中图分类号： [M
- 收稿：2025-03-13，
  
  修回：2025-04-03，
  
  录用：2025-04-08，
  
  网络首发：2025-07-01，
  
  纸质出版：2025-09-05
- Accepted：
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Zhao, M. Y.; Luo, X. Z.; Li, D.; Dong, Y. Q.; Wang, Q.; Xu, X. L.; Zhang, Q. Monitoring the interfacial polymerization and membrane fouling of selective layer with boronate ester linkages via aggregation-induced emission. Chinese J. Polym. Sci. 2025, 43, 1505–1515

Meng-Yao Zhao, Xin-Zhao Luo, Die Li, et al. Monitoring the Interfacial Polymerization and Membrane Fouling of Selective Layer with Boronate Ester Linkages via Aggregation-induced Emission[J]. Chinese Journal of Polymer Science, 2025, 43(9): 1505-1515. DOI: 10.1007/s10118-025-3352-4.
Zhao, M. Y.; Luo, X. Z.; Li, D.; Dong, Y. Q.; Wang, Q.; Xu, X. L.; Zhang, Q. Monitoring the interfacial polymerization and membrane fouling of selective layer with boronate ester linkages via aggregation-induced emission. Chinese J. Polym. Sci. 2025, 43, 1505–1515 DOI： 10.1007/s10118-025-3352-4.

Meng-Yao Zhao, Xin-Zhao Luo, Die Li, et al. Monitoring the Interfacial Polymerization and Membrane Fouling of Selective Layer with Boronate Ester Linkages via Aggregation-induced Emission[J]. Chinese Journal of Polymer Science, 2025, 43(9): 1505-1515. DOI: 10.1007/s10118-025-3352-4. DOI：

摘要

An aggregation-induced emission (AIE)-active polymer membrane was prepared by the interfacial polymerization of a cyclodextrin-based glycocluster (CD@Glucose) and a tetraphenylethylene derivative modified with boronic acid groups (TPEDB) on the surface of a polyacrylonitrile (PAN) ultrafiltration membrane used for real-time monitoring of interfacial polymerization as well as membrane fouling.

Abstract

It is important to understand the evolution of the matter on the polymer membrane surface. The

in situ

and real-time monitoring of the membrane surface will not only favor the investigation of selective layer formation but can also track the fouling process during operation. Herein

an aggregation-induced emission (AIE)-active polymer membrane was prepared by the interfacial polymerization of a cyclodextrin-based glycocluster (CD@Glucose) and a tetraphenylethylene derivative modified with boronic acid groups (TPEDB) on the surface of a polyacrylonitrile (PAN) ultrafiltration membrane. This interfacial polymerization method can be stacked layer-by-layer to regulate the hydrophilicity and pore structure of the membrane. With the increase in the number of polymer layers

the separation and antifouling properties of the membrane gradually improved. Owing to the AIE property of the crosslinking agent TPEDB

the occurrence of interfacial polymerization and the degree of fouling during membrane operation can be monitored by the fluorescence distribution and intensity. With the aggravation of membrane fouling

the fluorescence decreased gradually

but recovered after cleaning. Therefore

this AIE effect can be used for real-time monitoring of interfacial polymerization as well as membrane fouling.

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Monitoring the Interfacial Polymerization and Membrane Fouling of Selective Layer with Boronate Ester Linkages via Aggregation-induced Emission

Monitoring the Interfacial Polymerization and Membrane Fouling of Selective Layer with Boronate Ester Linkages via Aggregation-induced Emission

DOI：10.1007/s10118-025-3352-4

摘要

Abstract

关键词

Keywords

references