Relaxation-reversed Phase Transition of Poly(butylene succinate)

Jia-Liang Qiao; Xin-Yu Liu; Ying-Zhuo Liu; Gui-Qiu Ma; Zhe Ma

doi:10.1007/s10118-025-3345-3

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Relaxation-reversed Phase Transition of Poly(butylene succinate)

RESEARCH ARTICLE | Updated：2025-08-25

- Relaxation-reversed Phase Transition of Poly(butylene succinate)
- Relaxation-reversed Phase Transition of Poly(butylene succinate)
- 高分子科学（英文） 2025年43卷第9期页码：1576-1583
- Affiliations：
  
  School of Materials Science and Engineering, State Key Laboratory of High Performance Roll Materials and Composite Forming, Tianjin Key Laboratory of Composite and Functional Materials, Key Laboratory of Organic Integrated Circuits, Ministry of Education, Tianjin University, Tianjin 300072, China
- Author bio：
  
  magq@tju.edu.cn (G.Q.M.)
  zhe.ma@tju.edu.cn (Z.M.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 52273025).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-025-3345-3.
- DOI：10.1007/s10118-025-3345-3
  中图分类号：
- 收稿：2025-02-24，
  
  修回：2025-03-22，
  
  录用：2025-03-24，
  
  网络首发：2025-05-08，
  
  纸质出版：2025-09-05
- Accepted：
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Qiao, J. L.; Liu, X. Y.; Liu, Y. Z.; Ma, G. Q.; Ma, Z. Relaxation-reversed phase transition of poly(butylene succinate). Chinese J. Polym. Sci. 2025, 43, 1576–1583

Jia-Liang Qiao, Xin-Yu Liu, Ying-Zhuo Liu, et al. Relaxation-reversed Phase Transition of Poly(butylene succinate)[J]. Chinese Journal of Polymer Science, 2025, 43(9): 1576-1583.
Qiao, J. L.; Liu, X. Y.; Liu, Y. Z.; Ma, G. Q.; Ma, Z. Relaxation-reversed phase transition of poly(butylene succinate). Chinese J. Polym. Sci. 2025, 43, 1576–1583 DOI： 10.1007/s10118-025-3345-3.

Jia-Liang Qiao, Xin-Yu Liu, Ying-Zhuo Liu, et al. Relaxation-reversed Phase Transition of Poly(butylene succinate)[J]. Chinese Journal of Polymer Science, 2025, 43(9): 1576-1583. DOI： 10.1007/s10118-025-3345-3.

摘要

This study employed the in-situ wide angle X-ray diffraction to explore the stretching-induced and relaxation-reversed phase transition in poly(butylene succinate) (PBS). It was found that relaxation was able to trigger the reversed

phase transition of PBS

where

phase completely transformed into

phase by partially unloading the stress.

Abstract

The stretching-induced phase transition of biodegradable poly(butylene succinate) (PBS) was explored using a combination of mechanical testing and

in situ

wide angle X-ray diffraction characterization. The phase transition from

phase to

phase can be effectively triggered by severe stretching

in which the threshold strain is dependent on the PBS crystallites. Interestingly

this

phase transition can be reversed immediately once mechanical stretching begins to be released. It should be pointed out that the finish of

phase transition reversed

corresponding to the disappearance of the generated

phase

does not necessarily need the external stretching to completely release. Fo

r the relaxation-reversed phase transition

the evolution of the normalized

-phase fraction exhibited a similar correlation with the stress released. It was indicated that the decay kinetics followed a stretching-dominant mechanism

and the amount of

phase generated just prior to relaxation had a negligible influence on the reversed phase transition.

关键词

Keywords

references

[Xu, S. S.; Zhou, J.; Pan, P. J. Strain-induced multiscale structural evolutions of crystallized polymers: from fundamental studies to recent progresses. Prog. Polym. Sci . 2023, 140 , 101676..

Zheng, L. R.; Liu, L.; Shao, C. G.; Wang, W.; Wang, B.; Pan, L.; Li, Y. S.; Ma, Z. Phase transition from tetragonal form II to hexagonal form I of butene-1/4-methyl-1-pentene random copolymers: molecular factor versus stretching stimuli. Macromolecules 2019 , 52 , 1188−1199..

Wang, W.; Shao, C. G.; Zheng, L. R.; Wang, B.; Pan, L.; Ma, G. Q.; Li, Y. S.; Wang, Y. M.; Liu, C. T.; Ma, Z. Stretching-induced phase transition of the butene-1/ethylene random copolymer: orientation and kinetics. J. Polym. Sci., Part B: Polym. Phys. 2018 , 57 , 116−126..

Miyasaka, K.; Makishima, K. Transition of nylon 6 γ -phase crystals by stretching in the chain direction. J. Polym. Sci., Part A: Polym. Chem. 1967 , 5 , 3017−3027..

Schultz, J. W. a. J. M. In-situ simultaneous synchrotron small- and wide-angle X-ray scattering measurement of poly(vinylidene fluoride) fibers under deformation. Macromolecules 2000 , 33 , 1765−1777..

[Guo, H.; Zhang, Z. C.; Zhu, Y. Study on the effect of stretching behavior on the properties of PVDF films and mechanism. Polymer 2024, 297 ..

Zhang, C. B.; Wang, L.; Yang, B.; Zhao, H.; Liu, G. M.; Wang, D. J. Stress-induced solid-solid crystal transition in trans-1,4-polyisoprene. Chinese J. Polym. Sci. 2022 , 40 , 256−265..

Lu, Y.; Sun, Y. Y.; Chen, R.; Li, X. H.; Men, Y. F. Defor mation temperature and lamellar thickness dependency of form I to form III phase transition in syndiotactic polypropylene during tensile stretching. Chinese J. Polym. Sci. 2014 , 32 , 1210−1217..

Danusso, F.; Gianotti, G. Isotactic polybutene-1: formation and transformation of modification 2. Die Makromolekulare Chemie 1965 , 88 , 149−158..

Azzurri, F.; Flores, A.; Alfonso, G. C.; Baltá Calleja, F. J. Polymorphism of isotactic poly(1-butene) as revealed by microindentation hardness. 1. kinetics of the transformation. Macromolecules 2002 , 35 , 9069−9073..

Miyoshi, T.; Mamun, A. Critical roles of molecular dynamics in the superior mechanical properties of isotactic-poly(1-butene) elucidated by solid-state NMR. Polym. J. 2012 , 44 , 65−71..

Li, Y.; Tang, S.; Pan, M. W.; Zhu, L.; Zhong, G. J.; Li, Z. M. Polymorphic extended-chain and folded-chain crystals in poly(vinylidene fluoride) achieved by combination of high pressure and ion–dipole interaction. Macromolecules 2015 , 48 , 8565−8573..

Du, C. H.; Zhu, B. K.; Xu, Y. Y. Effects of stretching on crystalline phase structure and morphology of hard elastic PVDF fibers. J. Appl. Polym. Sci. 2007 , 104 , 2254−2259..

Yang, J. J.; Pan, P. J.; Hua, L.; Zhu, B.; Dong, T.; Inoue, Y. Polymorphic crystallization and phase transition of poly(butylene adipate) in its miscible crystalline/crystalline blend with poly(vinylidene fluoride). Macromolecules 2010 , 43 , 8610−8618..

Martins, P.; Lopes, A. C.; Lanceros-Mendez, S. Electroactive phases of poly(vinylidene fluoride): determination, processing and applications. Prog. Polym. Sci. 2014 , 39 , 683−706..

Qiu, Z. B.; Lei, T. P.; Li, S. P.; Cai, X. M.; Yang, K. Insights into polymorphic transition of PVDF during nonsolvent-induced phase separation. Macromolecules 2024 , 57 , 1159−1168..

Nie, Y. J.; Zhao, W. P.; Chen, X.; Zhang, H.; Hu, J.; Wang, S. J.; Yan, S. K. Different crystallization behaviors of poly(vinylidene fluoride) blended with or coated with cetyltrimethylammonium bromide. Macromolecules 2023 , 56 , 8214−8221..

Tan, Z. Y.; Fu, C.; Gao, Y. X.; Qian, J.; Li, W. Y.; Wu, X. Y.; Chu, H. Y.; Chen, C. H.; Nie, W.; Ran, X. H. Modifications of gamma poly(vinylidene fluoride) ( γ -PVDF) films by high-energy electron beam irradiation. Radiat. Phys. Chem. 2018 , 153 , 258−268..

Li, Q. Q.; Wang, G. K.; Liang, Z. X.; Hu, Z. J. Highly transparent and adhesive poly(vinylidene difluoride) films for self-powered piezoelectric touch sensors. Chinese J. Polym. Sci. 2022 , 40 , 726−737..

[Ichikawa, Y.; Noguchi, K.; Okuyama, K. W., J Crystal transition mechanisms in poly(ethylene succinate). Polymer 2001, 42 , 3703-3708..

Takahashi, Y.; Sumita, I.; Tadokoro, H. Structural studies of polyethers. IX. planar zigzag modification of poly(ethylene oxide). J. Polym. Sci., Polym. Phys. Ed. 1973 , 11 , 2113−2122..

Liu, G. M.; Zheng, L. C.; Zhang, X. Q.; Li, C. C.; Jiang, S. C.; Wang, D. J. Reversible lamellar thickening induced by crystal transition in poly(butylene succinate). Macromolecules 2012 , 45 , 5487−5493..

Liu, G. M.; Zheng, L. C.; Zhang, X. Q.; Li, C. C.; Wang, D. J. Critical stress for crystal transition in poly(butylene succinate)-based crystalline–amorphous multiblock copolymers. Macromolecules 2014 , 47 , 7533−7539..

Tashiro, K.; Nakai, Y.; Kobayashi, M.; Tadokoro, H. Solid-state transition of poly(butylene terephthalate) induced by mechanical deformation. Macromolecules 1980 , 13 , 137−145..

Yokouchi, M.; Sakakibara, Y.; Chatani, Y.; Tadokoro, H.; Tanaka, T.; Yoda, K. Structures of two crystalline forms of poly(butylene terephthalate) and reversible transition between them by mechanical deformation. Macromolecules 1976 , 9 , 266−273..

Zhao, J. Y.; Chen, P. Z.; Lin, Y. F.; Chang, J. R.; Lu, A.; Chen, W.; Meng, L. P.; Wang, D. L.; Li, L. B. Stretch-induced crystallization and phase transitions of poly(dimethylsiloxane) at low temperatures: an in situ synchrotron radiation wide-angle X-ray scattering study. Macromolecules 2018 , 51 , 8424−8434..

Liu, G. M.; Zhang, X. Q.; Wang, D. J. Stress induced reversible crystal transition in polymers. Polym. Int. 2015 , 64 , 951−956..

Tashiro, K.; Cheng, J.; Ike, M. Stress-induced reversible phase transition of poly(tetramethylene naphthalate). Macromolecules 2003 , 36 , 359−367..

Auriemma, F.; De Rosa, C. Time-resolved study of the martensitic phase transition in syndiotactic polypropylene. Macromolecules 2003 , 36 , 9396−9410..

De Rosa, C.; Auriemma, F.; Corradi, M.; Caliano, L.; Talarico, G. Stress-induced phase transitions in syndiotactic propene−butene copolymers. Macromolecules 2008 , 41 , 8712−8720..

Zhou, J.; Zheng, Y.; Shan, G. R.; Bao, Y. Z.; Wang, W. J.; Pan, P. J. Stretch-induced α-to-β crystal transition and lamellae structural evolution of poly(butylene adipate-ran-terephthalate) aliphatic–aromatic copolyester. Macromolecules 2019 , 52 , 1334−1347..

Wang, Y. T.; Jiang, Z. Y.; Wu, Z. H.; Men, Y. F. Tensile deformation of polybutene-1 with stable form I at elevated temperature. Macromolecules 2013 , 46 , 518−522..

Men, Y. F. Critical strains determine the tensile deformation mechanism in semicrystalline polymers. Macromolecules 2020 , 53 , 9155−9157..

Chen, G. Q.; Patel, M. K. Plastics derived from biological sources: present and future: a technical and environmental review. Chem. Rev. 2012 , 112 , 2082−2099..

Barletta, M.; Aversa, C.; Ayyoob, M.; Gisario, A.; Hamad, K.; Mehrpouya, M.; Vahabi, H. Poly(butylene succinate) (PBS): materials, processing, and industrial applications. Prog. Polym. Sci. 2022 , 132 , 101579..

Tserki, V.; Matzinos, P.; Pavlidou, E.; Panayiotou, C. Biodegradable aliphatic polyesters. part II. synthesis and characterization of chain extended poly(butylene succinate- co -butylene adipate). Polym. Degrad. Stabil. 2006 , 91 , 377−384..

Tserki, V.; Matzinos, P.; Pavlidou, E.; Vachliotis, D.; Panayiotou, C. Biodegradable aliphatic polyesters. part I. properties and biodegradation of poly(butylene succinate-co-butylene adipate). Polym. Degrad. Stabil. 2006 , 91 , 367−376..

Xu, J.; Guo, B. H. Poly(butylene succinate) and its copolymers: research, development and industrialization. Biotechnol. J. 2010 , 5 , 1149−1163..

Gigli, M.; Fabbri, M.; Lotti, N.; Gamberini, R.; Rimini, B.; Munari, A. Poly(butylene succinate)-based polyesters for biomedical applications: a review. Eur. Polym. J. 2016 , 75 , 431−460..

Zhu, C. Y.; Zhang, Z. Q.; Liu, Q. P.; Wang, Z. P.; Jin, J. Synthesis and biodegradation of aliphatic polyesters from dicarboxylic acids and diols. J. Appl. Polym. Sci. 2003 , 90 , 982−990..

Jacquel, N.; Freyermouth, F.; Fenouillot, F.; Rousseau, A.; Pascault, J. P.; Fuertes, P.; Saint-Loup, R. Synthesis and properties of poly(butylene succinate): efficiency of different transesterification catalysts. J. Polym. Sci., Part A: Polym. Chem. 2011 , 49 , 5301−5312..

Jin, T. X.; Zhou, M.; Hu, S. D.; Chen, F.; Fu, Q.; Fu, Y. Effect of molecular weight on the properties of poly(butylene succinate). Chinese J. Polym. Sci. 2014 , 32 , 953−9 60..

Ichikawa, Y.; Kondo, H.; Igarashi, Y.; Noguchi, K.; Okuyama, K.; Washiyama, J. Crystal structures of α and β forms of poly(tetramethylene succinate). Polymer 2000 , 41 , 4719−4727..

Ichikawa, Y.; Washiyama, J.; Moteki, Y.; Noguchi, K.; Okuyama, K. Crystal transition mechanisms in poly(tetramethylene succinate). Polym. J. 1995 , 27 , 1230−1238..

Tatsuoka, S.; Sato, H. Stress-induced crystal transition of poly(butylene succinate) studied by terahertz and low-frequency raman spectroscopy and quantum chemical calculation. Spectrochim. Acta, Part A 2018 , 197 , 95−102..

Ichikawa, Y.; Suzuki, J.; Washiyama, J.; Moteki, Y.; Noguchi, K.; Okuyama, K. Strain-induced crystal modification in poly(tetramethylene succinate). Polymer 1994 , 35 , 3338−3339..

Tashiro, K.; Hu, J.; Wang, H.; Hanesaka, M.; Saiani, A. Refinement of the crystal structures of forms I and II of isotactic polybutene-1 and a proposal of phase transition mechanism between them. Macromolecules 2016 , 49 , 1392−1404..

Shen, J. Z.; Li, W.; Zhao, R. J.; Liu, Y. Z.; Ma, Z. Utilizing 3-methyl-1-butene co-units to tailor phase transition behavior in butene-1 copolymers. CrystEngComm 2024 , 26 , 51−60..

Men, Y. F.; Rieger, J.; Strobl, G. Role of the entangled amorphous network in tensile deformation of semicrystalline polymers. Phys. Rev. Lett. 2003 , 91 , 095502..

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