Unconventional 2D Periodic Nanopatterns Based on Block Molecules

Bo Hou; Wen-Bin Zhang; Yu Shao

doi:10.1007/s10118-023-3038-8

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Unconventional 2D Periodic Nanopatterns Based on Block Molecules

REVIEW | Updated：2023-09-21

- Unconventional 2D Periodic Nanopatterns Based on Block Molecules
- Unconventional 2D Periodic Nanopatterns Based on Block Molecules
- 高分子科学（英文版） 2023年41卷第10期页码：1508-1524
- Affiliations：
  
  Beijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry & Physics of Ministry of Education, Center for Soft Matter Science and Engineering, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
- Author bio：
  
  wenbin@pku.edu.cn (W.B.Z.)
  yushao@pku.edu.cn (Y.S.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 21925102, 21991132, 92056118 and 22101010). W. B. Z. also thanks the financial support from the National Key R&D Program of China (No. 2018YFB0703702) and Beijing National Laboratory for Molecular Sciences (No. BNLMS-CXXM-202006). We thank Dr. Yahong Chen at Peking University for helpful discussion.;Wen-Bin Zhang received his BS from Peking University in 2004 and his Ph.D. in Polymer Science from the University of Akron in 2010. After his postdoctoral study at Caltech, he started his independent career at Peking University in 2013 and was promoted to a tenured associate professor in 2019 and to full professor in 2020. He aims to integrate the design principles and building blocks of both synthetic and biological polymers for the development of precision macromolecules with unique functions for health-related applications.Yu Shao obtained his Ph.D. in material science from Donghua University in 2019. He then worked as a Boya postdoctoral fellow and BMS fellow at the College of Chemistry and Molecular Engineering at Peking University in Prof. Wen-Bin Zhang’s group. In 2023, he joined Peking University as a deputy investigator. His main research interests are the design and synthesis of giant molecules and exploring their applications in fields of unconventional phase construction and advanced nanofabrication.
- DOI：10.1007/s10118-023-3038-8
  中图分类号：
- 收稿：2023-06-20，
  
  修回：2023-8-4，
  
  录用：2023-8-15，
  
  网络首发：2023-08-24，
  
  纸质出版：2023-10-01
- Accepted：
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Hou, B.; Zhang, W. B.; Shao, Y. Unconventional 2D periodic nanopatterns based on block molecules. Chinese J. Polym. Sci. 2023, 41, 1508–1524

Bo Hou, Wen-Bin Zhang, Yu Shao. Unconventional 2D Periodic Nanopatterns Based on Block Molecules[J]. Chinese Journal of Polymer Science, 2023, 41(10): 1508-1524.
Hou, B.; Zhang, W. B.; Shao, Y. Unconventional 2D periodic nanopatterns based on block molecules. Chinese J. Polym. Sci. 2023, 41, 1508–1524 DOI： 10.1007/s10118-023-3038-8.

Bo Hou, Wen-Bin Zhang, Yu Shao. Unconventional 2D Periodic Nanopatterns Based on Block Molecules[J]. Chinese Journal of Polymer Science, 2023, 41(10): 1508-1524. DOI： 10.1007/s10118-023-3038-8.

摘要

This review highlights the structural diversity of emerged unconventional 2D morphologies including the bottom-up self-assembly of block molecules such as block copolymers

liquid crystals

giant molecules

etc.

together with the state-of-the-art top-down nanofabrication technologies using direct self-assembly of block copolymers.

Abstract

This review summarizes the self-assembly of block molecules forming unconventional two-dimensional (2D) periodic nanopatterns. Especially

we emphasize the structural evolution from simple columnar phases to complex 2D tiling morphologies in soft materials including block copolymers

liquid crystals

giant molecules

etc

. Then

the state-of-the-art nanofabrication technologies for making sophisticated nanostructures with specific functions

via

combining both bottom-up assembly and top-down lithography-based methods are discussed

highlighting the use of directed self-assembly processes. Finally

we provide our perspective on this area. By further increasing the complexity of block molecules and the designability of lithography

low-dimensional ordered morphologies will be particularly promising for further application in nanotechnology.

关键词

Keywords

references

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