<italic style="font-style: italic">n</italic>-Type Semiconductive Polymers Based on Pyrene-1,5,6,10-Tetracarboxyl Diimide

Xu-Dong Bai; Zi-Di Yu; Yao Li; Tian-Yu Zhang; Di Zhang; Jie-Yu Wang; Jian Pei; Da-Hui Zhao

doi:10.1007/s10118-023-3026-z

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n-Type Semiconductive Polymers Based on Pyrene-1,5,6,10-Tetracarboxyl Diimide

RESEARCH ARTICLE | Updated：2023-09-21

- n-Type Semiconductive Polymers Based on Pyrene-1,5,6,10-Tetracarboxyl Diimide
- n-Type Semiconductive Polymers Based on Pyrene-1,5,6,10-Tetracarboxyl Diimide
- 高分子科学（英文版） 2023年41卷第10期页码：1584-1590
- Affiliations：
  
  Beijing National Laboratory for Molecular Sciences, Centre of Soft Matter Science and Engineering and Key Lab of Polymer Chemistry & Physics of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China
- Author bio：
  
  jianpei@pku.edu.cn (J.P.)
  dhzhao@pku.edu.cn (D.H.Z.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 21925501, 22175004 and 22020102001) and the Beijing National Laboratory for Molecular Sciences (No. BNLMS-CXXM-201902). Part of the characterization measurements were performed at the Analytical Instrumentation Center of Peking University, and the computational resources were supplied by the High-performance Computing Platform of Peking University.;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-023-3026-z.
- DOI：10.1007/s10118-023-3026-z
  中图分类号：
- 收稿：2023-04-28，
  
  修回：2023-6-19，
  
  录用：2023-7-4，
  
  网络首发：2023-08-07，
  
  纸质出版：2023-10-01
- Accepted：
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Bai, X. D.; Yu, Z. D.; Li, Y.; Zhang, T. Y.; Zhang, D.; Wang, J. Y.; Pei, J.; Zhao, D. H. n-Type semiconductive polymers based on pyrene-1,5,6,10-tetracarboxyl diimide. Chinese J. Polym. Sci. 2023, 41, 1584–1590

Xu-Dong Bai, Zi-Di Yu, Yao Li, et al. n-Type Semiconductive Polymers Based on Pyrene-1,5,6,10-Tetracarboxyl Diimide[J]. Chinese Journal of Polymer Science, 2023, 41(10): 1584-1590. DOI: 10.1007/s10118-023-3026-z.
Bai, X. D.; Yu, Z. D.; Li, Y.; Zhang, T. Y.; Zhang, D.; Wang, J. Y.; Pei, J.; Zhao, D. H. n-Type semiconductive polymers based on pyrene-1,5,6,10-tetracarboxyl diimide. Chinese J. Polym. Sci. 2023, 41, 1584–1590 DOI： 10.1007/s10118-023-3026-z.

Xu-Dong Bai, Zi-Di Yu, Yao Li, et al. n-Type Semiconductive Polymers Based on Pyrene-1,5,6,10-Tetracarboxyl Diimide[J]. Chinese Journal of Polymer Science, 2023, 41(10): 1584-1590. DOI: 10.1007/s10118-023-3026-z. DOI：

摘要

Using the novel pyrene-1

10-tetracarboxyldiimide (PyDI) as the electron acceptor

two new D-A conjugated polymers are synthesized. In solution-processed FETs

these polymers display impressive electron mobility of 0.18 and 0.20 cm2·V

−1

·s

−1

demonstrating the optimal potential of PyDI for the development of high-performance electron-transporting materials.

Abstract

Donor-acceptor (D-A) conjugated polymers comprising electron-deficient aromatic dicarboximide units represent an important type of organic semiconductors

especially for electron transporting properties. Pyrene-1

10-tetracarboxyl diimide (PyDI)

a new PAH dicarboximide molecule recently reported by us

provides a fine balance between the electron-stabilizing ability and

-stacking tendency

as compared to the naphthalenediimide (NDI) and perylenediimide (PDI) analogues. In this study

using thienylene-vinylene-thienylene (TVT) and biselenophene (BS) as the electron donating comonomer

along with PyDI as the acceptor moiety

we develop two new D-A type conjugated polymers

which exhibit impressive electron-transporting performance. Specifically

in the solution-processed OFET devices

electron mobility of 0.18 and 0.20 cm

·V

−1

·s

−1

are achieved with these polymers

respectively. Such findings further prove the optimal potential of PyDI for application as an electron-acceptor building block in the development of polymeric

-type semiconductors among all various high-performance functional D-A polymers.

关键词

Keywords

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n-Type Semiconductive Polymers Based on Pyrene-1,5,6,10-Tetracarboxyl Diimide

n-Type Semiconductive Polymers Based on Pyrene-1,5,6,10-Tetracarboxyl Diimide

DOI：10.1007/s10118-023-3026-z

摘要

Abstract

关键词

Keywords

references