Modified Triphenylmethane-based Polyimides with Improved Optical, Dielectric and Solubility Properties <italic style="font-style: italic">via</italic> Post-Polymerization Modification

Yan-Cheng Wu; Guo-Tao Huang; Man-Yu Lian; Rui Liang; Hong-Lin Deng; Feng Gan; Yang-Fan Zhang; Ning-Bo Yi; Li-Yong Tian; Chun-Ping Ma; Yen Wei

doi:10.1007/s10118-023-3018-z

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Modified Triphenylmethane-based Polyimides with Improved Optical, Dielectric and Solubility Properties via Post-Polymerization Modification

RESEARCH ARTICLE | Updated：2023-09-21

- Modified Triphenylmethane-based Polyimides with Improved Optical, Dielectric and Solubility Properties via Post-Polymerization Modification
- Modified Triphenylmethane-based Polyimides with Improved Optical, Dielectric and Solubility Properties via Post-Polymerization Modification
- 高分子科学（英文版） 2023年41卷第10期页码：1609-1616
- Affiliations：
  
  a.School of Textile Materials and Engineering, Wuyi University, Jiangmen 529020, China
  b.Department of Chemistry and the Tsinghua Center for Frontier Polymer Research, Tsinghua University, Beijing 100084, China
- Author bio：
  
  wyc@wyu.edu.cn (Y.C.W.)
  machunpingaa@126.com (C.P.M.)
  weiyen@mail.tsinghua.edu.cn (Y.W.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 52203014, 52103010 and 52003200), the Guangdong Basic and Applied Basic Research Foundation (Nos. 2020A1515110767, 2022A1515010969, 2020A1515110897 and 2023A1515010999), the Open Fund for Key Lab of Guangdong High Property and Functional Macromolecular Materials, China (No. 20220601), Guangdong Provincial Department of Education Featured Innovation Project (No. 2021KTSCX138), the Science Foundation for Young Research Groups of Wuyi University (Nos. 2020AL016 and 2019AL019).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-023-3018-z.
- DOI：10.1007/s10118-023-3018-z
  中图分类号：
- 收稿：2023-05-08，
  
  修回：2023-6-1，
  
  录用：2023-6-4，
  
  网络首发：2023-07-24，
  
  纸质出版：2023-10-01
- Accepted：
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Wu, Y. C.; Huang, G. T.; Lian, M. Y.; Liang, R.; Deng, H. L.; Gan, F.; Zhang, Y. F.; Yi, N. B.; Tian, L. Y.; Ma, C. P.; Wei, Y. Modified triphenylmethane-based polyimides with improved optical, dielectric and solubility properties via post-polymerization modification. Chinese J. Polym. Sci. 2023, 41, 1609–1616

Yan-Cheng Wu, Guo-Tao Huang, Man-Yu Lian, et al. Modified Triphenylmethane-based Polyimides with Improved Optical, Dielectric and Solubility Properties via Post-Polymerization Modification[J]. Chinese Journal of Polymer Science, 2023, 41(10): 1609-1616. DOI: 10.1007/s10118-023-3018-z.
Wu, Y. C.; Huang, G. T.; Lian, M. Y.; Liang, R.; Deng, H. L.; Gan, F.; Zhang, Y. F.; Yi, N. B.; Tian, L. Y.; Ma, C. P.; Wei, Y. Modified triphenylmethane-based polyimides with improved optical, dielectric and solubility properties via post-polymerization modification. Chinese J. Polym. Sci. 2023, 41, 1609–1616 DOI： 10.1007/s10118-023-3018-z.

Yan-Cheng Wu, Guo-Tao Huang, Man-Yu Lian, et al. Modified Triphenylmethane-based Polyimides with Improved Optical, Dielectric and Solubility Properties via Post-Polymerization Modification[J]. Chinese Journal of Polymer Science, 2023, 41(10): 1609-1616. DOI: 10.1007/s10118-023-3018-z. DOI：

摘要

A post-polymerization modification is developed to prepare a new family of bulky tert-butyldimethylsiloxy modified polyimide films with significantly improved optical

dielectric and solubility properties.

Abstract

A family of new triphenylmethane (TPM)-based polyimides (PIs) containing bulky

tert

-butyldimethylsiloxy (TBS) side-groups (PI-TPMOSis) has been prepared by a post-polymerization modification

via

a simple silyl ether reaction of TPM-based PIs containing hydroxyl (OH) groups (PI-TPMOHs). The attachment of TBS side-groups in PI-TPMOSis can be achieved up to 100%

as confirmed by the

H-NMR and IR spectra. Due to the presence of the TPM structure

PI-TPMOSi films still display the excellent thermal stability with high glass transition temperature (

) of 314−351 °C and high degradation temperature (

d5%

) of 480−501 °C. It is quite remarkable that the introduction of TBS side-groups into PI-TPMOSi chains results in more superior optical

dielectric and solubility properties in comparison with the precursor PI-TPMOH films

probably due to the reductions of the packing density and charge-transfer complexes (CTCs) formation. The optical transmittance at 400 nm (

400

) of PI-TPMOSi films is significantly increased from 45.3%−68.8% to 75.4%−81.6% of the precursor PI-TPMOH films. The dielectric constant (

) and dissipation factor (

) at 1 MHz of PI-TPMOSi films are reduced from 4.11−4.40 and 0.00159−0.00235 to 2.61−2.92 and 0.00125−0.00171 of the precursor PI-TPMOH films

respectively. Combining the molecular design and simple preparation method

this study provides an effective approach for enhancement of various properties of PI films for microelectronic and photoelectric engineering applications.

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Modified Triphenylmethane-based Polyimides with Improved Optical, Dielectric and Solubility Properties via Post-Polymerization Modification

Modified Triphenylmethane-based Polyimides with Improved Optical, Dielectric and Solubility Properties via Post-Polymerization Modification

DOI：10.1007/s10118-023-3018-z

摘要

Abstract

关键词

Keywords

references