Fluorinated Colorless Polyimides with High Heat-resistance and Low Birefringence

Bing-Yu Zou; Lu-Hao Qiu; Huan-Yu Lei; Jin-Ming Liu; Wei-Feng Peng; Hong-Qin Zhao; Feng Bao; Ming-Jun Huang

doi:10.1007/s10118-023-3011-6

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Fluorinated Colorless Polyimides with High Heat-resistance and Low Birefringence

RESEARCH ARTICLE | Updated：2023-09-21

- Fluorinated Colorless Polyimides with High Heat-resistance and Low Birefringence
- Fluorinated Colorless Polyimides with High Heat-resistance and Low Birefringence
- 高分子科学（英文版） 2023年41卷第10期页码：1599-1608
- Affiliations：
  
  a.South China Advanced Institute for Soft Matter Science and Technology, School of Emergent Soft Matter, South China University of Technology, Guangzhou 510640, China
  b.Guangdong Provincial Key Laboratory of Functional and Intelligent Hybrid Materials and Devices, South China University of Technology, Guangzhou 510640, China
- Author bio：
  
  fbao@scut.edu.cn (F.B.)
  huangmj25@scut.edu.cn (M.J.H.)
- Funds：
  
  This work was financially supported by the Natural Science Foundation of Guangdong Province (No. 2022A1515010125), the Key-Area Research and Development Program of Guangdong Province (No. 2020B010182002), the Guangdong Basic and Applied Basic Research Foundation (No. 2022A1515110543), the R&D Program of Guangzhou (No. 2023A04J1577), the Major Program of National Natural Science Foundation of China (No. 51890871), the Recruitment Program of Guangdong (No. 2016ZT06C322), the 111 Project (No. B18023) and Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application at Soochow University. We thank Prof. Rongrong Hu and Dr. Guanfei Yao of South China University of Technology for the assistance in GPC measurement.;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-023-3011-6.
- DOI：10.1007/s10118-023-3011-6
  中图分类号：
- 收稿：2023-04-23，
  
  修回：2023-5-24，
  
  录用：2023-5-31，
  
  网络首发：2023-07-24，
  
  纸质出版：2023-10-01
- Accepted：
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Zou, B. Y.; Qiu, L. H.; Lei, H. Y.; Liu, J. M.; Peng, W. F.; Zhao, H. Q.; Bao, F.; Huang, M. J. Fluorinated colorless polyimides with high heat-resistance and low birefringence. Chinese J. Polym. Sci. 2023, 41, 1599–1608

Bing-Yu Zou, Lu-Hao Qiu, Huan-Yu Lei, et al. Fluorinated Colorless Polyimides with High Heat-resistance and Low Birefringence[J]. Chinese Journal of Polymer Science, 2023, 41(10): 1599-1608.
Zou, B. Y.; Qiu, L. H.; Lei, H. Y.; Liu, J. M.; Peng, W. F.; Zhao, H. Q.; Bao, F.; Huang, M. J. Fluorinated colorless polyimides with high heat-resistance and low birefringence. Chinese J. Polym. Sci. 2023, 41, 1599–1608 DOI： 10.1007/s10118-023-3011-6.

Bing-Yu Zou, Lu-Hao Qiu, Huan-Yu Lei, et al. Fluorinated Colorless Polyimides with High Heat-resistance and Low Birefringence[J]. Chinese Journal of Polymer Science, 2023, 41(10): 1599-1608. DOI： 10.1007/s10118-023-3011-6.

摘要

We designed and synthesized a series of fluorinated colorless polyimides (CPI) through one-step polymerization of 2

5-substituted m-phenylenediamine diamine and CHDA dianhydride. Excellent combination of high heat-resistance

high transparency and low birefringence was achieved in these CPIs with simple chemical structures.

Abstract

The development of optical films with high transparency

high thermal resistance and low birefringence remains a challenge in the flexible display industry. In this work

we designed and synthesized a series of fluorinated colorless polyimides (CPIs) materials using 2

5-substituted

-phenylenediamine diamine monomers and 1

5-cyclohexanetetracarboxylic dianhydride (CHDA). We systematically studied the effects of fluorinated group substitutions on the thermal

mechanical

optical and dielectric properties of CPI films. The introduction of alicyclic CHDA dianhydride affords high transparency and low yellowness

while the 2

5-substituted

-phenylenediamine diamines offer the CPIs with quite low birefringence as well as high glass transition temperatures. A particular CHDA/

3FBDA film with simple chemical structure stands out

exhibiting well-balanced overall properties.

关键词

Keywords

references

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