Catalyst-Free Four-Component Spiropolymerization for the Construction of Spirocopolymers with Tunable Photophysical Properties

Luo-Jie Zhu; Gui-Nan Zhu; Wen-Ya Yan; Peng Sun; Jian-Bing Shi; Jun-Ge Zhi; Bin Tong; Zheng-Xu Cai; Yu-Ping Dong

doi:10.1007/s10118-023-3007-2

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Catalyst-Free Four-Component Spiropolymerization for the Construction of Spirocopolymers with Tunable Photophysical Properties

RESEARCH ARTICLE | Updated：2023-09-21

- Catalyst-Free Four-Component Spiropolymerization for the Construction of Spirocopolymers with Tunable Photophysical Properties
- Catalyst-Free Four-Component Spiropolymerization for the Construction of Spirocopolymers with Tunable Photophysical Properties
- 高分子科学（英文版） 2023年41卷第10期页码：1525-1532
- Affiliations：
  
  a.Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green Applications, School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
  b.Advanced Research Institute of Multidisciplinary Science, Beijing Institute of Technology, Beijing 100081, China
  c.Key Laboratory of Cluster Science of Ministry of Education, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China
- Author bio：
  
  sunpeng@bit.edu.cn (P.S.)
  chdongyp@bit.edu.cn (Y.P.D.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 21875019, 22175023, 21975020 and 21975021), the National Key Research and Development Program of China (No. 2018YFA0901800) College Students’ Innovative Entrepreneurial Training Plan Program (No. BIT2022LH180) and Beijing Institute of Technology Research Fund Program for Young Scholars.;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-023-3007-2.
- DOI：10.1007/s10118-023-3007-2
  中图分类号：
- 收稿：2023-03-26，
  
  修回：2023-5-17，
  
  录用：2023-5-23，
  
  网络首发：2023-07-05，
  
  纸质出版：2023-10-01
- Accepted：
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Zhu, L. J.; Zhu, G. N.; Yan, W. Y.; Sun, P.; Shi, J. B.; Zhi, J. G.; Tong, B.; Cai, Z. X.; Dong, Y. P. Catalyst-free four-component spiropolymerization for the construction of spirocopolymers with tunable photophysical properties. Chinese J. Polym. Sci. 2023, 41, 1525–1532

Luo-Jie Zhu, Gui-Nan Zhu, Wen-Ya Yan, et al. Catalyst-Free Four-Component Spiropolymerization for the Construction of Spirocopolymers with Tunable Photophysical Properties[J]. Chinese Journal of Polymer Science, 2023, 41(10): 1525-1532.
Zhu, L. J.; Zhu, G. N.; Yan, W. Y.; Sun, P.; Shi, J. B.; Zhi, J. G.; Tong, B.; Cai, Z. X.; Dong, Y. P. Catalyst-free four-component spiropolymerization for the construction of spirocopolymers with tunable photophysical properties. Chinese J. Polym. Sci. 2023, 41, 1525–1532 DOI： 10.1007/s10118-023-3007-2.

Luo-Jie Zhu, Gui-Nan Zhu, Wen-Ya Yan, et al. Catalyst-Free Four-Component Spiropolymerization for the Construction of Spirocopolymers with Tunable Photophysical Properties[J]. Chinese Journal of Polymer Science, 2023, 41(10): 1525-1532. DOI： 10.1007/s10118-023-3007-2.

摘要

A series of spirocopolymers are successfully constructed through the catalyst-free four-component spiropolymerization of diisocyanides

activated alkynes

and two different kinds of monomers with reactive carbonyl groups. The spirocopolymers display the unique cluster-triggered emission and aggregation-induced emission properties

and their emission properties can be well-modulated by altering the ratio of comonomers.

Abstract

Spiropolymers have gained a great deal of interest from both academic and industrial fields by virtue of their unique geometric structures and physical properties. Herein

we prepared a series of spirocopolymers through the catalyst-free four-component spiropolymerization of diisocyanides

activated alkynes

and two different kinds of monomers with reactive carbonyl groups. It is found that the polymerization reactivity of monomers

feeding modes

and feed ratios play significant roles in spirocopolymerization. Monomers with high reactivity and feeding reactive monomers first contribute to improving the molecular weights and yields of the polymers. The constructed copolymers have two different kinds of spiro structures

which is confirmed by the nuclear magnetic resonance. In addition

the spirocopolymers display the unique cluster-triggered emission and aggregation-induced emission properties

and their emission properties can be well-modulated by altering the ratio of comonomers. It is highly anticipated that this line of research will enrich the methodology of multi-component spiropolymerization

and provide a new insight into developing spiropolymers with various spiro structures and tunable properties.

关键词

Keywords

references

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