Hyperbranched Polymeric Fluorosurfactants: Synthesis, Surface Activity and Their Application in Firefighting Foams

Dan-Ling Yang; Pei-Yao Chen; Yan Wang; Shuang Zhuang; Yu Chen; Hua-Ji Liu

doi:10.1007/s10118-023-2981-8

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Hyperbranched Polymeric Fluorosurfactants: Synthesis, Surface Activity and Their Application in Firefighting Foams

RESEARCH ARTICLE | Updated：2023-11-10

- Hyperbranched Polymeric Fluorosurfactants: Synthesis, Surface Activity and Their Application in Firefighting Foams
- Hyperbranched Polymeric Fluorosurfactants: Synthesis, Surface Activity and Their Application in Firefighting Foams
- 高分子科学（英文版） 2023年41卷第11期页码：1767-1777
- Affiliations：
  
  a.Department of Chemistry, School of Science, Tianjin University, Tianjin 300354, China
  b.Tianjin Fire Research Institute of MEM, Tianjin 300381, China
- Author bio：
  
  chenyu@tju.edu.cn (Y.C.)
  liuhuaji@tju.edu.cn (H.J.L.)
- Funds：
  
  This work was financially supported by the Key Research and Development Project of the Ministry of Science and Technology of China (No. 2022YFC3004900).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-023-2981-8.
- DOI：10.1007/s10118-023-2981-8
  中图分类号：
- 收稿：2023-02-13，
  
  修回：2023-3-19，
  
  录用：2023-3-22，
  
  网络首发：2023-05-07，
  
  纸质出版：2023-11-01
- Accepted：
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Yang, D. L.; Chen, P. Y.; Wang, Y.; Zhuang, S.; Chen, Y.; Liu, H. J. Hyperbranched polymeric fluorosurfactants: synthesis, surface activity and their application in firefighting foams. Chinese J. Polym. Sci. 2023, 41, 1767–1777

Dan-Ling Yang, Pei-Yao Chen, Yan Wang, et al. Hyperbranched Polymeric Fluorosurfactants: Synthesis, Surface Activity and Their Application in Firefighting Foams[J]. Chinese Journal of Polymer Science, 2023, 41(11): 1767-1777.
Yang, D. L.; Chen, P. Y.; Wang, Y.; Zhuang, S.; Chen, Y.; Liu, H. J. Hyperbranched polymeric fluorosurfactants: synthesis, surface activity and their application in firefighting foams. Chinese J. Polym. Sci. 2023, 41, 1767–1777 DOI： 10.1007/s10118-023-2981-8.

Dan-Ling Yang, Pei-Yao Chen, Yan Wang, et al. Hyperbranched Polymeric Fluorosurfactants: Synthesis, Surface Activity and Their Application in Firefighting Foams[J]. Chinese Journal of Polymer Science, 2023, 41(11): 1767-1777. DOI： 10.1007/s10118-023-2981-8.

摘要

Hyperbranched polymeric fluorosurfactants had a strong synergism with the small molecule fluorosurfactant C1157 in raising their surface activity

which favored their use for highly efficient fire-extinguishing towards flammable oils.

Abstract

Fluorosurfactants are the key ingredients in the formulations of aqueous film-forming foams (AFFFs) for extinguishing flammable liquids

thus developing high-efficient and low-toxic fluorosurfactants is desirable in AFFFs application. Herein

a series of hyperbranched polymeric fluorosurfactants (HPFs) were successfully synthesized through sequentially modifying hyperbranched polyethylenimine (PEI) with the hydrophilic poly(ethylene glycol) (PEG) chains and the hydrophobic C6/C4-based perfluoroalkyl chains

which were verified by FTIR

H- and

F-NMR. The surface tensions of all the HPFs in water were measured

and the corresponding physicochemical parameters were interpreted. It was found that the surface activities of HPFs could be tuned through adjusting the ratio of PEG to perfluoroalkyl chains

the length of perfluoroalkyl chains

the molecular weight of PEI core

but not the PEG chain length. In the binary mixture of HPFs with the commercial small molecule fluorosurfactant Capstone

1157 (C1157)

a strong synergism led to the elevation of surface activity

which was attributed to the efficient encapsulation of C1157 guests by the compact hyperbranched HPFs as the hosts. The utilization of HPF/C1157 as fluorosurfactant ingredients in AFFF formulations could realize much higher fire-extinguishing efficiency towards flammable oils than the control AFFFs prepared from the polymeric Capstone

1460 or the neat C1157.

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