Infrared Photodetectors and Image Arrays Made with Organic Semiconductors

Zhi-Ming Zhong; Feng Peng; Lei Ying; Zhen-Qiang Huang; Wen-Kai Zhong; Gang Yu; Yong Cao; Fei Huang

doi:10.1007/s10118-023-2973-8

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Infrared Photodetectors and Image Arrays Made with Organic Semiconductors

RESEARCH ARTICLE | Updated：2023-09-21

- Infrared Photodetectors and Image Arrays Made with Organic Semiconductors
- Infrared Photodetectors and Image Arrays Made with Organic Semiconductors
- 高分子科学（英文版） 2023年41卷第10期页码：1629-1637
- Affiliations：
  
  Institute of Polymer Optoelectronic Materials and Devices, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510640, China
- Author bio：
  
  msleiying@scut.edu.cn (L.Y.)
  gangyu@scut.edu.cn (G.Y.)
  msfhuang@scut.edu.cn (F.H.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. U21A6002 and 51933003) and the Basic and Applied Basic Research Major Program of Guangdong Province (No. 2019B030302007).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-023-2973-8.
- DOI：10.1007/s10118-023-2973-8
  中图分类号：
- 收稿：2023-01-31，
  
  修回：2023-2-24，
  
  录用：2023-2-27，
  
  网络首发：2023-04-18，
  
  纸质出版：2023-10-01
- Accepted：
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Zhong, Z. M.; Peng, F.; Ying, L.; Huang, Z. Q.; Zhong, W. K.; Yu, G.; Cao, Y.; Huang, F. Infrared photodetectors and image arrays made with organic semiconductors. Chinese J. Polym. Sci. 2023, 41, 1629–1637

Zhi-Ming Zhong, Feng Peng, Lei Ying, et al. Infrared Photodetectors and Image Arrays Made with Organic Semiconductors[J]. Chinese Journal of Polymer Science, 2023, 41(10): 1629-1637.
Zhong, Z. M.; Peng, F.; Ying, L.; Huang, Z. Q.; Zhong, W. K.; Yu, G.; Cao, Y.; Huang, F. Infrared photodetectors and image arrays made with organic semiconductors. Chinese J. Polym. Sci. 2023, 41, 1629–1637 DOI： 10.1007/s10118-023-2973-8.

Zhi-Ming Zhong, Feng Peng, Lei Ying, et al. Infrared Photodetectors and Image Arrays Made with Organic Semiconductors[J]. Chinese Journal of Polymer Science, 2023, 41(10): 1629-1637. DOI： 10.1007/s10118-023-2973-8.

摘要

Thin film photodiode based on narrow-bandgap polymer PPCPD achieved high detectivity and quantum efficiency and realized high pixel-density image arrays without pixel-level-patterning. Short-wavelength infrared imaging could be scanned and read out by a 1 × 256 linear array with 25 μm × 25 μm pixel pitch.

Abstract

Combining the strategies of introducing larger heteroatom

regio-regular backbone and extended branching position of side-chain

we developed polymer semiconductors (

PPCPD

) with narrow band-gap to construct the photosensing layer of thin-film photodiodes and image arrays. The spectral response of the resulting organic photodiodes spans from the near ultra-violet to short-wavelength infrared region. The performance of these short-wavelength infrared photodiodes in 900–1200 nm range achieved a level competitive with that of indium gallium arsenide-based inorganic crystalline detectors

exhibiting a specific detectivity of 5.55×10

Jones at 1.15 μm. High photodetectivity and quantum efficiency in photodiode with amorphous/nanocrystalline thin-films of 100−200 nm thickness enabled high pixel-density image arrays without pixel-level-patterning in the sensing layer. 1 × 256 linear diode arrays with 25 μm × 25 μm pixel pitch were achieved

enabling high pixel-density short-wavelength infrared imaging at room temperature.

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