Novel Quasi Solid-State Succinonitrile-based Electrolyte with Low-flammability for Lithium-ion Battery

Yan-Kun Xie; Lu-Kun Feng; Dong-Dong Li; Yin Tang; Cai-Zhen Zhu; Ming-Liang Wang; Jian Xu

doi:10.1007/s10118-023-2970-y

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Novel Quasi Solid-State Succinonitrile-based Electrolyte with Low-flammability for Lithium-ion Battery

RESEARCH ARTICLE | Updated：2023-11-10

- Novel Quasi Solid-State Succinonitrile-based Electrolyte with Low-flammability for Lithium-ion Battery
- Novel Quasi Solid-State Succinonitrile-based Electrolyte with Low-flammability for Lithium-ion Battery
- 高分子科学（英文版） 2023年41卷第11期页码：1695-1705
- Affiliations：
  
  Institute of Low-Dimensional Materials Genome Initiative, College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518060, China
- Author bio：
  
  czzhu@szu.edu.cn (C.Z.Z.)
  wangml@szu.edu.cn (M.L.W.)
  jxu@iccas.ac.cn (J.X.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 52003160 and 51973118), Guangdong Basic and Applied Basic Research Foundation (No. 2020A1515010644), Key-Area Research and Development Program of Guangdong Province (Nos. 2019B010929002 and 2019B010941001), the Science and Technology Innovation Commission of Shenzhen (No. JCYJ20190808150001775), the Program for Guangdong Introducing Innovative and Entrepreneurial Teams (No. 2019ZT08C642). And the authors would like to appreciate the help of MD simulations from the Wang-Mingliang Lab of Shenzhen University.;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-023-2970-y.
- DOI：10.1007/s10118-023-2970-y
  中图分类号：
- 收稿：2022-12-14，
  
  修回：2023-2-18，
  
  录用：2023-2-20，
  
  网络首发：2023-04-18，
  
  纸质出版：2023-11-01
- Accepted：
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Xie, Y. K.; Feng, L. K.; Li, D. D.; Tang, Y.; Zhu, C. Z.; Wang, M. L.; Xu, J. Novel quasi solid-state succinonitrile-based electrolyte with low-flammability for lithium-ion battery. Chinese J. Polym. Sci. 2023, 41, 1695–1705

Yan-Kun Xie, Lu-Kun Feng, Dong-Dong Li, et al. Novel Quasi Solid-State Succinonitrile-based Electrolyte with Low-flammability for Lithium-ion Battery[J]. Chinese Journal of Polymer Science, 2023, 41(11): 1695-1705.
Xie, Y. K.; Feng, L. K.; Li, D. D.; Tang, Y.; Zhu, C. Z.; Wang, M. L.; Xu, J. Novel quasi solid-state succinonitrile-based electrolyte with low-flammability for lithium-ion battery. Chinese J. Polym. Sci. 2023, 41, 1695–1705 DOI： 10.1007/s10118-023-2970-y.

Yan-Kun Xie, Lu-Kun Feng, Dong-Dong Li, et al. Novel Quasi Solid-State Succinonitrile-based Electrolyte with Low-flammability for Lithium-ion Battery[J]. Chinese Journal of Polymer Science, 2023, 41(11): 1695-1705. DOI： 10.1007/s10118-023-2970-y.

摘要

The SN-based electrolyte with low-flammability has been successfully through in-situ polymerization method. The as-prepared SN-based electrolyte exhibited good electrochemical performance and low-flammability.

Abstract

Quasi solid-state succinonitrile (SN)-based polymer electrolytes have emerged for lithium-metal batteries due to their excellent ion-conductivity at room temperature

wide electrochemical stability window (ESW

usually

5 V). However

the practical application of these solid SN-based polymer electrolytes is hampered by the flammability and the inherent instability of SN to Li-metal anode. In this work

solid SN-based polymer electrolytes were prepared with succinonitrile

ethoxylated trimethylolpropane triacrylate (ETPTA)

triethyl phosphate (TEP) and fluoroethylene carbonate for Li-metal battery

via

in situ

polymerization method. The SN-based polymer electrolytes with 5 wt% triethyl phosphate and FEC showed good nonflammability

superior ion-conductivity as high as 1.01×10

−3

S/cm

and wide ESW of 5.41 V. This SN-based polymer electrolyte also exhibited excellent interfacial compatibility to lithium metal anode. And it also delivered a high specific capacity of 156 mAh/g at 0.2 C at ambient temperature

and presented stable cycling at 1.0 C with a specific capacity retention of 98.4% after 1000 cycles. This work provides an alternative and simple strategy to realize the practical application of the solid-state SN-based polymer electrolyte.

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