3-Methylcyclohexanone Processed n-Channel Organic Thin-Film Transistors Based on a Conjugated Polymer Synthesized by Direct Arylation Polycondensation

Dong-Sheng Yan; Xu-Wen Zhang; Zhong-Li Wang; Chen-Hui Xu; Yi-Bo Shi; Yun-Feng Deng; Yang Han; Yan-Hou Geng

doi:10.1007/s10118-023-2937-z

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3-Methylcyclohexanone Processed n-Channel Organic Thin-Film Transistors Based on a Conjugated Polymer Synthesized by Direct Arylation Polycondensation

RESEARCH ARTICLE | Updated：2023-04-21

- 3-Methylcyclohexanone Processed n-Channel Organic Thin-Film Transistors Based on a Conjugated Polymer Synthesized by Direct Arylation Polycondensation
- 3-Methylcyclohexanone Processed n-Channel Organic Thin-Film Transistors Based on a Conjugated Polymer Synthesized by Direct Arylation Polycondensation
- 高分子科学（英文版） 2023年41卷第5期页码：824-831
- Affiliations：
  
  a.School of Materials Science and Engineering and Tianjin Key Laboratory of Molecular Optoelectronic Science, Tianjin University, and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, China
  b.State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin Key Laboratory of Advanced Fibers and Energy Storage, School of Material Science and Engineering, Tiangong University, Tianjin 300387, China
  c.Joint School of National University of Singapore and Tianjin University, International Campus of Tianjin University, Fuzhou 350207, China
- Author bio：
  
  zhongliwang@tiangong.edu.cn(Z.L.W.)
  yanhou.geng@tju.edu.cn (Y.H.G.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51933008 and 52121002) and the Fundamental Research Funds for the Central Universities.;Electronic supplementary information (ESI) is available free of charge in the online version of this article athttp://doi.org/10.1007/s10118-023-2937-z.
- DOI：10.1007/s10118-023-2937-z
  中图分类号：
- 收稿：2022-11-21，
  
  修回：2022-12-22，
  
  录用：2022-12-23，
  
  网络首发：2023-02-21，
  
  纸质出版：2023-05-01
- Accepted：
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Yan, D. S.; Zhang, X. W.; Wang, Z. L.; Xu, C. H.; Shi, Y. B.; Deng, Y. F.; Han, Y.; Geng, Y. H. 3-Methylcyclohexanone processed n-channel organic thin-film transistors based on a conjugated polymer synthesized by direct arylation polycondensation.Chinese J. Polym. Sci.2023,41, 824–831

Dong-Sheng Yan, Xu-Wen Zhang, Zhong-Li Wang, et al. 3-Methylcyclohexanone Processed n-Channel Organic Thin-Film Transistors Based on a Conjugated Polymer Synthesized by Direct Arylation Polycondensation[J]. Chinese Journal of Polymer Science, 2023, 41(5): 824-831.
Yan, D. S.; Zhang, X. W.; Wang, Z. L.; Xu, C. H.; Shi, Y. B.; Deng, Y. F.; Han, Y.; Geng, Y. H. 3-Methylcyclohexanone processed n-channel organic thin-film transistors based on a conjugated polymer synthesized by direct arylation polycondensation.Chinese J. Polym. Sci.2023,41, 824–831 DOI： 10.1007/s10118-023-2937-z.

Dong-Sheng Yan, Xu-Wen Zhang, Zhong-Li Wang, et al. 3-Methylcyclohexanone Processed n-Channel Organic Thin-Film Transistors Based on a Conjugated Polymer Synthesized by Direct Arylation Polycondensation[J]. Chinese Journal of Polymer Science, 2023, 41(5): 824-831. DOI： 10.1007/s10118-023-2937-z.

摘要

Direct arylation polycondensation synthesized conjugated polymer PFuDPP-4FTVT is soluble in 3-methylcyclohexanone (3-MC). n-Channel organic thin-film transistors of the polymer with electron mobility (

) above 1 cm

·V

−1

·s

−1

were fabricated with 3-MC. This is the first report on high mobility conjugated polymers processible with naturally occurred green solvent.

Abstract

The solubility of a direct arylation polycondensation (DArP) synthesized conjugated polymer

i.e.

poly(3

6-bis(furan-2-yl)-2

5-bis(4-tetradecyloctadecyl)-pyrrolo[3

]pyrrole-1

4(2

)-dione-

alt

-1

2-bis(3

4-difluorothien-2-yl)ethene) (PFuDPP-4FTVT)

in various organic solvents was studied. The polymer is soluble in 3-methylcyclohexanone (3-MC)

a green solvent from peppermint oil

besides other solvents such as anisole

cyclopentyl methyl ether (CPME) and

-dichlorobenzene (

-DCB)

etc

. Based on the Hansen solubility parameters (HSP) analysis

3-MC is identified as a “marginal solvent” of PFuDPP-4FTVT. The morphology of the spin-coated films with 3-MC as the solvent strongly correlated with the solution preparation conditions. With a 3-MC solution aged for 3 h at 70 °C

n-channel organic thin-film transistors (OTFTs) with electron mobility (

) above 1 cm

·V

−1

·s

−1

and current on/off ratio (

off

) higher than 10

were fabricated by spin-coating. This is the first report on high mobility conjugated polymers for OTFTs processible with naturally occurred green solvent.

关键词

Keywords

references

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