Asymmetric Mesoporous Carbon Microparticles by 3D-Confined Self-Assembly of Block Copolymer/Homopolymer Blends and Selective Carbonization

Jing-Ye Liu; Hao-Rui Song; Mian Wang; Shao-Hong Jin; Zheng Liang; Xi Mao; Wang Li; Ren-Hua Deng; Jin-Tao Zhu

doi:10.1007/s10118-023-2935-1

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Asymmetric Mesoporous Carbon Microparticles by 3D-Confined Self-Assembly of Block Copolymer/Homopolymer Blends and Selective Carbonization

RESEARCH ARTICLE | Updated：2023-04-21

- Asymmetric Mesoporous Carbon Microparticles by 3D-Confined Self-Assembly of Block Copolymer/Homopolymer Blends and Selective Carbonization
- Asymmetric Mesoporous Carbon Microparticles by 3D-Confined Self-Assembly of Block Copolymer/Homopolymer Blends and Selective Carbonization
- 高分子科学（英文版） 2023年41卷第5期页码：787-793
- Affiliations：
  
  State Key Laboratory of Materials Processing and Die & Mould Technology, Key Laboratory of Material Chemistry for Energy Conversion and Storage of Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
- Author bio：
  
  rhdeng@hust.edu.cn(R.H.D.)
  jtzhu@mail.hust.edu.cn(J.T.Z.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 52003094 and 52273010). We also acknowledge the HUST Analytical and Testing Center and the HUST Core Facilities of Life Sciences for providing characterization services. Prof. Jiang Gong is appreciated for his help in carbonization experiments.;Electronic supplementary information (ESI) is available free of charge in the online version of this article athttp://doi.org/10.1007/s10118-023-2935-1.
- DOI：10.1007/s10118-023-2935-1
  中图分类号：
- 收稿：2022-11-25，
  
  修回：2022-12-18，
  
  录用：2022-12-21，
  
  网络首发：2023-02-21，
  
  纸质出版：2023-05-01
- Accepted：
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Liu, J. Y.; Song, H. R.; Wang, M.; Jin, S. H.; Liang, Z.; Mao, X.; Li, W.; Deng, R. H.; Zhu, J. T. Asymmetric mesoporous carbon microparticles by 3D-confined self-assembly of block copolymer/homopolymer blends and selective carbonization.Chinese J. Polym. Sci.2023,41, 787–793

Jing-Ye Liu, Hao-Rui Song, Mian Wang, et al. Asymmetric Mesoporous Carbon Microparticles by 3D-Confined Self-Assembly of Block Copolymer/Homopolymer Blends and Selective Carbonization[J]. Chinese Journal of Polymer Science, 2023, 41(5): 787-793.
Liu, J. Y.; Song, H. R.; Wang, M.; Jin, S. H.; Liang, Z.; Mao, X.; Li, W.; Deng, R. H.; Zhu, J. T. Asymmetric mesoporous carbon microparticles by 3D-confined self-assembly of block copolymer/homopolymer blends and selective carbonization.Chinese J. Polym. Sci.2023,41, 787–793 DOI： 10.1007/s10118-023-2935-1.

Jing-Ye Liu, Hao-Rui Song, Mian Wang, et al. Asymmetric Mesoporous Carbon Microparticles by 3D-Confined Self-Assembly of Block Copolymer/Homopolymer Blends and Selective Carbonization[J]. Chinese Journal of Polymer Science, 2023, 41(5): 787-793. DOI： 10.1007/s10118-023-2935-1.

摘要

A method is developed to prepare asymmetric mesoporous carbon microparticles by neutral interface-guided 3D-confined self-assembly of block copolymer/homopolymer blends

followed by a self-templated selective direct carbonization strategy.

Abstract

Shape control of mesoporous carbon microparticles (MCMPs) is of critical importance; in particular

asymmetric shapes that can yield unique properties have attracted significant attention. However

the tailored synthesis of asymmetric MCMPs with ordered structures remains challenging. Herein

we report a facile route to prepare asymmetric MCMPs by dynamic neutral interface-guided 3D-confined self-assembly (3D-CSA) of block copolymer/homopolymer (BCP/

P) blends

followed by a self-templated selective direct carbonization strategy. BCP/

P Janus microparticles with ordered hierarchical mesostructures were prepared with emulsion solvent evaporation-induced 3D-CSA. The continuous phase of BCP domains was then crosslinked. Composite asymmetric MCMPs are successfully generated after selective carbonization of the crosslinked continuous phase. This method allows tuning the shape of MCMPs easily by varying the blending ratio of BCP/

P. The composite asymmetric MCMPs combine the advantages of asymmetric shape

ordered structure

high specific surface area

chemical inertness and thermal stability and could provide great possibilities for applications in catalysis

drug delivery

energy conversion and storage.

关键词

Keywords

references

Liu, J.; Wickramaratne, N. P.; Qiao, S. Z.; Jaroniec, M . Molecular-based design and emerging applications of nanoporous carbon spheres . Nat. Mater. , 2015 , 14 763 - 774 . DOI: 10.1038/nmat4317 http://doi.org/10.1038/nmat4317 .

Liu, J.; Qiao, S.Z.; Liu, H.; Chen, J.; Orpe, A.; Zhao, D.; Lu, G. Q . Extension of the Stöber method to the preparation of monodisperse resorcinol-formaldehyde resin polymer and carbon spheres . Angew. Chem. Int. Ed. , 2011 , 50 5947 - 5951 . DOI: 10.1002/anie.201102011 http://doi.org/10.1002/anie.201102011 .

Liu, C.; Yu, M. H.; Li, Y.; Li, J. S.; Wang, J.; Yu, C. Z.; Wang, L. J . Synthesis of mesoporous carbon nanoparticles with large and tunable pore sizes . Nanoscale , 2015 , 7 11580 - 11590 . DOI: 10.1039/C5NR02389K http://doi.org/10.1039/C5NR02389K .

Pan, P.; Zhang, T.; Yue, Q.; Elzatahry, A. A.; Alghamdi, A.; Cheng, X. W.; Deng, Y. H . Interface coassembly and polymerization on magnetic colloids: toward core-shell functional mesoporous polymer microspheres and their carbon derivatives . Adv. Sci. , 2020 , 7 2000443 DOI: 10.1002/advs.202000443 http://doi.org/10.1002/advs.202000443 .

Wang, C. W.; Wang, Y.; Graser, J.; Zhao, R.; Gao, F.; O’Connell, M. J . Solution-based carbohydrate synthesis of individual solid, hollow, and porous carbon nanospheres using spray pyrolysis . ACS Nano , 2013 , 7 11156 - 11165 . DOI: 10.1021/nn4048759 http://doi.org/10.1021/nn4048759 .

Han, X.; Zhang, T. Y.; Wang, X. H.; Zhang, Z. D.; Li, Y. P.; Qin, Y. J.; Wang, B. Q.; Han, A. J.; Liu, J. F . Hollow mesoporous atomically dispersed metal-nitrogen-carbon catalysts with enhanced diffusion for catalysis involving larger molecules . Nat. Commun. , 2022 , 13 2900 DOI: 10.1038/s41467-022-30520-3 http://doi.org/10.1038/s41467-022-30520-3 .

Fang, Y.; Zheng, G. F.; Yang, J. P.; Tang, H. S.; Zhang, Y. F.; Kong, B.; Lv, Y. Y.; Xu, C. J.; Asiri, A.M.; Zi, J.; Zhang, F.; Zhao, D. Y . Dual-pore mesoporous carbon@silica composite core-shell nanospheres for multidrug delivery . Angew. Chem. Int. Ed. , 2014 , 53 5366 - 5370 . DOI: 10.1002/anie.201402002 http://doi.org/10.1002/anie.201402002 .

Zhang, L. H.; He, B.; Li, W.C.; Lu, A.H . Surface free energy-induced assembly to the synthesis of grid-like multicavity carbon spheres with high level in-cavity encapsulation for lithium-sulfur cathode . Adv. Energy Mater. , 2017 , 7 1701518 DOI: 10.1002/aenm.201701518 http://doi.org/10.1002/aenm.201701518 .

Tang, J.; Wang, J.; Shrestha, L. K.; Hossain, M. S. A.; Alothman, Z. A.; Yamauchi, Y.; Ariga, K . Activated porous carbon spheres with customized mesopores through assembly of diblock copolymers for electrochemical capacitor . ACS Appl. Mater. Interfaces , 2017 , 9 18986 - 18993 . DOI: 10.1021/acsami.7b04967 http://doi.org/10.1021/acsami.7b04967 .

Schuster, J.; He, G.; Mandlmeier, B.; Yim, T.; Lee, K.T.; Bein, T.; Nazar, L.F . Spherical ordered mesoporous carbon nanoparticles with high porosity for lithium-sulfur batteries . Angew. Chem. Int. Ed. , 2012 , 51 3591 - 3595 . DOI: 10.1002/anie.201107817 http://doi.org/10.1002/anie.201107817 .

Fang, Y.; Gu, D.; Zou, Y.; Wu, Z. X.; Li, F. Y.; Che, R. C.; Deng, Y. H.; Tu, B.; Zhao, D. Y . A low-concentration hydrothermal synthesis of biocompatible ordered mesoporous carbon nanospheres with tunable and uniform size . Angew. Chem. Int. Ed. , 2010 , 49 7987 - 7991 . DOI: 10.1002/anie.201002849 http://doi.org/10.1002/anie.201002849 .

Liang, J.; Kou, H.; Ding, S. J . Complex hollow bowl-like nanostructures: synthesis, application, and perspective . Adv. Funct. Mater. , 2021 , 31 2007801 DOI: 10.1002/adfm.202007801 http://doi.org/10.1002/adfm.202007801 .

Ku, K. H.; Lee, Y. J.; Kim, Y. J.; Kim, B. J . Shape-anisotropic diblock copolymer particles from evaporative emulsions: experiment and theory . Macromolecules , 2019 , 52 1150 - 1157 . DOI: 10.1021/acs.macromol.8b02465 http://doi.org/10.1021/acs.macromol.8b02465 .

Kim, S. S.; Hwang, J. K.; Lee, J. S.; Lee, J. W . Polymer blend directed anisotropic self-assembly toward mesoporous inorganic bowls and nanosheets . Sci. Adv. , 2020 , 6 eabb3814 DOI: 10.1126/sciadv.abb3814 http://doi.org/10.1126/sciadv.abb3814 .

Peng, L.; Hung, C. T.; Wang, Zhang, X. M.; Zhu, X. H.; Zhao, Z. W.; Wang, C. Y.; Tang, Y.; Li, W.; Zhao, D. Y . Versatile nanoemulsion assembly approach to synthesize functional mesoporous carbon nanospheres with tunable pore sizes and architectures . J. Am. Chem. Soc. , 2019 , 141 7073 - 7080 . DOI: 10.1021/jacs.9b02091 http://doi.org/10.1021/jacs.9b02091 .

Liu, Y.; Wang, Z. R.; Teng, W.; Zhu, H. W.; Wang, J. X.; Elzatahry, A. A.; Al-Dahyan, D.; Li, W.; Deng, Y. H.; Zhao, D. Y . A template-catalyzed in situ polymerization and co-assembly strategy for rich nitrogen-doped mesoporous carbon . J. Mater. Chem. A , 2018 , 6 3162 - 3170 . DOI: 10.1039/C7TA10106F http://doi.org/10.1039/C7TA10106F .

Jiang, S. Q.; Li, C.; Zhang, J. C.; Li, Q.; Xu, H. S., Xu, F. G.; Mai, Y, Y . Block copolymer self-assembly guided synthesis of mesoporous carbons with in-plane holey pores for efficient oxygen reduction reaction . Macromol. Rapid Commun. , 2022 , 43 2100884 DOI: 10.1002/marc.202100884 http://doi.org/10.1002/marc.202100884 .

Hou, D.; Zhang, J. C.; Tian, H.; Li, Q.; Li, C.; Mai, Y. Y . Pore engineering of 2D mesoporous nitrogen-doped carbon on graphene through block copolymer self-assembly . Adv. Mater. Interfaces , 2019 , 6 1901476 DOI: 10.1002/admi.201901476 http://doi.org/10.1002/admi.201901476 .

Li, C.; Li, Q.; Kaneti, Y. V.; Hou, D.; Yamauchi, Y.; Mai, Y. Y . Self-assembly of block copolymers towards mesoporous materials for energy storage and conversion systems . Chem. Soc. Rev. , 2020 , 49 4681 - 4736 . DOI: 10.1039/D0CS00021C http://doi.org/10.1039/D0CS00021C .

He, T. X.; Wang, W. B.; Wang, J.; Chen, B. S.; Liang, Q. L . Mesoporous carbon spheres: synthesis and applications in drug delivery system . Prog. Chem. , 2020 , 32 309 - 319 .

Xu, M.; Yu, Q.; Liu, Z. H.; Lv, J. S.; Lian, S. T.; Hu, B.; Mai L. Q.; Zhou, L . Tailoring porous carbon spheres for supercapacitors . Nanoscale , 2018 , 10 21604 - 21616 . DOI: 10.1039/C8NR07560C http://doi.org/10.1039/C8NR07560C .

Tian, H.; Liang, J.; Liu, J . Nanoengineering carbon spheres as nanoreactors for sustainable energy applications . Adv. Mater. , 2019 , 31 1903886 DOI: 10.1002/adma.201903886 http://doi.org/10.1002/adma.201903886 .

Guan, B. Y.; Yu, L.; Lou, X. W . Formation of asymmetric bowl-like mesoporous particles via emulsion-induced interface anisotropic assembly . J. Am. Chem. Soc. , 2016 , 138 11306 - 11311 . DOI: 10.1021/jacs.6b06558 http://doi.org/10.1021/jacs.6b06558 .

Fang, Y.; Lv, Y. Y.; Gong, F.; Wu, Z. X.; Li, X. M.; Zhu, H. W.; Zhou, L.; Yao, C.; Zhang, F.; Zheng, G. F.; Zhao, D. Y . Interface tension-induced synthesis of monodispersed mesoporous carbon hemispheres . J. Am. Chem. Soc. , 2015 , 137 2808 - 2811 . DOI: 10.1021/jacs.5b01522 http://doi.org/10.1021/jacs.5b01522 .

Deng, R. H.; Liang, F. X.; Zhou, P.; Zhang, C. L.; Qu, X. Z.; Wang, Q.; Li, J. L.; Zhu, J. T.; Yang, Z. Z . Janus nanodisc of diblock copolymers . Adv. Mater. , 2014 , 26 4469 - 4472 . DOI: 10.1002/adma.201305849 http://doi.org/10.1002/adma.201305849 .

Deng, R. H.; Liang, F. X.; Li, W. K.; Yang, Z. Z.; Zhu, J. T . Reversible transformation of nanostructured polymer particles . Macromolecules , 2013 , 46 7012 - 7017 . DOI: 10.1021/ma401398h http://doi.org/10.1021/ma401398h .

Deng, R. H.; Xu, J. P.; Yi, G.-R.; Kim, J. W.; Zhu, J. T . Responsive colloidal polymer particles with ordered mesostructures . Adv. Funct. Mater. , 2021 , 31 2008169 DOI: 10.1002/adfm.202008169 http://doi.org/10.1002/adfm.202008169 .

Ku, K. H.; Ryu, J. H.; Kim, J.; Yun, H.; Nam, C.; Shin, J. M.; Kim, Y.; Jang, S. G.; Lee, W. B.; Kim, B. J . Mechanistic study on the shape transition of block copolymer particles driven by length-controlled nanorod surfactants . Chem. Mater. , 2018 , 30 8669 - 8678 . DOI: 10.1021/acs.chemmater.8b04020 http://doi.org/10.1021/acs.chemmater.8b04020 .

Yan, N.; Zhu, Y. T.; Jiang, W . Recent progress in the self-assembly of block copolymers confined in emulsion droplets . Chem. Commun. , 2018 , 54 13183 - 13195 . DOI: 10.1039/C8CC05812A http://doi.org/10.1039/C8CC05812A .

Wong, C. K.; Qiang, X. L.; Müller, A. H. E.; Gröschel, A. H . Self-assembly of block copolymers into internally ordered microparticles . Prog. Polym. Sci. , 2020 , 102 101211 DOI: 10.1016/j.progpolymsci.2020.101211 http://doi.org/10.1016/j.progpolymsci.2020.101211 .

Xu, J. P.; Zhu, J. T . Block copolymer colloidal particles with unique structures through three-dimensional confined assembly and disassembly . Chinese J. Polym. Sci. , 2019 , 37 744 - 759 . DOI: 10.1007/s10118-019-2294-0 http://doi.org/10.1007/s10118-019-2294-0 .

Deng, R. H.; Zheng, L. F.; Mao, X.; Li, B. H.; Zhu, J. T . Transformable colloidal polymer particles with ordered internal structures . Small , 2021 , 17 2006132 DOI: 10.1002/smll.202006132 http://doi.org/10.1002/smll.202006132 .

Hu, D. W.; Chang, X. H.; Xu, Y. Q.; Yu, Q. L.; Zhu, Y, T . Light-enabled reversible shape transformation of block copolymer particles . ACS Macro Lett. , 2021 , 10 914 - 920 . DOI: 10.1021/acsmacrolett.1c00356 http://doi.org/10.1021/acsmacrolett.1c00356 .

Yan, N.; Liu, X. J.; Zhu, J. T.; Zhu, Y. T.; Jiang, W . Well-ordered inorganic nanoparticle arrays directed by block copolymer nanosheets . ACS Nano , 2019 , 13 6638 - 6646 . DOI: 10.1021/acsnano.9b00940 http://doi.org/10.1021/acsnano.9b00940 .

He, Y.; Zhang, Y.; Yan, N.; Zhu, Y. T.; Jiang, W.; Shi, D. A . Self-assembly of block copolymers into sieve-like particles with arrayed switchable channels and as scaffolds to guide the arrangement of gold nanoparticles . Nanoscale , 2017 , 9 15056 - 15061 . DOI: 10.1039/C7NR04923D http://doi.org/10.1039/C7NR04923D .

Zhang, Q. Y.; Fan, H. L.; Zhang, L.; Jin, Z. X . Nanodiscs generated from the solvent exchange of a block copolymer . Macromolecules , 2020 , 53 7025 - 7033 . DOI: 10.1021/acs.macromol.0c01185 http://doi.org/10.1021/acs.macromol.0c01185 .

Jin, Z. X.; Fan, H. L . Self-assembly of nanostructured block copolymer nanoparticles . Soft Matter , 2014 , 10 9212 - 9219 . DOI: 10.1039/C4SM02064B http://doi.org/10.1039/C4SM02064B .

Fan, H. L.; Jin, Z. X . Freezing polystyrene- b -poly(2-vinylpyridine) micelle nanoparticles with different nanostructures and sizes . Soft Matter , 2014 , 10 2848 - 2855 . DOI: 10.1039/c3sm53049c http://doi.org/10.1039/c3sm53049c .

Dai, X. Z.; Qiang, X. L.; Hils, C.; Schmalz, H.; Gröschel, A. H . Frustrated microparticle morphologies of a semicrystalline triblock terpolymer in 3D soft confinement . ACS Nano , 2021 , 15 1111 - 1120 . DOI: 10.1021/acsnano.0c08087 http://doi.org/10.1021/acsnano.0c08087 .

Qiang, X. L.; Franzka, S.; Dai, X. Z.; Gröschel, A. H . Multicompartment microparticles of SBT triblock terpolymers through 3D confinement assembly . Macromolecules , 2020 , 53 4224 - 4233 . DOI: 10.1021/acs.macromol.0c00806 http://doi.org/10.1021/acs.macromol.0c00806 .

Navarro, L.; Thünemann, A. F.; Yokosawa, T.; Spiecker, E.; Klinger, D . Regioselective seeded polymerization in block copolymer nanoparticles: post-assembly control of colloidal features . Angew. Chem. Int. Ed. , 2022 , 61 e202208084 .

Navarro, L.; Thünemann, A. F.; Klinger, D . Solvent annealing of striped ellipsoidal block copolymer particles: reversible control over lamellae asymmetry, aspect ratio, and particle surface . ACS Macro Lett. , 2022 , 11 329 - 335 . DOI: 10.1021/acsmacrolett.1c00665 http://doi.org/10.1021/acsmacrolett.1c00665 .

Cui, T. T.; Li, X. Y.; Dong, B.; Li, X.; Guo, M. X.; Wu, L. X.; Li, B. H.; Li, H. L . Janus onions of block copolymers via confined self-assembly . Polymer , 2019 , 174 70 - 76 . DOI: 10.1016/j.polymer.2019.04.062 http://doi.org/10.1016/j.polymer.2019.04.062 .

Li, Y. L.; Song, D. P.; Li, Y. S . Preparation of stimuli-responsive structural colored porous microspheres via emulsion self-assembly induced by bottlebrush triblock copolymers . Acta Polymerica Sinica (in Chinese) , 2021 , 52 1591 - 1602 .

Zhao, K. J.; Gao, Z. L.; Song, D. P.; Zhang, P. Y.; Cu, J. W . Assembly of catechol-modified polymer brushes for drug delivery . Polym. Chem. , 2022 , 13 373 - 378 . DOI: 10.1039/D1PY00947H http://doi.org/10.1039/D1PY00947H .

Shin, J. J.; Kim, E. J.; Ku, K. H.; Lee, Y. J.; Hawker, C. J.; Kim, B. J. 100 th Anniversary of macromolecular science viewpoint: block copolymer particles: tuning shape, interfaces, and morphology. ACS Macro Lett . 2020 , 9 , 306–317.

Ku, K. H.; Shin, J. M.; Yun, H.; Yi, G. R.; Jang, S. G.; Kim, B. J . Multidimensional design of anisotropic polymer particles from solvent-evaporative emulsion . Adv. Funct. Mater. , 2018 , 28 1802961 DOI: 10.1002/adfm.201802961 http://doi.org/10.1002/adfm.201802961 .

Hwang, J.; Kim, S.; Wiesner, U.; Lee, J . Generalized access to mesoporous inorganic particles and hollow spheres from multicomponent polymer blends . Adv. Mater. , 2018 , 30 1801127 DOI: 10.1002/adma.201801127 http://doi.org/10.1002/adma.201801127 .

Wang, M.; Mao, X.; Liu, J. Y.; Deng, B. T.; Deng, S.; Jin, S. H.; Li, W.; Gong, J.; Deng, R. H.; Zhu, J. T . A versatile 3D-confined self-assembly strategy for anisotropic and ordered mesoporous carbon microparticles . Adv. Sci. , 2022 : 2202394 .

Lee, Y. J.; Kim, H. E.; Oh, H.; Yun, H.; Lee, J.; Shin, S.; Lee, H. J.; Kim, B. J . Lens-shaped carbon particles with perpendicularly-oriented channels for high-performance proton exchange membrane fuel cells . ACS Nano , 2022 , 16 2988 - 2996 . DOI: 10.1021/acsnano.1c10280 http://doi.org/10.1021/acsnano.1c10280 .

Deng, R. H.; Liu, S. Q.; Liang, F. X.; Wang, K.; Zhu, J. T.; Yang, Z. Z . Polymeric Janus particles with hierarchical structures . Macromolecules , 2014 , 47 3701 - 3707 . DOI: 10.1021/ma500331w http://doi.org/10.1021/ma500331w .

Zhang, J.; Kong, W. X.; Duan, H. M . Soft confinement-induced morphologies of the blends of AB diblock copolymers and C homopolymers . Langmuir , 2017 , 33 3123 - 3133 . DOI: 10.1021/acs.langmuir.7b00181 http://doi.org/10.1021/acs.langmuir.7b00181 .

Yang, R. Q.; Li, B. H.; Shi, A. C . Phase behavior of binary blends of diblock copolymer/homopolymer confined in spherical nanopores . Langmuir , 2012 , 28 1569 - 1578 . DOI: 10.1021/la204449x http://doi.org/10.1021/la204449x .

Kim, E. J.; Shin, J. M.; Kim, Y. J.; Ku, K. H.; Yun, H.; Kim, B. J . Shape control of nanostructured cone-shaped particles by tuning the blend morphology of A- b -B diblock copolymers and C-type copolymers within emulsion droplets . Polym. Chem. , 2019 , 10 2415 - 2423 . DOI: 10.1039/C9PY00306A http://doi.org/10.1039/C9PY00306A .

Ikkala, O.; ten Brinke, G . Functional materials based on self-assembly of polymeric supramolecules . Science , 2002 , 295 2407 - 2409 . DOI: 10.1126/science.1067794 http://doi.org/10.1126/science.1067794 .

Deng, S.; Deng, R. H.; Mao, X.; Xiong, B. J.; Wang, M.; Chen, S. B.; Binder, W. H.; Zhu, J. T.; Yang, Z. Z. . Kinetically controlled supramolecular block copolymer self-assembly: multicolor photonic crystal patterns from a single formulation . CCS Chem. , 2022 : DOI: 10.31635/ccschem.022.202202530 DOI: 10.31635/ccschem.022.202202530 http://doi.org/10.31635/ccschem.022.202202530 .

Brandrup, J., Immergut, E. H., Grulke, E. A., Eds.; Polymer Handbook ; Wiley: New York, 1999 ; Section VII, pp. 675−714.

Drelinkiewicz, A.; Sobczak, J.W.; Sobczak, E.; Krawczyk, M.; Zięba, A.; WaksmundzkaGóra, A . Physicochemical and catalytic properties of Pt-poly(4-vinylpyridine) composites . Mater. Chem. Phys. , 2009 , 114 763 - 773 . DOI: 10.1016/j.matchemphys.2008.10.028 http://doi.org/10.1016/j.matchemphys.2008.10.028 .

Deng, R. H.; Liang, F. X.; Li, W. K.; Liu, S. Q.; Liang, R. J.; Cai, M. L.; Yang, Z. Z.; Zhu, J. T . Shaping functional nano-objects by 3D confined supramolecular assembly . Small , 2013 , 9 4099 - 4103 . DOI: 10.1002/smll.201300271 http://doi.org/10.1002/smll.201300271 .

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