Matrix Effect on Polydiarylfluorenes Electrospun Hybrid Microfibers: From Morphology Tuning to High Explosive Detection Efficiency

Wei Xue; Man Xu; Chuan-Xin Wei; Hua-Min Sun; Li-Li Sun; Sheng-Jie Wang; Jin-Yi Lin; Nai-En Shi; Ling-Hai Xie; Wei Huang

doi:10.1007/s10118-023-2927-1

Your Location：

Home >

Browse articles >

Matrix Effect on Polydiarylfluorenes Electrospun Hybrid Microfibers: From Morphology Tuning to High Explosive Detection Efficiency

RESEARCH ARTICLE | Updated：2023-06-14

- Matrix Effect on Polydiarylfluorenes Electrospun Hybrid Microfibers: From Morphology Tuning to High Explosive Detection Efficiency
  Enhanced Publication
- Matrix Effect on Polydiarylfluorenes Electrospun Hybrid Microfibers: From Morphology Tuning to High Explosive Detection Efficiency
- 高分子科学（英文版） 2023年41卷第7期页码：1011-1017
- Affiliations：
  
  a.State Key Laboratory of Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications, Nanjing 210023, China
  b.Center for Supramolecular Optoelectronics (CSO), Key Laboratory of Flexible Electronics (KLOFE) and Institute of Advanced Materials (IAM), Nanjing Tech University (NanjingTech), Nanjing 211816, China
  c.Frontiers Science Center for Flexible Electronics (FSCFE), Shaanxi Institute of Flexible Electronics (SIFE) & Shaanxi Institute of Biomedical Materials and Engineering (SIBME), Northwestern Polytechnical University (NPU), Xi'an 710072, China
- Author bio：
  
  iamjylin@njtech.edu.cn (J.Y.L.)
  iamneshi@njupt.edu.cn (N.E.S.)
  wei-huang@njtech.edu.cn (W.H.)
- Funds：
  
  The work was financially supported by the National Natural Science Foundation of China (Nos. 22075136 and 61874053), the open research fund from Anhui Province Key Laboratory of Environment-friendly Polymer Materials, Anhui Province Key Laboratory of Optoelectronic Materials Science and Technology, and the State Key Laboratory of Luminescent Materials and Devices (South China University of Technology).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-023-2927-1.
- DOI：10.1007/s10118-023-2927-1
  中图分类号：
Scan for full text
Matrix Effect on Polydiarylfluorenes Electrospun Hybrid Microfibers: From Morphology Tuning to High Explosive Detection Efficiency[J]. 高分子科学（英文版）, 2023,41(7):1011-1017.

Wei Xue, Man Xu, Chuan-Xin Wei, et al. Matrix Effect on Polydiarylfluorenes Electrospun Hybrid Microfibers: From Morphology Tuning to High Explosive Detection Efficiency[J]. Chinese Journal of Polymer Science, 2023,41(7):1011-1017.
Matrix Effect on Polydiarylfluorenes Electrospun Hybrid Microfibers: From Morphology Tuning to High Explosive Detection Efficiency[J]. 高分子科学（英文版）, 2023,41(7):1011-1017. DOI： 10.1007/s10118-023-2927-1.

Wei Xue, Man Xu, Chuan-Xin Wei, et al. Matrix Effect on Polydiarylfluorenes Electrospun Hybrid Microfibers: From Morphology Tuning to High Explosive Detection Efficiency[J]. Chinese Journal of Polymer Science, 2023,41(7):1011-1017. DOI： 10.1007/s10118-023-2927-1.

摘要

A flexible polyethylene oxide (PEO)are introduced as the supramolecular matrix to obtain a series of polydiarylfluorenes electrospun hybrid microfibers toward the highly sensitive for detecting explosives, associated with the synergistic effect of β-conformation formation, high deep-blue emission efficiency and surface morphology of ES fibers.

Abstract

Precisely optimizing the morphology of functional hybrid polymeric systems is crucial to improve its photophysical property and further extend their optoelectronic applications. The physic-chemical property of polymeric matrix in electrospinning (ES) processing is a key factor to dominate the condensed structure of these hybrid microstructures and further improve its functionality. Herein, we set a flexible poly(ethylene oxide) (PEO) as the matrix to obtain a series of polydiarylfluorenes (including PHDPF, PODPF and PNDPF) electrospun hybrid microfibers with a robust deep-blue emission. Significantly different from the rough morphology of their poly(,N,-vinylcarbazole) (PVK) ES hybrid fibers, polydiarylfluorenes/PEO ES fibers showed a smooth morphology and small size with a diameter of 1~2 μm. Besides, there is a relatively weak phase separation under rapid solvent evaporation during the ES processing, associated with the hydrogen-bonded-assisted network of PEO in ES fibers. These relative “homogeneous” ES fibers present efficient deep-blue emission (PLQY,>,50%), due to weak interchain aggregation. More interestingly, low fraction of planar (,β,) conformation appears in the uniform PODPF/PEO ES fibers, induced by the external traction force in ES processing. Meanwhile, PNDPF/PEO ES fibers present a highest sensitivity than those of other ES fibers, associated with the smallest diameter and large surface area. Finally, compared to PODPF/PVK fibers and PODPF/PEO amorphous ES fibers, PODPF/PEO ES fibers obtained from DCE solution exhibit an excellent quenching behavior toward a saturated DNT vapor, mainly due to the synergistic effect of small size, weak separation,β,-conformation formation and high deep-blue emission efficiency.

关键词

Keywords

Matrix effectElectrospun fibersPolydiarylfluorenesPlanar conformationExplosive detection

references

Bai,L.;Han,Y.;Lin,J.;Xie,L.;Huang,W.Intrinsicallystretchableconjugatedpolymersforflexibleoptoelectronicdevices.Sci. Bull.2021,66,2162−2164..

Burroughes,J.H.;Bradley,D.D.C.;Brown,A.R.;Marks,R.N.;Mackay,K.;Friend,R.H.;Burns,P.L.;Holmes,A.B.Light-emittingdiodesbasedonconjugatedpolymers.Nature1990,347,539−541..

Ling,H.;Liu,S.;Zheng,Z.;Yan,F.Organicflexibleelectronics.Small Meth.2018,2,1800070..

Oh,J.Y.;Rondeau-Gagné,S.;Chiu,Y.-C.;Chortos,A.;Lissel,F.;Wang,G.J.N.;Schroeder,B.C.;Kurosawa,T.;Lopez,J.;Katsumata,T.;Xu,J.;Zhu,C.;Gu,X.;Bae,W.G.;Kim,Y.;Jin,L.;Chung,J.W.;Tok,J.B.H.;Bao,Z.Intrinsicallystretchableandhealablesemiconductingpolymerfororganictransistors.Nature2016,539,411−415..

Swager,T.Polymerlight-emittingdevices-lightfrominsulatedorganicwires.Nat. Mater.2002,1,151−152..

White,M.S.;Kaltenbrunner,M.;Głowacki,E.D.;Gutnichenko,K.;Kettlgruber,G.;Graz,I.;Aazou,S.;Ulbricht,C.;Egbe,D.A.M.;Miron,M.C.;Major,Z.;Scharber,M.C.;Sekitani,T.;Someya,T.;Bauer,S.;Sariciftci,N.S.Ultrathin,highlyflexibleandstretchablePLEDs.Nat. Photon.2013,7,811..

Zhang,Z.;Guo,K.;Li,Y.;Li,X.;Guan,G.;Li,H.;Luo,Y.;Zhao,F.;Zhang,Q.;Wei,B.;Pei,Q.;Peng,H.Acolour-tunable,weavablefibre-shapedpolymerlight-emittingelectrochemicalcell.Nat. Photon.2015,9,233..

Yokota,T.;Zalar,P.;Kaltenbrunner,M.;Jinno,H.;Matsuhisa,N.;Kitanosako,H.;Tachibana,Y.;Yukita,W.;Koizumi,M.;Someya,T.Ultraflexibleorganicphotonicskin.Sci. Adv.2016,2,e1501856..

Liang,A.-H.;Zhang,K.;Zhang,J.;Huang,F.;Zhu,X.H.;Cao,Y.Supramolecularphosphorescentpolymeriridiumcomplexesforhigh-efficiencyorganiclight-emittingdiodes.Chem. Mater.2013,25,1013−1019..

Bai,L.;Han,Y.;Sun,C.;An,X.;Wei,C.;Liu,W.;Xu,M.;Sun,L.;Sun,N.;Yu,M.;Zhang,H.;Wei,Q.;Xu,C.;Yang,Y.;Qin,T.;Xie,L.;Lin,J.;Huang,W.Unveilingtheeffectsofinterchainhydrogenbondsonsolutiongelationandmechanicalpropertiesofdiarylfluorene-basedsemiconductorpolymers.Research2020,2020,3405826..

Zhou,K.;Dai,K.;Liu,C.;Shen,C.Flexibleconductivepolymercompositesforsmartwearablestrainsensors.SmartMat2020,1,e1010..

Huang,W.;Meng,H.;Yu,W.L.;Gao,J.;Heeger,A.J.Anewbluelight-emittingpolymercontainingsubstitutedthiopheneandanarylene-1,3,4-oxadiazolemoiety.Adv. Mater.1998,10,593−596..

Yu,W.L.;Meng,H.;Pei,J.;Huang,W.Tuningredoxbehaviorandemissivewavelengthofconjugatedpolymersbyp-ndiblockstructures.J. Am. Chem. Soc.1998,120,11808−11809..

Heeger,A.J.Semiconductingandmetallicpolymers:thefourthgenerationofpolymericmaterials(NobelLecture).Angew. Chem. Int. Ed.2001,40,2591−2611..

Yao,Y.;Chen,Y.;Wang,H.;Samorì,P.Organicphotodetectorsbasedonsupramolecularnanostructures.SmartMat2020,1,e1009..

Xie,L.H.;Yin,C.R.;Lai,W.Y.;Fan,Q.L.;Huang,W.Polyfluorene-basedsemiconductorscombinedwithvariousperiodictableelementsfororganicelectronics.Prog. Polym. Sci.2012,37,1192−1264..

Kim,B.-G.;Jeong,E.J.;Chung,J.W.;Seo,S.;Koo,B.;Kim,J.Amoleculardesignprincipleoflyotropicliquid-crystallineconjugatedpolymerswithdirectedalignmentcapabilityforplasticelectronics.Nat. Mater.2013,12,659−664..

Facchetti,A.Madetoorder.Nat. Mater.2013,12,598−600..

Diao,Y.;Tee,B.C.K.;Giri,G.;Xu,J.;Kim,D.H.;Becerril,H.A.;Stoltenberg,R.M.;Lee,T.H.;Xue,G.;Mannsfeld,S.C.B.;Bao,Z.Solutioncoatingoflarge-areaorganicsemiconductorthinfilmswithalignedsingle-crystallinedomains.Nat. Mater.2013,12,665−671..

Treat,N.D.;NekudaMalik,J.A.;Reid,O.;Yu,L.;Shuttle,C.G.;Rumbles,G.;Hawker,C.J.;Chabinyc,M.L.;Smith,P.;Stingelin,N.Microstructureformationinmolecularandpolymersemiconductorsassistedbynucleationagents.Nat. Mater.2013,12,628−633..

Venkateshvaran,D.;Nikolka,M.;Sadhanala,A.;Lemaur,V.;Zelazny,M.;Kepa,M.;Hurhangee,M.;Kronemeijer,A.J.;Pecunia,V.;Nasrallah,I.;Romanov,I.;Broch,K.;McCulloch,I.;Emin,D.;Olivier,Y.;Cornil,J.;Beljonne,D.;Sirringhaus,H.Approachingdisorder-freetransportinhigh-mobilityconjugatedpolymers.Nature2014,515,384−388..

Spano,F.C.;Silva,C.H-andJ-aggregatebehaviorinpolymericsemiconductors.Annu. Rev. Phys. Chem.2014,65,477−500..

Hoeben,F.J.M.;Jonkheijm,P.;Meijer,E.W.;Schenning,A.Aboutsupramolecularassembliesofpi-conjugatedsystems.Chem. Rev.2005,105,1491−1546..

Haedler,A.T.;Klaus,K.;Abey,I.;Bernd,W.;Milan,K.;Natalie,H.;Jürgen,K.;Hans-Werner,S.;Richard,H.Long-rangeenergytransportinsinglesupramolecularnanofibresatroomtemperature.Nature2018,523,196−199..

Noriega,R.;Rivnay,J.;Vandewal,K.;Koch,F.P.V.;Stingelin,N.;Smith,P.;Toney,M.F.;Salleo,A.Ageneralrelationshipbetweendisorder,aggregationandchargetransportinconjugatedpolymers.Nat. Mater.2013,12,1038..

Dong,H.;Hu,W.Multilevelinvestigationofchargetransportinconjugatedpolymers.Acc. Chem. Res.2016,49,2435−2443..

Heeger,A.J.Semiconductingpolymers:theThirdGeneration.Chem. Soc. Rev.2010,39,2354−2371..

Wang,Y.;Yang,J.;Gong,Y.;Fang,M.;Li,Z.;Tang,B.Z.Host-guestmaterialswithroomtemperaturephosphorescence:tunableemissioncolorandthermalprintingpatterns.SmartMat2020,1,e1006..

Zhang,X.;Hu,Q.;Lin,J.;Lei,Z.;Guo,X.;Xie,L.;Lai,W.;Huang,W.Efficientandstabledeepbluepolymerlight-emittingdevicesbasedonβ-phasepoly(9,9-dioctylfluorene).Appl. Phys. Lett.2013,103,153301..

Xu,M.;Yu,M.;Liu,B.;Lin,J.;Soleimaninejad,H.;Smith,T.A.;Ding,X.;Bai,L.;Han,Y.;Xie,L.;Liu,W.;Ghiggino,K.P.;Lin,Z.;Yu,T.;Xu,C.;Huang,W.Hierarchicaluniformcrystallinenanowiresofwidebandgapconjugatedpolymerforlight-emittingoptoelectronicdevices.Cell Rep. Phys. Sci.2020,1,100029..

Yu,M.N.;Lin,J.Y.;Li,Y.X.;Soleimaninejad,H.;Ou,C.J.;Bai,L.B.;Liu,B.;Liu,W.;Wei,Q.;Bo,Y.F.;Smith,T.A.;Dunstan,D.E.;Ghiggino,K.P.;Xie,L.H.;Xu,C.X.;Bradley,D.D.C.;Huang,W.Emissionenhancedandstabilizedbystereoisomericstrategyinhierarchicaluniformsupramolecularframework.Chem2019,5,2470−2483..

Ou,C.;Cheetham,N.J.;Weng,J.;Yu,M.;Lin,J.;Wang,X.;Sun,C.;Cabanillas-Gonzalez,J.;Xie,L.;Bai,L.;Han,Y.;Bradley,D.D.C.;Huang,W.Hierarchicaluniformsupramolecularconjugatedspheruliteswithsuppressionofdefectemission.iScience2019,16,399−411..

Hao,X.-T.;McKimmie,L.J.;Smith,T.A.Spatialfluorescenceinhomogeneitiesinlight-emittingconjugatedpolymerfilms.J. Phys. Chem. Lett.2011,2,1520−1525..

Shaw,P.E.;Ruseckas,A.;Peet,J.;Bazan,G.C.;Samuel,I.D.W.Exciton-excitonannihilationinmixed-phasepolyfluorenefilms.Adv. Funct. Mater.2010,20,155−161..

Yang,F.;Sun,L.;Duan,Q.;Dong,H.;Jing,Z.;Yang,Y.;Li,R.;Zhang,X.;Hu,W.;Chua,L.Vertical-organic-nanocrystal-arraysforcrossbarmemristorswithtuningswitchingdynamicstowardneuromorphiccomputing.SmartMat2021,2,99−108..

Ding,X.H.;Chang,Y.Z.;Ou,C.J.;Lin,J.Y.;Xie,L.H.;Huang,W.Halogenbondingintheco-crystallizationofpotentiallyditopicdiiodotetrafluorobenzene:apowerfultoolforconstructingmulticomponentsupramolecularassemblies.Natl. Sci. Rev.2020,7,1906−1932..

He,B.;Li,J.;Bo,Z.;Huang,Y.Highlypolarizedblueluminescencefromtheorientedpoly(9,9-dioctylfluorene)/polyethyleneblendingfilms.Macromolecules2005,38,6762−6766..

Podzorov,V.Conjugatedpolymers:Longandwindingpolymericroads.Nat. Mater.2013,12,947−948..

Camposeo,A.;Persano,L.;Pisignano,D.Light-emittingelectrospunnanofibersfornanophotonicsandoptoelectronics.Macromol. Mater. Eng.2013,298,487−503..

Xue,W.;Xu,M.;Yu,M.N.;Sun,H.M.;Lin,J.Y.;Jiang,R.C.;Xie,L.H.;Shi,N.E.;Huang,W.Electrospunsupramolecularhybridmicrofibersfromconjugatedpolymers:colortransformationandconductivityevolution.Chinese J. Polym. Sci.2021,39,824−830..

Xue,W.;Lin,J.Y.;Liu,B.;Shi,N.E.;Yu,M.N.;Wu,W.D.;Zhu,W.S.;Xie,L.H.;Wang,L.H.;Huang,W.Exploringside-chainlengtheffectonβ-phaseofpolyfluorenederivativesinelectrospinningandtheiropticalbehavior.Polymer2018,153,338−343..

Vohra,V.;Giovanella,U.;Tubino,R.;Murata,H.;Botta,C.Electroluminescencefromconjugatedpolymerelectrospunnanofibersinsolutionprocessableorganiclight-emittingdiodes.ACS Nano2011,5,5572−5578..

Agarwal,S.;Greiner,A.;Wendorff,J.H.Functionalmaterialsbyelectrospinningofpolymers.Prog. Polym. Sci.2013,38,963−991..

Xie,Z.;Xie,K.;Hu,T.;Ma,J.;Zhang,J.;Ma,R.;Cheng,X.;Li,J.;Hu,Z.Multi-wavelengthcoherentrandomlaserinbio-microfibers.Opt. Express2020,28,5179−5188..

Xie,L.H.;Yang,S.H.;Lin,J.Y.;Yi,M.D.;Huang,W.Fluorene-basedmacromolecularnanostructuresandnanomaterialsfororganic(opto)electronics.Philosophical Transactions of the Royal Society a-Mathematical Physical and Engineering Sciences2012,371,20120337..

Scherf,U.;List,E.J.W.Semiconductingpolyfluorenes—towardsreliablestructure-propertyrelationships.Adv. Mater.2002,14,477−487..

Xie,L.H.;Ling,Q.D.;Hou,X.Y.;Huang,W.AneffectiveFriedel-Craftspostfunctionalizationofpoly(N-vinylcarbazole)totunecarriertransportationofsupramolecularorganicsemiconductorsbasedonpi-stackedpolymersfornonvolatileflashmemorycell.J. Am. Chem. Soc.2008,130,2120−2121..

An,X.;Liu,W.;Bai,L.B.;Sun,L.L.;Xu,M.;Xie,L.H.;Song,L.;Xu,C.X.;Yang,Y.G.;Liu,B.;Lin,J.Y.;Huang,W.Long-rangeorderedhierarchicalstructureassistedbytheside-oligoethernetworkinlight-emittingconjugatedpolymerforanefficientdeep-blueorganiclaser.Chem. Mater.2021,33,5326−5336..

Lin,J.;Liu,B.;Yu,M.;Wang,X.;Lin,Z.;Zhang,X.;Sun,C.;Cabanillas-Gonzalez,J.;Xie,L.;Liu,F.;Ou,C.;Bai,L.;Han,Y.;Xu,M.;Zhu,W.;Smith,T.A.;Stavrinou,P.N.;Bradley,D.D.C.;Huang,W.Ultrastablesupramolecularself-encapsulatedwide-bandgapconjugatedpolymersforlarge-areaandflexibleelectroluminescentdevices.Adv. Mater.2019,31,1804811..

Lin,Z.Q.;Shi,N.E.;Li,Y.B.;Qiu,D.;Zhang,L.;Lin,J.Y.;Zhao,J.F.;Wang,C.;Xie,L.H.;Huang,W.Preparationandcharacterizationofpolyfluorene-basedsupramolecularπ-conjugatedpolymergels.J. Phys. Chem. C2011,115,4418−4424..

Bai,L.;Liu,B.;Han,Y.;Yu,M.;Wang,J.;Zhang,X.;Ou,C.;Lin,J.;Zhu,W.;Xie,L.;Yin,C.;Zhao,J.;Wang,J.;Bradley,D.D.C.;Huang,W.Steric-hindrance-functionalizedpolydiarylfluorenes:conformationalbehavior,stabilizedblueelectroluminescence,andefficientamplifiedspontaneousemission.ACS Appl. Mater. Interfaces2017,9,37856−37863..

Liu,B.;Lin,J.Y.;Liu,F.;Yu,M.N.;Zhang,X.;Xia,R.;Yang,T.;Fang,Y.;Xie,L.;Huang,W.Ahighlycrystallineandwide-bandgappolydiarylfluorenewith²-phaseconformationtowardstableelectroluminescenceanddualamplifiedspontaneousemission.ACS Appl. Mater. Interfaces2016,8,21648−21655..

Lin,J.Y.;Zhu,W.S.;Liu,F.;Xie,L.H.;Zhang,L.;Xia,R.;Xing,G.C.;Huang,W.Arationalmoleculardesignofβ-phasepolydiarylfluorenes:synthesis,morphology,andorganiclasers.Macromolecules2014,47,1001−1007..

Liu,B.;Lin,J.Y.;Yu,M.N.;Li,B.;Xie,L.;Ou,C.;Liu,F.;Li,T.;Lu,D.;Huang,W.Hereditarycharacterofalkyl-chainlengtheffectonβ-phaseconformationfrompolydialkylfluorenestobulkypolydiarylfluorenes.J. Phys. Chem. C2017,121,19087−19096..

Bright,D.W.;Dias,F.B.;Galbrecht,F.;Scherf,U.;Monkman,A.P.Theinfluenceofalkyl-chainlengthonbeta-phaseformationinpolyfluorenes.Adv. Funct. Mater.2009,19,67−73..

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Cooperative Supramolecular Polymerization of Propeller-Shaped Triphenylamine Cyanostilbenes for Explosive Detection

Melting Temperature of Individual Electrospun Poly(vinylidene fluoride) Fibers Studied by AFM-based Local Thermal Analysis

Synthesis of Functional Hyperbranched Poly(methyltriazolylcarboxylate)s by Catalyst-free Click Polymerization of Butynoates and Azides