IMPROVED PROPERTIES OF METALLOCENE-CATALYZED LINEAR LOW-DENSITY POLYETHYLENE/POLYPROPYLENE BLENDS DURING ULTRASONIC EXTRUSION
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IMPROVED PROPERTIES OF METALLOCENE-CATALYZED LINEAR LOW-DENSITY POLYETHYLENE/POLYPROPYLENE BLENDS DURING ULTRASONIC EXTRUSION
IMPROVED PROPERTIES OF METALLOCENE-CATALYZED LINEAR LOW-DENSITY POLYETHYLENE/POLYPROPYLENE BLENDS DURING ULTRASONIC EXTRUSION
高分子科学(英文版)2007年第4期 页码:357-364
Affiliations:
1. Qingdao University of Science and Technology), Ministry of Education
2. Chengdu 610065
3. China
Author bio:
Funds:
This work was financially supported by the Special Funds for Major State Basic Research Projects of China (No.2005CB623800)();the National Natural Science Foundation of China (No. 20374037)();the Open Foundation of Key Laboratory of Rubber-plastics (QUST),Ministry of Education, China and the Foundation for Youth of Sichuan University()
DOI:
中图分类号:TQ320.6
纸质出版:2007
Accepted:
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[1]郭少云.IMPROVED PROPERTIES OF METALLOCENE-CATALYZED LINEAR LOW-DENSITY POLYETHYLENE/POLYPROPYLENE BLENDS DURING ULTRASONIC EXTRUSION[J].Chinese Journal of Polymer Science,2007(04):357-364.
Hong Wu and Shao-yun Guo The State Key Laboratory of Polymer Materials Engineering. IMPROVED PROPERTIES OF METALLOCENE-CATALYZED LINEAR LOW-DENSITY POLYETHYLENE/POLYPROPYLENE BLENDS DURING ULTRASONIC EXTRUSION[J]. 2007, (4): 357-364.
[1]郭少云.IMPROVED PROPERTIES OF METALLOCENE-CATALYZED LINEAR LOW-DENSITY POLYETHYLENE/POLYPROPYLENE BLENDS DURING ULTRASONIC EXTRUSION[J].Chinese Journal of Polymer Science,2007(04):357-364.DOI:
Hong Wu and Shao-yun Guo The State Key Laboratory of Polymer Materials Engineering. IMPROVED PROPERTIES OF METALLOCENE-CATALYZED LINEAR LOW-DENSITY POLYETHYLENE/POLYPROPYLENE BLENDS DURING ULTRASONIC EXTRUSION[J]. 2007, (4): 357-364.DOI:
IMPROVED PROPERTIES OF METALLOCENE-CATALYZED LINEAR LOW-DENSITY POLYETHYLENE/POLYPROPYLENE BLENDS DURING ULTRASONIC EXTRUSION
<正>Metallocene-catalyzed linear low-density polyethylene/polypropylene (mLLDPE/PP) blends were prepared by ultrasonic extrusion in this work. Their extrusion processing behaviors were estimated by online measured data
such as the die pressure and flow rate. Crystallization and mechanical properties of the blends were also investigated. The results show that the addition of PP improves the processing behaviors of mLLDPE
but has little effect on its mechanical properties. On the other hand
the addition of mLLDPE improves the impact strength of PP
but has little effect on its processing behavior. The processing behaviors and mechanical properties of mLLDPE/PP blends get further improved due to the presence of ultrasonic oscillation during extrusion. Compared with PP-rich blends
the apparent viscosity drop of mLLDPE-rich blends is more sensitive to ultrasonic oscillation. The ultrasonic oscillation affects the crystal nucleation
while barely the other crystalline behaviors of the blends.
Abstract
Metallocene-catalyzed linear low-density polyethylene/polypropylene (mLLDPE/PP) blends were prepared by ultrasonic extrusion in this work. Their extrusion processing behaviors were estimated by online measured data
such as the die pressure and flow rate. Crystallization and mechanical properties of the blends were also investigated. The results show that the addition of PP improves the processing behaviors of mLLDPE
but has little effect on its mechanical properties. On the other hand
the addition of mLLDPE improves the impact strength of PP
but has little effect on its processing behavior. The processing behaviors and mechanical properties of mLLDPE/PP blends get further improved due to the presence of ultrasonic oscillation during extrusion. Compared with PP-rich blends
the apparent viscosity drop of mLLDPE-rich blends is more sensitive to ultrasonic oscillation. The ultrasonic oscillation affects the crystal nucleation
while barely the other crystalline behaviors of the blends.
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