Ordered Chain-Entanglement Topology and Compressive Mechanical Response in Crystalline Dative B―N Polymers

Tian-Yu Shan; Ding Xiao; Zhi-Jin Ju; Zhe-Wen Guo; Meng-Bin Wang; Xue-Dong Xiao; Guang-Feng Li; Fei-He Huang

doi:10.1007/s10118-026-3862-8

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Ordered Chain-Entanglement Topology and Compressive Mechanical Response in Crystalline Dative B―N Polymers

RESEARCH ARTICLE | Updated：2026-10-14

- Ordered Chain-Entanglement Topology and Compressive Mechanical Response in Crystalline Dative B―N Polymers
- Ordered Chain-Entanglement Topology and Compressive Mechanical Response in Crystalline Dative B―N Polymers
- Chinese Journal of Polymer Science 2026年44卷页码：1-9
- Affiliations：
  
  a.State Key Laboratory of Soil Pollution Control and Safety, Stoddart Institute of Molecular Science, Department of Chemistry, Zhejiang University, Hangzhou 310058, China
  b.Key Laboratory of High-Performance Adhesion Functional Materials and Application Technology of Zhejiang, Zhejiang-Israel Joint Laboratory of Self-Assembling Functional Materials, ZJU-Hangzhou Global Scientific and Technological Innovation Center, Hangzhou 311215, China
  c.College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China
  d.Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge MA 02139, USA
- Author bio：
  
  guangfengli@zju.edu.cn (G.F.L.)
  fhuang@zju.edu.cn (F.H.H.)
- Funds：
  
  This work was financially supported by Zhejiang Provincial Natural Science Foundation of China (Nos. LD26B020001 and LZ24B040001), the “pioneer” and “Leading Goose” R&D Program of Zhejiang (No. 2025C04010), the National Natural Science Foundation of China (Nos. 22035006, 22320102001, 22350007, 22205200 and 22475188), and Fundamental and Interdisciplinary Disciplines Breakthrough Plan of the Ministry of Education of China (No. JYB2025XDXM407). We thank the Chemistry Instrumentation Center of Zhejiang University for technical support.;The authors declare no interest conflict.Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-026-3862-8.The data that support the findings of this study are available from the corresponding author upon reasonable request.
- DOI：10.1007/s10118-026-3862-8
  中图分类号：
- 收稿：2026-07-23，
  
  录用：2026-08-25，
  
  网络首发：2026-10-14，
  
  纸质出版：2026-09
- Accepted：
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Shan, T. Y.; Xiao, D.; Ju, Z. J.; Guo, Z. W.; Wang, M. B.; Xiao, X. D.; Li, G. F.; Huang, F. H. Ordered chain-entanglement topology and compressive mechanical response in crystalline dative B―N polymers. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-026-3862-8

Tian-Yu Shan, Ding Xiao, Zhi-Jin Ju, et al. Ordered Chain-Entanglement Topology and Compressive Mechanical Response in Crystalline Dative B―N Polymers[J/OL]. Chinese Journal of Polymer Science, 2026, 441-9.
Shan, T. Y.; Xiao, D.; Ju, Z. J.; Guo, Z. W.; Wang, M. B.; Xiao, X. D.; Li, G. F.; Huang, F. H. Ordered chain-entanglement topology and compressive mechanical response in crystalline dative B―N polymers. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-026-3862-8 DOI：

Tian-Yu Shan, Ding Xiao, Zhi-Jin Ju, et al. Ordered Chain-Entanglement Topology and Compressive Mechanical Response in Crystalline Dative B―N Polymers[J/OL]. Chinese Journal of Polymer Science, 2026, 441-9. DOI： 10.1007/s10118-026-3862-8.

摘要

Abstract

While the effects of chain entanglement on the mechanical properties of polymer systems have been extensively studied

it remains a major challenge to further clarify the deformation and motion of the entangled polymers at the molecular scale. Herein

one-dimensional and two-dimensional long-range ordered entangled polymers

along with a non-entangled control

are constructed by exploiting the bonding and extended conformations of dative B―N bonds in identical monomers to drive polymerization

thereby providing a powerful platform to investigate the evolution mechanism of chain entanglements under stress stimuli and their impact on the mechanical properties of materials. Combined mechanical measurements and density functional theory calculations reveal that polymer mechanics are not only profoundly influenced by the presence of chain entanglements but also strongly dictated by the specific entanglement topology. Compared with one-dimensional entangled polymers containing a limited number of intertwined chains

two-dimensional entangled polymers

in which numerous chains interweave within a planar network

demonstrate markedly enhanced resistance to deformation. This study elucidates the role of entanglements in the mechanical properties of polymers

providing new insights into the relationship between polymer entanglement structures and material performance.

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references

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