Donor-node-Acceptor Type Systems Based on Perylene Bisimides: a Versatile Class of Functional Polymers

Ying-Hui Song; Zeng-Qi Xie

doi:10.1007/s10118-026-3788-1

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Donor-node-Acceptor Type Systems Based on Perylene Bisimides: a Versatile Class of Functional Polymers

REVIEW | Updated：2026-09-29

- Donor-node-Acceptor Type Systems Based on Perylene Bisimides: a Versatile Class of Functional Polymers
- Donor-node-Acceptor Type Systems Based on Perylene Bisimides: a Versatile Class of Functional Polymers
- Chinese Journal of Polymer Science 2026年44卷页码：1-16
- Affiliations：
  
  State Key Laboratory of Luminescent Materials and Devices, Institute of Polymer Optoelectronic Materials and Devices, Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates, Guangdong Basic Research Center of Excellence for Energy and Information Polymer Materials, South China University of Technology, Guangzhou 510640, China
- Author bio：
  
  msxiez@scut.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 52373178 and 22575090), the National Key Research and Development Program of China (No. 2022YFA1204404), and the Fund of the Key Laboratory of Luminescence from Molecular Aggregates of Guangdong Province (No. 2023B1212060003). The authors would also like to thank the State Key Lab of Luminescent Materials and Devices, South China University of Technology (No. Skllmd-2025-03/2026-02).;Zeng-Qi Xie received his Ph.D. degree from Jilin University (JLU) in 2007. He did postdoctoral research at the Seoul National University with Prof. Soo Young Park and AvH research at the Würzburg University with Prof. Frank Würthner. He joined the School of Materials Science and Engineering, South China University of Technology (SCUT) in 2012, and was appointed as a Full Professor since then. He leads an Optoelectronic group working on perylene bisimide chemistry, organic/polymer functional materials, and optoelectronic devices.The authors declare no interest conflict.
- DOI：10.1007/s10118-026-3788-1
  中图分类号：
- 收稿：2026-04-29，
  
  修回：2026-06-12，
  
  录用：2026-06-17，
  
  网络首发：2026-09-29，
  
  纸质出版：2026-08
- Accepted：
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Song, Y. H.; Xie, Z. Q. Donor-node-acceptor type systems based on perylene bisimides: a versatile class of functional polymers. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-026-3788-1

Ying-Hui Song, Zeng-Qi Xie. Donor-node-Acceptor Type Systems Based on Perylene Bisimides: a Versatile Class of Functional Polymers[J/OL]. Chinese Journal of Polymer Science, 2026, 441-16.
Song, Y. H.; Xie, Z. Q. Donor-node-acceptor type systems based on perylene bisimides: a versatile class of functional polymers. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-026-3788-1 DOI：

Ying-Hui Song, Zeng-Qi Xie. Donor-node-Acceptor Type Systems Based on Perylene Bisimides: a Versatile Class of Functional Polymers[J/OL]. Chinese Journal of Polymer Science, 2026, 441-16. DOI： 10.1007/s10118-026-3788-1.

摘要

Abstract

Donor-node-acceptor (D-n-A) systems based on perylene bisimide (PBI) have emerged as versatile platforms for organic electronics and quantum materials. In this architecture

a non-conjugated node

typically an imide nitrogen

breaks conjugation between the donor and acceptor

spatially separating the highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) on the two components. This decoupling renders p- and n-type doping independent and precisely controllable

thereby overcoming the fundamental limitations of conventional conjugated polymers. This review systematically summarizes the recent progress in D-n-A systems from small molecules to functional polymers. In PBI dyads and triads

node-induced exciton coupling enables tunable photophysics

whereas molecular conformation controls the competition between fluorescence and symmetry-breaking charge separation. The cascade energy-level alignment in the D-n-A

-n-A

architectures yields long-lived charge-separated states by spatially separating the radical ion pair. Covalent linking of stable radicals (TEMPO

TTM) to PBI or naphthalene bisimide (NBI)

via

nodes allows efficient photoinduced intersystem crossing and the formation of quartet states (S=3/2)

promising for molecular qubits. In the polymer domain

D-n-A polymers with a small fraction of PBI acceptors exhibit photoenhanced hole transportation

serving as hole-transporting layers for photodetectors. Bipolar polymers with a D:A ratio of approximately 1:1 demonstrate ambipolar charge transport and storage and have been successfully applied in flexible supercapacitors

lithium-ion batteries

and multicolor electrochromic devices. Finally

the outlook highlights future directions: precise control of donor-acceptor coupling

optimization of polymer morphology

translation to stable solid-

state systems

and multifunctional integration of electrochemistry with spin quantum properties.

关键词

Keywords

references

Phung, V. D.; Tran, V. V. Advances and innovations in conjugated polymer fluorescent sensors for environmental and biological detection. Biosensors 2025 , 15 , 580..

Zhao, N. X.; Jeon, S. J.; Li, Y. N. Cross-conjugated polymer semiconductors. Macromol. Rapid Commun. 2025 , 46 , e00281..

Kotp, M. G.; Mohamed, M. G.; Kuo, S. W. Conjugated microporous polymer electrodes for supercapacitors: recent progress, key challenges, and future directions. Chem. Sci. 2025 , 16 , 20718−20754..

Chougle, A.; Rezk, A.; Afzal, S. U. B.; Mohammed, A. K.; Shetty, D.; Nayfeh, A. Evolving role of conjugated polymers in nanoelectronics and photonics. Nano-Micro Lett. 2025 , 17 , 230..

Zheng, Y.; Yu, Z. A.; Zhang, S.; Kong, X.; Michaels, W.; Wang, W.; Chen, G.; Liu, D. Y.; Lai, J. C.; Prine, N.; Zhang, W. M.; Nikzad, S.; Cooper, C. B.; Zhong, D. L.; Mun, J.; Zhang, Z. T.; Kang, J.; Tok, J. B. H.; McCulloch, I.; Qin, J.; Gu, X. D.; Bao, Z. N. A molecular design approach towards elastic and multifunctional polymer electronics. Nat. Commun. 2021 , 12 , 5701..

Zhang, X. Y.; Yu, Z. D.; Liu, N. F.; Sun, W. X.; Wang, X. Y.; Wu, J. J.; Feng, J. T.; Qu, Y. K.; Li, S. L.; Xie, Z. H.; Sun, Y. Z.; Hsieh, W. Y.; Pan, C. K.; Ye, L.; Yao, Z. F.; Wang, J. Y.; Pei, J. Achieving intrinsically stretchable high-performance n-type semiconducting polymers by tuning side chain ordering inspired by oleic acid. npj Flexible Electron. 2026 , 10 , 45..

Qiu, Y. C.; Zhang, B.; Yang, J. C.; Gao, H. F.; Li, S.; Wang, L.; Wu, P. H.; Su, Y. W.; Zhao, Y.; Feng, J. G.; Jiang, L.; Wu, Y. C. Wafer-scale integration of stretchable semiconducting polymer microstructures via capillary gradient. Nat. Commun. 2021 , 12 , 7038..

Luo, X. N.; Liu, X. R.; Yang, W. Y.; Li, Y. L.; Yang, Z. Y.; Huang, W. T.; Wu, J. M.; Zhang, X. W.; Li, Z. Y.; Ma, D. G.; Zhong, W. K.; Li, N.; Ying, L. A synergistic strategy of crosslinking and filler toughening enabling stretchable organic photovoltaics for wearable applications. Nat. Commun. 2026 , 17 , 1240..

Zhang, M. J.; Guo, X.; Ma, W.; Ade, H.; Hou, J. H. A large-bandgap conjugated polymer for versatile photovoltaic applications with high performance. Adv. Mater. 2015 , 27 , 4655−4660..

Royakkers, J.; Yang, H.; Gillett, A. J.; Eisner, F.; Ghosh, P.; Congrave, D. G.; Azzouzi, M.; Andaji-Garmaroudi, Z.; Leventis, A.; Rao, A.; Fro st, J. M.; Nelson, J.; Bronstein, H. Synthesis of model heterojunction interfaces reveals molecular-configuration-dependent photoinduced charge transfer. Nat. Chem. 2024 , 16 , 1453−1461..

Liao, S. H.; Jhuo, H. J.; Cheng, Y. S.; Chen, S. A. Fullerene derivative-doped zinc oxide nanofilm as the cathode of inverted polymer solar cells with low-bandgap polymer (ptb7-th) for high performance. Adv. Mater. 2013 , 25 , 4766−4771..

He, Z. C.; Zhong, C. M.; Su, S. J.; Xu, M.; Wu,H. B.; Cao, Y. Enhanced power-conversion efficiency in polymer solar cells using an inverted device structure. Nat. Photonics. 2012 , 6 , 591−595..

[Li, W. T.; You, W. Donor–acceptor alternating copolymers. In Conjugated polymers: A practical guide to synthesis , Müllen, K.; Reynolds, J. R.; Masuda, T. Eds.; The Royal Society of Chemistry, 2013 , pp. 319–342..

Müllen, K.; Pisula, W. Donor–acceptor polymers. J. Am. Chem. Soc. 2015 , 137 , 9503−9505..

Nizamuddin, S.; Nousheen, S.; Nava dharsana, M.; Yadagiri, B.; Narayanaswamy, K.; Singh, S. P.; Sharma, G. D. A review on the development of covalently connected donor–acceptor molecular materials for single-component organic solar cells. J. Mater. Chem. A. 2025 , 13 , 11114−11133..

Yi, J. C.; Zhang, G. Y.; Yu, H.; Yan, H. Advantages, challenges and molecular design of different material types used in organic solar cells. Nat. Rev. Mater. 2023 , 9 , 46−62..

Holliday, S.; Li, Y. L.; Luscombe, C. K. Recent advances in high performance donor-acceptor polymers for organic photovoltaics. Prog. Polym. Sci. 2017 , 70 , 34−51..

Yan, H.; Chen, Z. H.; Zheng, Y.; Newman, C.; Quinn, J. R.; Dötz, F.; Kastler, M.; Facchetti, A. A high-mobility electron-transporting polymer for printed transistors. Nature 2009 , 457 , 679−686..

Bronstein, H.; Chen, Z. Y.; Ashraf, R. S.; Zhang, W. M.; Du, J. P.; Durrant, J. R.; Shakya Tuladhar, P.; Song, K.; Watkins, S. E.; Geerts, Y.; Wienk, M. M.; Janssen, R. A. J.; Anthopoulos, T.;Sirringhaus, H.; Heeney, M.; McCulloch, I. Thieno[3,2- b ] thiophene−diketopyrrolopyrrole-containing polymers for high-performance organic field-effect transistors and organic photovoltaic devices. J. Am. Chem. Soc. 2011 , 133 , 3272−3275..

Tam, T. L. D.; Ng, C. K.; Lim, S. L.; Yildirim, E.; Ko, J.; Leong, W. L.; Yang, S. W.; Xu, J. W. Proquinoidal-conjugated polymer as an effective strategy for the enhancement of electrical conductivity and thermoelectric properties. Chem. Mater. 2019 , 31 , 8543−8550..

Biswas, P.; Kong, L. C.; Tian, Z.T. Donor–acceptor conjugated polymers as high-mobility semiconductors: prospects for organic thermoelectrics. Nanoscale 2025 , 17 , 23896−23914..

Liu, Z. T.; Hu, Y. C.; Li, P. C.; Wen, J.; He, J. G.; Gao, X. Enhancement of the thermoelectric performance of dpp based polymers by introducing one 3,4-ethylenedioxythiophene electron-rich building block. J. Mater. Chem. C 2020 , 8 , 10859−10867..

Suh, E. H.; Jeong, Y. J.; Oh, J. G.; Lee, K.; Jung, J.; Kang, Y. S.; Jang, J. Doping of donor-acceptor polymers with long side chains via solution mixing for advancing thermoelectric properties. Nano Energy 2019 , 58 , 585−595..

Kim, B. G.; Ma, X.; Chen, C.; Ie, Y.; Coir, E. W.; Hashemi, H.; Aso, Y.; Green, P. F.; Kieffer, J.; Kim, J. Energy level modulation of homo, lumo, and band-gap in conjugated polymers for organic photovoltaic applications. Adv. Funct. Mater. 2012 , 23 , 439−445..

Cao, Z. Q.; Tolba, S. A.; Li, Z. F.; Mason, G. T.; Wang, Y.; Do, C.; Rondeau-Gagné, S.; Xia, W. J.; Gu, X.D. Molecular structure and conformational design of donor-acceptor conjugated polymers to enable predictable optoelectronic property. Adv. Mater. 2023 , 35 , 2302178..

Ma, B. W.; Shi, Q. Q.; Ma, X. Y.; Li, Y. W.; Chen, H.; Wen, K. K.; Zhao, R. H.; Zhang, F. J.; Lin, Y. Z.; Wang, Z. X.; Huang, H. Defect-free alternating conjugated polymers enabled by room-temperature stille polymerization. Angew. Chem. Int. Ed. 2022 , 61 , e202115969..

He, Y. R.; Huo, L. J.; Zheng, B. Advances of batch-variation control for photovoltaic polymers. Nano Energy 2024 , 123 , 109397..

Liguori, R.; Botta, A.; Rubino, A.; Pragliola, S.; Venditto, V. Stereoregular polymers with pendant carbazolyl groups: Synthesis, properties and optoelectronic applications. Synth. Met. 2018 , 246 , 185−194..

Szymanski, A.; Labes, M. M. Carrier mobility in poly( N -vinylcarbazole). J. Chem. Phys. 1969 , 50 , 3568−3571..

Pai, D. M. Transient photoconductivity in poly( N -vinylcarbazole). J. Chem. Phys. 1970 , 52 , 2285−2291..

Grazulevicius, J. V.; Strohriegl, P.; Pielichowski, J.; Pielichowski, K. Carbazole-containing polymers: synthesis, properties and applications. Prog. Polym. Sci. 2003 , 28 , 1297−1353..

Chen, F.; Hu, J.; Wang, X. D.; Shao, S. Y.; Wang, L. X.; Jing, X. B.; Wang, F. S. Through-space charge transfer blue polymers containing acridan donor and oxygen-bridged triphenylboron acceptor for highly efficient solution-processed organic light-emitting diodes. Sci. China Chem. 2020 , 63 , 1112−1120..

Shao, S. Y.; Hu, J.; Wang, X. D.; Wang, L. X.; Jing, X. B.; Wang, F. S. Blue thermally activated delayed fluorescence polymers with nonconjugated backbone and through-space charge transfer effect. J. Am. Chem. Soc. 2017 , 139 , 17739−17742..

Shao, S. Y.; Wang, L. X. Through-space charge transfer polymersfor solution-processed organic light-emitting diodes. Aggregate 2020 , 1 , 45−56..

Hu, J.; Li, Q.; Wang, X. D.; Shao, S. Y.; Wang, L. X.; Jing, X. B.; Wang, F. S. Developing through-space charge transfer polymers as a general approach to realize full-color and white emission with thermally activated delayed fluorescence. Angew. Chem. Int. Ed. 2019 , 58 , 8405−8409..

Chen, M. Q.; Li, M. H.; Wang, H. T.; Qu, S. X.; Zhao, X. M.; Xie, L. X.; Yang, S. F. Side-chain substitution of poly(3-hexylthiophene) (P3HT) by pcbm via postpolymerization: an intramolecular hybrid of donor and acceptor. Polym. Chem. 2013 , 4 , 550−557..

Liang, S. J.; Jiang, X. D.; Xiao, C. Y.; Li, C.; Chen, Q. M.; Li, W. W. Double-cable conjugated polymers with pendant rylene diimides for single-component organic solar cells. Acc. Chem. Res. 2021 , 54 , 2227−2237..

Feng, G. T.; Li, J. Y.; He, Y. K.; Zheng, W. Y.; Wang, J.; Li, C.; Tang, Z.; Osvet, A.; Li, N.; Brabec, C. J.; Yi, Y. P.; Yan, H.; Li, W. W. Thermal-driven phase separation of double-cable polymers enables efficient single-component organic solar cells. Joule 2019 , 3 , 1765−1781..

Liang, S. J.; Liu, B. Q.; Karuthedath, S.; Wang, J.; He, Y. K.; Tan, W. L.; Li, H.; Xu, Y. H.; Li, N.; Hou, J. H.; Tang, Z.; Laquai, F.; McNeill, C. R.; Brabec, C. J.; Li, W. W. Double-cable conjugated polymers with pendent near-infrared electron acceptors for single-component organic solar cells. Angew. Chem. Int. Ed. 2022 , 61 , e202209316..

[Feng, G. T.; Li, J. Y.; Colberts, F. J. M.; Li, M. M.; Zhang, J. Q.; Yang, F.; Jin, Y. Z.; Zhang, F. L.; Janssen, R. A. J.; Li, C.; Li, W. W. “Double-cable” conjugated polymers with linear backbone toward high quantum efficiencies in single-component polymer solar cells. J. Am. Chem. Soc . 2017 , 139 , 18647–18656..

Liu, B. Q.; Xu, Y. H.; Liu, F.; Xie, C. C.; Liang, S. J.; Chen, Q. M.; Li, W. W. Double-cable conjugated polymers with fullerene pendant for single-component organic solar cells. Chinese J. Polym. Sci. 2022 , 40 , 898−904..

Li, C.; Wu, X. X.; Sui, X. Y.; Wu, H. B.; Wang, C.; Feng, G. T.; Wu, Y. G.; Liu, F.; Liu, X. F.; Tang, Z.; Li, W. W. Crys talline cooperativity of donor and acceptor segments in double-cable conjugated polymers toward efficient single-component organic solar cells. Angew. Chem. Int. Ed. 2019 , 58 , 15532−15540..

[Liang, S.; Xiao, C. Y.; Xie, C. C.; Liu, B. Q.; Fang, H. S.; Li, W. W. 13% single-component organic solar cells based on double-cable conjugated polymers with pendent y-series acceptors. Adv. Mater . 2023 , 35 , 2300629.

Yin, Z.; Gu, M. X.; Ma, H. L.; Jiang, X. Y.; Zhi, J. H.; Wang, Y. F.; Yang, H. F.; Zhu, W. G.; An, Z. F. Molecular engineering through control of structural deformation for highly efficient ultralong organic phosphorescence. Angew. Chem. Int. Ed. 2020 , 60 , 2058−2063..

Nakae, T.; Nishio, M.; Usuki, T.; Ikeya, M.; Nishimoto, C.; Ito, S.; Nishihara, H.; Hattori, M.; Hayashi, S.; Yamada, T.; Yamanoi, Y. Luminescent behavior elucidation of a disilane-bridged D–A–D triad composed of phenothiazine and thienopyrazine. Angew. Chem. Int. Ed. 2021 , 60 , 22871−22878..

Levin, M. D.; Kaszynski, P.; Michl, J. Bicyclo[1.1.1 ] pentanes, [n ] staffanes, [1.1.1 ] propellanes, and tricyclo[2.1.0.02,5 ] pentanes. Chem. Rev. 2000 , 100 , 169−234..

[Wurthner, F. Perylene bisimide dyes as versatile building blocks for functional supramolecular architectures. Chem. Commun . 2004 , 1564–1579..

Wang, H. L.; Zhang, Q. L.; Zhou, J. D.; Su, X. J.; Xie, G. J.; Tang, N. N.; Zheng, N.; Liu, L. L.; Xie, Z. Q. Donor-node-acceptor type hole-transporting materials based on conjugated polymers with perylene diimide pendants for high-performance vertical-structure perovskite photodetectors. Adv. Opt. Mater. 2022 , 10 , 2201202..

Łępicka, K.; Rybakiewicz-Sekita, R. Ambipolar polymer finite-space probing of voltage-driven counterion-insertion-coupled charge transport for wide-voltage energy storage. Chem. Eng. J. Adv. 2026 , 26 , 101090..

Hou, W. W.; Yao, S. L.; Chen, Y. S.; Tang, D. Y.; Gao, Y. J.; Zhang, X. Y.; Zhang, L.; Zhang, Z. L.; Ouyang, M.; Liu, J. L.; Gu, L.; Zhang, C. Fluorine modification regulation of d-a ambipolar conducting polymers towards high-performance energy storage device. Chem. Eng. J. 2024 , 479 , 147674..

Würthner, F.; Thalacker, C.; Diele, S.; Tschierske, C. Fluorescent j-type aggregates and thermotropic columnar mesophases of perylene bisimide dyes. Chem. Eur. J. 2001 , 7 , 2245−2253..

Lee, S. K.; Zu, Y. B.; Herrmann, A.; Geerts, Y.; Müllen, K.; Bard, A. J. Electrochemistry, spectroscopy and electrogenerated chemiluminescence of perylene, terrylene, and quaterrylene diimides in aprotic solution. J. Am. Chem. Soc. 1999 , 121 , 3513−3520..

Langhals, H.; Jona, W. Intense dyes through chromophore-chromophore interactions: bi- and trichromophoric perylene-3,4:9,10-bis(dicarboximide)s. Angew. Chem. Int. Ed. 1998 , 37 , 952−955..

Fang, S. M.; Zhou, J. D.; Zhou, X. H.; Wang, C.; Jiang, N. Q.; Liu, L. L.; Xie, Z. Q. Interchromophore rotation-related ultrafast charge separation at excited states in head-to-tail linked perylene diimide dyads. J. Phys. Chem. C 2019 , 123 , 23306−23311..

Chen, J. H.; Tang, N. N.; Zhou, J. D.; Wang, L. X.; Jiang, N. Q.; Zheng, N.; Liu, L. L.; Xie, Z. Q. Coexistence of parallel and rotary stackings in the lamellar crystals of a perylene bisimide dyad for temperature-sensitive bicomponent emission. J. Phys. Chem. Lett. 2021 , 12 , 3373−3378..

Xu, B.; Wang, C.; Ma, W. T.; Liu, L. L.; Xie, Z. Q.; Ma, Y. G. Photoinduced electron transfer in asymmetrical perylene diimide: Understanding the photophysical processes of light-absorbing nonfullerene acceptors. J. Phys. Chem. C 2017 , 121 , 5498−5502..

Tang, N. N.; Zhou, J. D.; Wang, L. X.; Stolte, M.; Xie, G. J.; Wen, X. B.; Liu, L. L.; Wurthner, F.; Gierschner, J.; Xie, Z. Q. Anomalous deep-red luminescence of perylene black analogues with strong pi-pi interactions. Nat. Commun. 2023 , 14 , 1922..

Loong, H.; Zhou, J. D.; Jiang, N. Q.; Feng, Y.; Xie, G. J.; Liu, L. L.; Xie, Z. Q. Photoinduced cascading charge transfer in perylene bisimide-based triads. J. Phys. Chem. B 2022 , 126 , 2441−2448..

Zhang, Y.; Xie, Z. Q.; Ma, Y. G. Utilization of low-energy photons of sunlight by multiphoton strategy: from nature to artificial techniques. CCS Chem. 2025 , 7 , 10−21..

Maylander, M.; Kopp, K.; Nolden, O.; Franz, M.; Thielert, P.; Vargas Jentzsch, A.; Gilch, P.; Schiemann, O.; Richert, S. PDi-t rityl dyads as photogenerated molecular spin qubit candidates. Chem. Sci. 2023 , 14 , 10727−10735..

Maylander, M.; Thielert, P.; Quintes, T.; Vargas Jentzsch, A.; Richert, S. Room temperature electron spin coherence in photogenerated molecular spin qubit candidates. J. Am. Chem. Soc. 2023 , 145 , 14064−14069..

Chen, Y. Z.; Palmer, J. R.; Phelan, B. T.; Peinkofer, K. R.; Krzyaniak, M. D.; Young, R. M.; Wasielewski, M. R. Charge-transfer states enable spin-selective formation of quartet state qudits in luminescent radical-chromophore dyads. J. Am. Chem. Soc. 2025 , 147 , 38762−38771..

Maylander, M.; Nolden, O.; Franz, M.; Chen, S.; Bancroft, L.; Qiu, Y.; Wasielewski, M. R.; Gilch, P.; Richert, S. Accessing the triplet state of perylenediimide by radical-enhanced intersystem crossing. Chem. Sci. 2022 , 13 , 6732−6743..

Maylander, M.; Chen, S.; Lorenzo, E. R.; Wasielewski, M. R.; Richert, S. Exploring photogenerated molecular quartet states as spin qubits and qudits. J. Am. Chem. Soc. 2021 , 143 ,7050−7058..

Wen, X. B.; Fang, S. M.; Xu, Y. C.; Zheng, N.; Liu, L. L.; Xie, Z. Q.; Wurthner, F. Enhanced electron transportation by dye doping in very low-temperature ( < 130 degrees c)-processed sol-gel zno toward flexible organic solar cells. ACS Appl. Mater. Interfaces 2019 , 11 , 34151−34157..

Nian, L.; Zhang, W. Q.; Zhu, N.; Liu, L. L.; Xie, Z. Q.; Wu, H. B.; Wurthner, F.; Ma, Y. G. Photoconductive cathode interlayer for highly efficient inverted polymer solar cells. J. Am. Chem. Soc. 2015 , 137 , 6995−6998..

Luo, Y. Q.; Yu, T. C.; Nian, L.; Liu, L. L.; Huang, F.; Xie, Z. Q.; Ma, Y. G. Photoconductive cathode interlayer for enhanced electron injection in inverted polymer light-emitting diodes. ACS Appl. Mater. Interfaces 2018 , 10 , 11377−11381..

Hu, L.; Han, L. J.; Quan, J. W.; Wu, F. Y.; Li, W.; Zhou, D.; Zhang, L.; Jin, Y. Z.; Yin, X. X.; Song, J. X.; Su, Z.; Li, Z. F.; Chen, L. Doping of zno electron transport layer with organic dye molecules to enhance efficiency and photo-stability of the non-fullerene organic solar cells. Small 2024 , 20 , e2310125..

Luo, Y. Q.; Fang, S. M.; Zheng, N.; Liu, L. L.; Würthner, F.; Xie, Z. Q. Increased electron transport and hol e blocking in an aqueous solution processed dye-doped zno cathode interlayer for high performance organic solar cells. ACS Appl. Energy Mater. 2020 , 3 , 1694−1701..

Qin, L. Q.; Ma, W. T.; Hanif, M.; Jiang, J. X.; Xie, Z. Q.; Ma, Y. G. Donor–node–acceptor polymer with excellent n-doped state for high-performance ambipolar flexible supercapacitors. Macromolecules 2017 , 50 , 3565−3572..

Wang, H. L.; Jiang, N. Q.; Zhang, Q. L.; Xie, G. J.; Tang, N. N.; Liu, L. L.; Xie, Z. Q. Facilely tunable redox behaviors in donor–node–acceptor polymers toward high-performance ambipolar electrode materials. Macromolecules 2021 , 54 , 3469−3477..

Miltenburg, M. B.; An, S. Y.; Obhi, N. K.; Grignon, E.; McAllister, B. T.; Seferos, D. S. Ambipolar poly(3,4-ethylenedioxythiophene)-pendant tetrachlorinated perylene diimide for symmetric supercapacitors. ACS Appl. Polym. Mater. 2020 , 2 , 5574−5580..

Liu, J. L.; Hou, W. W.; Tang, D. Y.; Gao, Y. J.; Yao, S. L.; Jiang, L. X.; Zhang, Z. L.; Ouyang, M.; Zhang, C. Donor–node–acceptor ambipolar conducting polymer electrode materials for wide-voltage and high-stability supercapacitors. ACS Sustainable Chem. Eng. 2022 , 10 , 15978−15986..

Guo, M. C.; Tang, W.; Tang, C. B.; He, X. S.; Fan, C. In-situ electropolymerization of bipolar organic cathodes for highly efficient li-ion batteries. J. Energy Storage. 2024 , 97 , 112939..

Wang, W.; Zhao, C.; Yang, J. X.; Xiong, P. X.; Su, H.; Xu, Y. H. In-situ electropolymerized bipolar organic cathode for stable and high-rate lithium-ion batteries. Sci. China Mater. 2021 , 64 , 2938−2948..

Ma, W. T.; Qin, L. Q.; Gao, Y.; Zhang, W. Q.; Xie, Z. Q.; Yang, B.; Liu, L. L.; Ma, Y. G. A perylene bisimide network for high-performance n-type electrochromism. Chem. Commun. 2016 , 52 , 13600−13603..

Hsiao, S. H.; Chen, Y. Z. Electrochemical synthesis of stable ambipolar electrochromic polyimide film from a bis(triphenylamine) perylene diimide. J. Electroanal. Chem. 2017 , 799 , 417−423..

Hsiao, S. H.; Chen, Y. Z. Electroactive and ambipolar electrochromic polyimides from arylene diimides with triphenylamine n -substituents. Dyes Pigm. 2017 , 144 , 173−183..

Zou, X. B.; Yang, S.; Zeng, H.; Yuan, X. Y.; Tang, S. Z.; Zhou, Z. H.; Song, Y. J.; Li, B.; Liu, M. Mixed-valence engineered bipolar polyimide covalent organic framework film for multicolor displays and dual-band electrochromism. J. Mater. Chem. A. 2026 , 14 , 15287−15296..

Ponnapati, R.; Felipe, M. J.; Advincula, R. Electropolymerizable terthiophene-terminated poly(aryl ether) dendrimers with naphthalene and perylene cores. Macromolecules 2011 , 44 , 7530−7537..

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