Multicomponent Polymerization of Diacetylarenes, Dialkynones, and NH<sub>4</sub>OAc for <italic style="font-style: italic">In situ</italic> Construction of Functional Conjugated Poly(triarylpyridine)s

Shi-Han Yu; Lu Wang; Meng-Chao Zhang; Hong-Kun Li

doi:10.1007/s10118-025-3362-2

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Multicomponent Polymerization of Diacetylarenes, Dialkynones, and NH₄OAc for In situ Construction of Functional Conjugated Poly(triarylpyridine)s

RESEARCH ARTICLE | Updated：2025-08-25

- Multicomponent Polymerization of Diacetylarenes, Dialkynones, and NH₄OAc for In situ Construction of Functional Conjugated Poly(triarylpyridine)s
- Multicomponent Polymerization of Diacetylarenes, Dialkynones, and NH₄OAc for In situ Construction of Functional Conjugated Poly(triarylpyridine)s
- 高分子科学（英文） 2025年43卷第9期页码：1496-1504
- Affiliations：
  
  Laboratory of Advanced Optoelectronic Materials, Suzhou Key Laboratory of Novel Semiconductor-Optoelectronics Materials and Devices, State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China
- Author bio：
  
  hkli@suda.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 22071166) and the Priority Academic Program Development of Jiangsu High Education Institutions (PAPD).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-025-3362-2.
- DOI：10.1007/s10118-025-3362-2
  中图分类号：
- 收稿日期：2025-03-15，
  
  修回日期：2025-04-12，
  
  录用日期：2025-04-17，
  
  网络出版日期：2025-07-03，
  
  纸质出版日期：2025-09-05
- Accepted：
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Yu, S. H.; Wang, L.; Zhang, M. C.; Li, H. K. Multicomponent polymerization of diacetylarenes, dialkynones, and NH₄OAc for in situ construction of functional conjugated poly(triarylpyridine)s. Chinese J. Polym. Sci. 2025, 43, 1496–1504

Shi-Han Yu, Lu Wang, Meng-Chao Zhang, et al. Multicomponent Polymerization of Diacetylarenes, Dialkynones, and NH₄OAc for In situ Construction of Functional Conjugated Poly(triarylpyridine)s[J]. Chinese journal of polymer science, 2025, 43(9): 1496-1504.
Yu, S. H.; Wang, L.; Zhang, M. C.; Li, H. K. Multicomponent polymerization of diacetylarenes, dialkynones, and NH₄OAc for in situ construction of functional conjugated poly(triarylpyridine)s. Chinese J. Polym. Sci. 2025, 43, 1496–1504 DOI： 10.1007/s10118-025-3362-2.

Shi-Han Yu, Lu Wang, Meng-Chao Zhang, et al. Multicomponent Polymerization of Diacetylarenes, Dialkynones, and NH₄OAc for In situ Construction of Functional Conjugated Poly(triarylpyridine)s[J]. Chinese journal of polymer science, 2025, 43(9): 1496-1504. DOI： 10.1007/s10118-025-3362-2.

摘要

The multicomponent polymerization of acetylarene

alkynones and NH

OAc is developed for

in-situ

construction of soluble conjugated poly(triarylpyridine)s with aggregation-induced emission and room-temperature phosphorescence characteristics.

Abstract

Exploration of new green polymerization strategies for the construction of conjugated polymers is important but challengeable. In this work

a multicomponent polymerization of acetylarenes

alkynones and ammonium acetate for

in situ

construction of conjugated poly(triarylpyridine)s was developed. The polymerization reactions of diacetylarenes

aromatic dialkynones and NH

OAc were performed in dimethylsulfoxide (DMSO) under heating in the presence of potassium

tert

-butoxide (

-BuOK)

affording four conjugated poly(2

6-triarylpyridine)s (PTAPs) in satisfactory yields. The resulting PTAPs have good solubility in common organic solvents and high thermal stability with 5% weight loss temperatures reaching up to 460 °C. They are also electrochemically active. The PTAPs incorporating tetraphenylethene units manifest aggregation-induced emission features. Moreover

through simply being doped into poly(vinyl alcohol) (PVA) matrix

the polymer and model compound containing triphenylamine moieties exhibit room-temperature phosphorescence properties wi

th ultralong lifetimes up to 696.2 ms and high quantum yields up to 28.7%. This work not only provides a facile green synthetic route for conjugated polymers but also offers new insights into the design of advanced materials with unique photophysical properties.

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Multicomponent Polymerization of Diacetylarenes, Dialkynones, and NH4OAc for In situ Construction of Functional Conjugated Poly(triarylpyridine)s

Multicomponent Polymerization of Diacetylarenes, Dialkynones, and NH4OAc for In situ Construction of Functional Conjugated Poly(triarylpyridine)s

DOI：10.1007/s10118-025-3362-2

摘要

Abstract

关键词

Keywords

references

Multicomponent Polymerization of Diacetylarenes, Dialkynones, and NH₄OAc for In situ Construction of Functional Conjugated Poly(triarylpyridine)s

Multicomponent Polymerization of Diacetylarenes, Dialkynones, and NH₄OAc for In situ Construction of Functional Conjugated Poly(triarylpyridine)s