Physical Adsorption and Glass Transition of Thin Polystyrene Films at a Graphene Interface

Jin-Tian Luo; Hao Zha; Hou-Kuan Tian; Biao Zuo

doi:10.1007/s10118-024-3241-2

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Physical Adsorption and Glass Transition of Thin Polystyrene Films at a Graphene Interface

RESEARCH ARTICLE | Updated：2024-11-14

- Physical Adsorption and Glass Transition of Thin Polystyrene Films at a Graphene Interface
- Physical Adsorption and Glass Transition of Thin Polystyrene Films at a Graphene Interface
- 高分子科学（英文版） 2024年42卷页码：1-7
- Affiliations：
  
  School of Chemistry and Chemical Engineering, Key Laboratory of Surface & Interface Science of Polymer Materials of Zhejiang Province, Zhejiang Sci-Tech University, Hangzhou 310018, China
- Author bio：
  
  chemizuo@zstu.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 22122306, 22303084 and 52373025).
- DOI：10.1007/s10118-024-3241-2
  中图分类号：
- 纸质出版日期：2024-10，
  
  网络出版日期：2024-11-14，
  
  收稿日期：2024-08-08，
  
  修回日期：2024-09-07，
  
  录用日期：2024-09-23
- Accepted：
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Luo, J. T.; Zha, H.; Tian, H. K.; Zuo, B. Physical adsorption and glass transition of thin polystyrene films at a graphene interface. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-024-3241-2

Jin-Tian Luo, Hao Zha, Hou-Kuan Tian, et al. Physical Adsorption and Glass Transition of Thin Polystyrene Films at a Graphene Interface. [J/OL]. Chinese Journal of Polymer Science, 2024,421-7.
Luo, J. T.; Zha, H.; Tian, H. K.; Zuo, B. Physical adsorption and glass transition of thin polystyrene films at a graphene interface. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-024-3241-2 DOI：

Jin-Tian Luo, Hao Zha, Hou-Kuan Tian, et al. Physical Adsorption and Glass Transition of Thin Polystyrene Films at a Graphene Interface. [J/OL]. Chinese Journal of Polymer Science, 2024,421-7. DOI： 10.1007/s10118-024-3241-2.

摘要

Abstract

Polymer adsorption at solid interfaces plays an important role in the dynamics of nanoscale polymer films. We investigated the influence of the interfacial chain adsorption on the glass transition temperature (

) and dewetting of polystyrene (PS) thin films on a graphene substrate that has strong interaction with PS. We found that the

s of PS films show a non-monotonic trend with increasing amount of polymer adsorption at the interface—first increasing and then decreasing

and this change in

is accompanied by a wetting-dewetting transition of the PS films. Film morphological analysis showed that the PS films dewet from the interfacially adsorbed layers rather than from the substrate

i.e

autophobic dewetting

indicating the presence of an unfavorable interaction between the adsorbed and free PS chains. We ascribed the repulsive interaction to the formation of a dense adsorbed layer on graphene due to the

interaction between PS and graphene

which prevents the non-adsorbed PS chain fro

m penetrating into the adsorbed layer. This may lead to drops in

at high adsorption extent.

关键词

Keywords

Polymer adsorptionInterfacial dynamicsGrapheneAutophobic dewettingThin films

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