Membranes of Amphiphilic Polyamide 1012 Prepared <italic style="font-style: italic">via</italic> Mixed‘Non-solvents’ Evaporation Induced Phase Separation

Xiang Liu; Jie Qiu; Yu-Ting Gao; Shuo Wang; Joachim Loos; Du-Jin Wang; Xia Dong; Tao Wen

doi:10.1007/s10118-024-3236-z

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Membranes of Amphiphilic Polyamide 1012 Prepared via Mixed‘Non-solvents’ Evaporation Induced Phase Separation

RESEARCH ARTICLE | Updated：2024-12-31

- Membranes of Amphiphilic Polyamide 1012 Prepared via Mixed‘Non-solvents’ Evaporation Induced Phase Separation
- Membranes of Amphiphilic Polyamide 1012 Prepared via Mixed‘Non-solvents’ Evaporation Induced Phase Separation
- 高分子科学（英文） 2025年43卷第1期页码：153-161
- Affiliations：
  
  a.School of Emergent Soft Matter, South China University of Technology, Guangzhou 510640, China
  b.Guangdong Provincial Key Laboratory of Functional and Intelligent Hybrid Materials and Devices, South China University of Technology, Guangzhou 510640, China
  c.Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  d.University of Chinese Academy of Sciences, Beijing 100049, China
- Author bio：
  
  twen@scut.edu.cn
- Funds：
  
  This work was financially supported by the Fundamental Research Funds for the Central Universities (No. 2023ZYGXZR107) and the TCL Science and Technology Innovation Fund.;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-024-3236-z.
- DOI：10.1007/s10118-024-3236-z
  中图分类号：
- 纸质出版日期：2025-01-01，
  
  网络出版日期：2024-11-14，
  
  收稿日期：2024-07-22，
  
  修回日期：2024-08-26，
  
  录用日期：2024-09-11
- Accepted：
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Liu, X.; Qiu, J.; Gao. Y. T.; Wang, S.; Loos, J.; Wang, D. J.; Dong, X.; Wen, T. Membranes of amphiphilic polyamide 1012 prepared via mixed ‘non-solvents’ evaporation induced phase separation. Chinese J. Polym. Sci. 2025, 43, 153–161

XIANG LIU, JIE QIU, YU-TING GAO, et al. Membranes of Amphiphilic Polyamide 1012 Prepared via Mixed‘Non-solvents’ Evaporation Induced Phase Separation. [J]. Chinese journal of polymer science, 2025, 43(1): 153-161.
Liu, X.; Qiu, J.; Gao. Y. T.; Wang, S.; Loos, J.; Wang, D. J.; Dong, X.; Wen, T. Membranes of amphiphilic polyamide 1012 prepared via mixed ‘non-solvents’ evaporation induced phase separation. Chinese J. Polym. Sci. 2025, 43, 153–161 DOI： 10.1007/s10118-024-3236-z.

XIANG LIU, JIE QIU, YU-TING GAO, et al. Membranes of Amphiphilic Polyamide 1012 Prepared via Mixed‘Non-solvents’ Evaporation Induced Phase Separation. [J]. Chinese journal of polymer science, 2025, 43(1): 153-161. DOI： 10.1007/s10118-024-3236-z.

摘要

Polyamide 1012 (PA1012) can be dissolved in mixed solvents due to polar segment and non-polar segment and membranes are prepared by using mixed ‘non-solvents’ evaporation induced phase separation (MNEIPS) within 60 s. The morphology of porous PA1012 films depends on solution concentration

solvent ratio and solvent evaporation rate.

Abstract

Long-chain polyamides (LCPAs) are a class of bio-based polymers that can bridge conventional polyoleﬁns and polycondensates. In this work

taking the advantage of the amphiphilic nature of polyamide 1012 (PA1012)

membranes were prepared by using a non-conventional phase separation approach

namely

mixed ‘non-solvents’ evaporation induced phase separation (MNEIPS). PA1012 can be dissolved in a mixture of polar and non-polar solvents

both of which are non-solvents of PA1012. During the sequential evaporation of the two solvents

the phase separation of PA1012 occurred

inducing the formation of porous structures. We investigated the process of membrane formation in detail

with a specific focus on the liquid-liquid and liquid-solid phase transitions involved. Moreover

we studied the influence of critical factors

such as polymer concentration and mixed-solvent ratio

on the morphologies and properties of PA1012 membranes. This study provides new insights into the development of porous materials based on long-chain polycondensates.

关键词

Keywords

Long-chain polyamidePhase separationMembrane

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Membranes of Amphiphilic Polyamide 1012 Prepared via Mixed‘Non-solvents’ Evaporation Induced Phase Separation

Membranes of Amphiphilic Polyamide 1012 Prepared via Mixed‘Non-solvents’ Evaporation Induced Phase Separation

DOI：10.1007/s10118-024-3236-z

摘要

Abstract

关键词

Keywords

references