A Simple-Prepared and Multi-Reusable Adhesive Based on Epoxy Vitrimer
RESEARCH ARTICLE|Updated:2024-09-23
|
A Simple-Prepared and Multi-Reusable Adhesive Based on Epoxy Vitrimer
A Simple-Prepared and Multi-Reusable Adhesive Based on Epoxy Vitrimer
高分子科学(英文版)2024年42卷第10期 页码:1589-1594
Affiliations:
a.Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China
b.The Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China
Author bio:
yangyang86@tsinghua.edu.cn
Funds:
This work was financially supported by the National Natural Science Foundation of China (No. 22175106), the Beijing Nova Program (No. 20220484126) and Young Elite Scientists Sponsorship Program by CAST (No. YESS20230470).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-024-3206-5.
Wang, Y. T.; Liang, H.; Wei, Y.; Wang, J. L.; He, X. M.; Yang, Y. A simple-prepared and multi-reusable adhesive based on epoxy vitrimer. Chinese J. Polym. Sci. 2024, 42, 1589–1594
Yu-Ting Wang, Huan Liang, Yen Wei, et al. A Simple-Prepared and Multi-Reusable Adhesive Based on Epoxy Vitrimer[J]. Chinese Journal of Polymer Science, 2024,42(10):1589-1594.
Wang, Y. T.; Liang, H.; Wei, Y.; Wang, J. L.; He, X. M.; Yang, Y. A simple-prepared and multi-reusable adhesive based on epoxy vitrimer. Chinese J. Polym. Sci. 2024, 42, 1589–1594 DOI: 10.1007/s10118-024-3206-5.
Yu-Ting Wang, Huan Liang, Yen Wei, et al. A Simple-Prepared and Multi-Reusable Adhesive Based on Epoxy Vitrimer[J]. Chinese Journal of Polymer Science, 2024,42(10):1589-1594. DOI: 10.1007/s10118-024-3206-5.
A Simple-Prepared and Multi-Reusable Adhesive Based on Epoxy Vitrimer
A high-performance adhesive is developed based on epoxy vitrimer in a simple and green method. This epoxy-vitrimer adhesive not only exhibits multi-reusability
but also has good water resistance. This advancement provides a reliable strategy for fabricating multi-reusable adhesive in a sustainable method.
Abstract
Adhesives play an important role in modern society's production and daily life. Developing robust and sustainable adhesives remains a great challenge. Here we report a sustainable epoxy-vitrimer adhesive with high adhesive strength (about 10 MPa) and reusability (82% strength after 3 times). This adhesive can be fabricated from commercially available products through a straightforward hot-pressing method without the need of solvents. The adhesive process is also simple
requiring only 30 min at 180 °C. In addition
the vitrimer adhesive has the advantages of both erasability for reuse and excellent water resistance. This work provides a facile strategy to fabricate high-strength adhesive that ensures reusability
recyclability
low cost of raw materials
and simple processing technology. Simultaneously
it expands the range of potential applications for epoxy vitrimers.
关键词
Keywords
EpoxyVitrimerAdhesiveReusableSustainable
references
Sanghvi, M. R.; Tambare, O. H.; More, A. P. Performance of various fillers in adhesives applications: a review.Polym. Bull.2022,79, 10491−10553..
Westerman, C. R.; McGill, B. C.; Wilker, J. J. Sustainably sourced components to generate high-strength adhesives.Nature2023,621, 306−311..
Mi, X.; Liang, N.; Xu, H.; Wu, J.; Jiang, Y.; Nie, B.; Zhang, D. Toughness and its mechanisms in epoxy resins.Prog. Mater. Sci.2022,130, 100977..
Prolongo, S. G.; del Rosario, G.; Ureña, A. Comparative study on the adhesive properties of different epoxy resins.Int. J. Adhe. Adhes.2006,26, 125−132..
Wang, J.; Sun, S.; Wu, P. A sustainable, ultratough, and ready-to-use adhesive heating patch driven by solar/electric dual energy.SusMat2021,1, 545−557..
Montarnal, D.; Capelot, M.; Tournilhac, F.; Leibler, L. Silica-like malleable materials from permanent organic networks.Science2011,334, 965−968..
Denissen, W.; Winne, J. M.; Du Prez, F. E. Vitrimers: permanent organic networks with glass-like fluidity.Chem. Sci.2016,7, 30−38..
Xu, H.; Zhang, Y.; Wang, H.; Wu, J. R. Unraveling the heterogeneity of epoxy-amine networks by introducing dynamic covalent bonds.Chinese J. Polym. Sci.2023,41, 926−932..
Wang, H.; Peng, W. S.; Wu, Q.; Zhao, Y.; Wang, S. T.; Yang, Y.; Wu, J. R.; Wang, X. L.; Zhang, R. C. Interplay of Crosslinking Structures and Segmental Dynamics in Solid-Liquid Elastomers.Chinese J. Polym. Sci.2022,40, 1297−1306..
Michal, B. T.; Spencer, E. J.; Rowan, S. J. Stimuli-responsive reversible two-level adhesion from a structurally dynamic shape-memory polymer.ACS Appl. Mater. Interfaces2016,8, 11041−11049..
Zheng, P.; McCarthy, T. J. A Surprise from 1954: Siloxane equilibration is a simple, robust, and obvious polymer self-healing mechanism.J. Am. Chem. Soc.2012,134, 2024−2027..
Ji, F.; Liu, X.; Sheng, D.; Yang, Y. Epoxy-vitrimer composites based on exchangeable aromatic disulfide bonds: reprocessibility, adhesive, multi-shape memory effect.Polymer2020,197, 122514..
Obadia, M. M.; Mudraboyina, B. P.; Serghei, A.; Montarnal, D.; Drockenmuller, E. Reprocessing and recycling of highly cross-linked ion-conducting networks through transalkylation exchanges of C–N bonds.J. Am. Chem. Soc.2015,137, 6078−6083..
Lai, J. C.; Mei, J. F.; Jia, X. Y.; Li, C. H.; You, X. Z.; Bao, Z. A stiff and healable polymer based on dynamic-covalent boroxine bonds.Adv. Mater.2016,28, 8277−8282..
Yang, Y.; Pei, Z.; Li, Z.; Wei, Y.; Ji, Y. Making and remaking dynamic 3D structures by shining light on flat liquid crystalline vitrimer films without a mold.J. Am. Chem. Soc.2016,138, 2118−2121..
Yang, Y.; Wang, H.; Zhang, S.; Wei, Y.; He, X.; Wang, J.; Zhang, Y.; Ji, Y. Vitrimer-based soft actuators with multiple responsiveness and self-healing ability triggered by multiple stimuli.Matter2021,4, 3354−3365..
Luo, J.; Demchuk, Z.; Zhao, X.; Saito, T.; Tian, M.; Sokolov, A. P.; Cao, P. F. Elastic vitrimers: beyond thermoplastic and thermoset elastomers.Matter2022,5, 1391−1422..
Zheng, N.; Fang, Z.; Zou, W.; Zhao, Q.; Xie, T. Thermoset shape-memory polyurethane with intrinsic plasticity enabled by transcarbamoylation.Angew. Chem. Int. Ed.2016,55, 11421−11425..
Aubert, J. H. Note: Thermally removable epoxy adhesives incorporating thermally reversible diels-alder adducts.J. Adhesion2003,79, 609−616..
Zhang, S.; Liu, T.; Hao, C.; Wang, L.; Han, J.; Liu, H.; Zhang, J. Preparation of a lignin-based vitrimer material and its potential use for recoverable adhesives.Green Chem.2018,20, 2995−3000..
Zhao, S.; Abu-Omar, M. M. Catechol-mediated glycidylation toward epoxy vitrimers/polymers with tunable properties.Macromolecules2019,52, 3646−3654..
Santiago, D.; Guzmán, D.; Padilla, J.; Verdugo, P.; De la Flor, S.; Serra, À. Recyclable and reprocessable epoxy vitrimer adhesives.ACS Appl. Polym. Mater.2023,5, 2006−2015..
Moreno, A.; Morsali, M.; Sipponen, M. H. Catalyst-free synthesis of lignin vitrimers with tunable mechanical properties: circular polymers and recoverable adhesives.ACS Appl. Mater. Interfaces2021,13, 57952−57961..
Sun, Y.; Wang, M.; Wang, Z.; Mao, Y.; Jin, L.; Zhang, K.; Xia, Y.; Gao, H. Amine-cured glycidyl esters as dual dynamic epoxy vitrimers.Macromolecules2022,55, 523−534..
Sun, P.; Li, Y.; Qin, B.; Xu, J. F.; Zhang, X. Super strong and multi-reusable supramolecular epoxy hot melt adhesives.ACS Mater. Lett.2021,3, 1003−1009..
Shi, Q.; Yu, K.; Kuang, X.; Mu, X.; Dunn, C. K.; Dunn, M. L.; Wang, T.; Jerry Qi, H. Recyclable 3D printing of vitrimer epoxy.Mater. Horiz.2017,4, 598−607..
Zheng, N.; Xu, Y.; Zhao, Q.; Xie, T. Dynamic covalent polymer networks: a molecular platform for designing functions beyond chemical recycling and self-healing.Chem. Rev.2021,121, 1716−1745..
Vidil, T.; Tournilhac, F.; Musso, S.; Robisson, A.; Leibler, L. Control of reactions and network structures of epoxy thermosets.Prog. Polym. Sci.2016,62, 126−179..
Kloxin, C. J.; Bowman, C. N. Covalent adaptable networks: smart, reconfigurable and responsive network systems.Chem. Soc. Rev.2013,42, 7161−7173..
Yang, Y.; Terentjev, E. M.; Zhang, Y.; Chen, Q.; Zhao, Y.; Wei, Y.; Ji, Y. Reprocessable thermoset soft actuators.Angew. Chem. Int. Ed.2019,58, 17474−17479..
Yang, Y.; Terentjev, E. M.; Wei, Y.; Ji, Y. Solvent-assisted programming of flat polymer sheets into reconfigurable and self-healing 3D structures.Nat. Commun.2018,9, 1906..
Regulating Actuations and Shapes of Liquid Crystal Elastomers through Combining Dynamic Covalent Bonds with Cooling-Rate-Mediated Control
Unlocking the Potential of Poly(butylene succinate) through Incorporation of Vitrimeric Network Based on Dynamic Imine Bonds
相关作者
Ya-Wen Liu
Huan Liang
Hong-Tu Xu
En-Jian He
Zhi-Jun Yang
Yi-Xuan Wang
Zhen Li
Yan Ji
相关机构
Advanced Materials and Energy Center, Academy of Aerospace Science and Innovation
School of Mechanical and Automotive Engineering, South China University of Technology
Chongqing Key Laboratory of Soft-Matter Material Manufacturing, School of Chemistry and Chemical Engineering, Southwest University
Jiangsu Key Laboratory for Micro and Nano Heat Fluid Flow Technology and Energy Application, School of Physical Science and Technology, Suzhou University of Science and Technology
Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, College of Chemistry, Chemical Engineering and Materials Science, Soochow University