Doping Effect of Poly(vinylidene fluoride) on Carbon Nanofibers Deduced by Thermoelectric Analysis of Their Melt Mixed Films

A. J. Paleo; V. M. Serrato; J. M. Mánuel; O. Toledano; E. Muñoz; M. Melle-Franco; B. Krause; P. Pötschke; K. Lozano

doi:10.1007/s10118-024-3200-y

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Doping Effect of Poly(vinylidene fluoride) on Carbon Nanofibers Deduced by Thermoelectric Analysis of Their Melt Mixed Films

RESEARCH ARTICLE | Updated：2024-11-04

- Doping Effect of Poly(vinylidene fluoride) on Carbon Nanofibers Deduced by Thermoelectric Analysis of Their Melt Mixed Films
- Doping Effect of Poly(vinylidene fluoride) on Carbon Nanofibers Deduced by Thermoelectric Analysis of Their Melt Mixed Films
- 高分子科学（英文版） 2024年42卷第11期页码：1802-1810
- Affiliations：
  
  a.2C2T-Centre for Textile Science and Technology, University of Minho, Campus de Azurém, 4800-058 Guimarães, Portugal
  b.Florida Institute of Technology, Melbourne, FL 32901, USA
  c.The Aerospace Corporation, El Segundo, CA 90245, USA
  d.Department of Condensed Matter Physics and Institute of Research on Electron Microscopy and Materials (IMEYMAT), Faculty of Sciences, University of Cádiz, Puerto Real, 11510 Cádiz, Spain
  e.CICECO – Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal
  f.UNED-Universidad Nacional de Educación a Distancia, Av. de Esparta, s/n, 28232, Las Rozas, Madrid, Spain
  g.Facultad de Física, Pontificia Universidad Católica de Chile, Santiago, 7820436, Chile
  h.Leibniz-Institut für Polymerforschung Dresden e.V. (IPF), Hohe Str. 6, 01069 Dresden, Germany
  i.Department of Mechanical Engineering, University of Texas Rio Grande Valley, Edinburg TX 78539, USA
- Author bio：
  
  ajpaleovieito@2c2t.uminho.pt
- Funds：
  
  This work was financially supported by the European Regional Development Fund through the Operational Competitiveness Program and the National Foundation for Science and Technology of Portugal (FCT) (No. UID/CTM/00264/2020 of Centre for Textile Science and Technology (2C2T) on its components Base and programmatic). A. J. P acknowledges support from project GreenAuto-Green Innovation for the Automotive Industry -PPS 3-Technical Textiles for the vehicle (Refª C6448637037-00000013) financed by EU funds, through the Plano de Recuperação e Resiliência (PRR), managed by IAPMEI, I.P.- Agência para a Competitividade e Inovação. M.M.-F. and O.T. acknowledge support within the scope of the project CICECO-Aveiro Institute of Materials, UIDB/50011/2020, UIDP/50011/2020 & LA/P/0006/2020, financed by national funds through the FCT/MCTES (PIDDAC). O.T. also acknowledges support from the Spanish Ministry of Universities with European Union funds – Next Generation EU through a Margarita Salas fellowship. K.L. also acknowledges support received from National Science Foundation under PREM award DMR 2122178. The authors would like to thank the staff of the Research Technology Department of the IPF for their support in setting up the thermoelectric measuring system, Manuela Heber (IPF) for SEM imaging and Ulrike Jentzsch-Hutschenreuther (IPF) for carrying out the thermoelectric measurements.;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-024-3200-y.
- DOI：10.1007/s10118-024-3200-y
  中图分类号：
- 纸质出版日期：2024-11-30，
  
  网络出版日期：2024-09-27，
  
  收稿日期：2024-04-02，
  
  修回日期：2024-06-09，
  
  录用日期：2024-07-08
- Accepted：
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Paleo, A. J.; Serrato, V. M.; Mánuel, J. M.; Toledano, O.; Muñoz, E.; Melle-Franco, M.; Krause, B.; Pötschke, P.; Lozano, K. Doping effect of poly(vinylidene fluoride) on carbon nanofibers deduced by thermoelectric analysis of their melt mixed films. Chinese J. Polym. Sci. 2024, 42, 1802–1810

A. J. Paleo, V. M. Serrato, J. M. Mánuel, et al. Doping Effect of Poly(vinylidene fluoride) on Carbon Nanofibers Deduced by Thermoelectric Analysis of Their Melt Mixed Films. [J]. Chinese Journal of Polymer Science, 2024,42(11):1802-1810.
Paleo, A. J.; Serrato, V. M.; Mánuel, J. M.; Toledano, O.; Muñoz, E.; Melle-Franco, M.; Krause, B.; Pötschke, P.; Lozano, K. Doping effect of poly(vinylidene fluoride) on carbon nanofibers deduced by thermoelectric analysis of their melt mixed films. Chinese J. Polym. Sci. 2024, 42, 1802–1810 DOI： 10.1007/s10118-024-3200-y.

A. J. Paleo, V. M. Serrato, J. M. Mánuel, et al. Doping Effect of Poly(vinylidene fluoride) on Carbon Nanofibers Deduced by Thermoelectric Analysis of Their Melt Mixed Films. [J]. Chinese Journal of Polymer Science, 2024,42(11):1802-1810. DOI： 10.1007/s10118-024-3200-y.

摘要

Electron transfer from the CNFs to the PVDF

computed using a Density Functional based Tight Binding (DFTB) Hamiltonian

responsible for the near-zero Seebeck coefficient found in melt mixed PVDF/CNF film.

Abstract

The effect of temperature on the electrical conductivity (

) and Seebeck coefficient (

) of n-type vapor grown carbon nanofibers (CNFs) and poly(vinylidene fluoride) (PVDF) melt-mixed with 15 wt% of those CNFs is analyzed. At 40 °C

the CNFs show stable n-type character (

=−4.8 μV·K

−1

) with an

.165 S·m

−1

while the PVDF/CNF composite film shows an

. 9 S·m

−1

and near-zero

(

=−0.5 μV·K

−1

). This experimental reduction in

is studied by the density functional tight binding (DFTB) method revealing a contact electron transfer from the CNFs to the PVDF in the interface. Moreover

in the temperature range from 40 °C to 100 °C

the

(

) of the CNFs and PVDF/CNF film

successfully described by the 3D variable range hopping (VRH) model

is explained as consequence of a thermally activated backscattering mechanism. On the contrary

the

(

) from 40 °C to 100 °C of the PVDF/CNF film

which satisfactorily matches the model proposed for some multi-walled carbon nanotube (MWCNT) doped mats; however

it does not follow the increase in

(

) found for CNFs. All these findings are presented with the aim of discerning the role of these n-type vapor grown carbon nanofibers on the

and S of their melt-mixed polymer composites.

关键词

Keywords

Carbon nanofibersPoly(vinylidene fluoride)Seebeck coefficientP-type dopingDensity functional based tight bindingVariable range hopping

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