A Dielectric Ink Combining Acrylate and Cyanate Moieties for Inkjet 3D Printing with Good Thermal Stability

Yi-Xuan Li; Liang-Ying Wu; Yan Yang; Yao-Zhong Lu; Zhong-Ying Ji; Yu-Xiong Guo; Xiao-Long Wang; Qiao-Sheng Pu

doi:10.1007/s10118-024-3114-8

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A Dielectric Ink Combining Acrylate and Cyanate Moieties for Inkjet 3D Printing with Good Thermal Stability

RESEARCH ARTICLE | Updated：2024-05-11

- A Dielectric Ink Combining Acrylate and Cyanate Moieties for Inkjet 3D Printing with Good Thermal Stability
- A Dielectric Ink Combining Acrylate and Cyanate Moieties for Inkjet 3D Printing with Good Thermal Stability
- 高分子科学（英文版） 2024年42卷第6期页码：766-774
- Affiliations：
  
  a.State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China
  b.State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Lanzhou 730000, China
  c.Lanzhou Traditional Chinese Medicine Hospital of Orthopedics and Traumatology, Lanzhou 730000, China
  d.Shandong Laboratory of Advanced Materials and Green Manufacturing at Yantai, Yantai Zhongke Research Institute of Advanced Materials and Green Chemical Engineering, Yantai 264006, China
- Author bio：
  
  guoyuxiong@licp.cas.cn (Y.X.G.)
  puqs@lzu.edu.cn (Q.S.P.)
- Funds：
  
  This work was financially supported by the National Key Research and Development Program of China (No. 2022YFB4600101), the Strategic Priority Research Program of the Chinese Academy of Sciences (No. XDB 0470303), the National Natural Science Foundation of China (No. 21974057), the Western Light Project of Chinese Academy of Sciences (No. xbzg–zdsy-202007) and the Oasis Scholar of Shihezi University and the Central Government to Guide Local Technological Development (No. 23ZYQA315).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-024-3114-8.
- DOI：10.1007/s10118-024-3114-8
  中图分类号：
- 纸质出版日期：2024-6-1，
  
  网络出版日期：2024-3-29，
  
  收稿日期：2023-11-30，
  
  修回日期：2024-2-18，
  
  录用日期：2024-2-28
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Li, Y. X.; Wu, L. Y.; Yang, Y.; Lu, Y. Z.; Ji, Z. Y.; Guo, Y. X.; Wang, X. L.; Pu, Q. S. A dielectric ink combining acrylate and cyanate moieties for inkjet 3D printing with good thermal stability. Chinese J. Polym. Sci. 2024, 42, 766–774

Yi-Xuan Li, Liang-Ying Wu, Yan Yang, et al. A Dielectric Ink Combining Acrylate and Cyanate Moieties for Inkjet 3D Printing with Good Thermal Stability[J]. Chinese Journal of Polymer Science, 2024,42(6):766-774.
Li, Y. X.; Wu, L. Y.; Yang, Y.; Lu, Y. Z.; Ji, Z. Y.; Guo, Y. X.; Wang, X. L.; Pu, Q. S. A dielectric ink combining acrylate and cyanate moieties for inkjet 3D printing with good thermal stability. Chinese J. Polym. Sci. 2024, 42, 766–774 DOI： 10.1007/s10118-024-3114-8.

Yi-Xuan Li, Liang-Ying Wu, Yan Yang, et al. A Dielectric Ink Combining Acrylate and Cyanate Moieties for Inkjet 3D Printing with Good Thermal Stability[J]. Chinese Journal of Polymer Science, 2024,42(6):766-774. DOI： 10.1007/s10118-024-3114-8.

摘要

A dielectric ink with favorable properties for inkjet 3D printing was formulated. An internal dual three-dimensional cross-linked network structure resin was prepared by a combination of photocuring and thermal curing. These can be applied to the 3D printing of printed circuit boards and other electronic devices that require dielectric properties.

Abstract

Inkjet 3D printing has potential in the additive manufacturing of electronic circuits and devices. However

inks that can be used for printing layers with

300 °C or hardness

200 MPa have been rarely reported. Cyanate ester (CE) polymers have excellent thermal stability

high strength

and low shrinkage compared to other common dielectric inks for inkjet 3D printing

but cannot be quickly shaped by ultraviolet (UV) irradiation or thermal treatment. Combining CEs with UV-curable monomers may be a possible way to accelerate crosslinking

but there are challenges from the adverse effects of the dilution of both monomers. In this study

dielectric inks with acrylate and cyanate moieties were developed. The low viscosity and su

rface tension of the CE precursor (Bisphenol E cyanate ester) were combined with photocurable acrylate diluent monomers and cross-linker to realize an ink suitable for inkjet 3D printing. An internal dual three-dimensional cross-linked network structure resin was prepared by a combination of photocuring and thermal curing with

up to 326.69 °C

hardness up to 431.84 MPa

dielectric constant of 2.70 at 8 GHz

and shrinkage of 1.64%. The developed dielectric inks can be applied to the 3D printing of printed circuit boards and other electronic devices that require dielectric properties.

关键词

Keywords

Inkjet printingCyanate ester resin3D doubly cross-linked networkGood thermal stability

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