High-Performance Recyclable Furan-based Epoxy Resin and Its Carbon Fiber Composites with Dense Hydrogen Bonding

Chang-Bo Zhao; Lu-Kun Feng; Hui Xie; Ming-Liang Wang; Bing Guo; Zhi-Yong Xue; Cai-Zhen Zhu; Jian Xu

doi:10.1007/s10118-023-3045-9

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High-Performance Recyclable Furan-based Epoxy Resin and Its Carbon Fiber Composites with Dense Hydrogen Bonding

RESEARCH ARTICLE | Updated：2023-12-26

- High-Performance Recyclable Furan-based Epoxy Resin and Its Carbon Fiber Composites with Dense Hydrogen Bonding
  Enhanced Publication
- High-Performance Recyclable Furan-based Epoxy Resin and Its Carbon Fiber Composites with Dense Hydrogen Bonding
- 高分子科学（英文版） 2024年42卷第1期页码：73-86
- Affiliations：
  
  a.Advanced Materials Research Institute, North China Electric Power University, Beijing 102206, China
  b.Institute of Low-Dimensional Materials Genome Initiative, College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518060, China
  c.Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, China
  d.School of Science and Shenzhen Key Laboratory of Flexible Printed Electronics Technology, and Shenzhen Key Laboratory of Advanced Functional Carbon Materials Research and Comprehensive Application, Harbin Institute of Technology, Shenzhen 518055, China
- Author bio：
  
  guobing2020@hit.edu.cn (B.G.)
  xuezy@ncepu.edu.cn (Z.Y.X.)
  czzhu@szu.edu.cn (C.Z.Z.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51973118, 22175121, 52003160 and 22001175), Key-Area Research and Development Program of Guangdong Province (Nos. 2019B010941001 and 2019B010929002), the Natural Science Foundation of Guangdong Province (No. 2020A1515010644), the Program for Guangdong Introducing Innovative and Entrepreneurial Teams (No. 2019ZT08C642), Shenzhen Science and Technology Program (Nos. JCYJ20220818095810022, JSGGZD20220822095201003 and JCYJ20210324095412035), the start-up fund of Shenzhen University (No. 000002110820), the Guangdong Natural Science Foundation (Nos. 2022A1515011781 and 2021A1515110086), Science and Technology Innovation Commission of Shenzhen, China (Nos. RCBS20200714114910141 and JCYJ20210324132816039), the Start-up Grant at Harbin Institute of Technology (Shenzhen), China (Nos. HA45001108 and HA11409049) and Shenzhen Key Laboratory of Advanced Functional Carbon Materials Research and Comprehensive Application (No. ZDSYS20220527171407017).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-023-3045-9.
- DOI：10.1007/s10118-023-3045-9
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Zhao, C. B.; Feng, L. K.; Xie, H; Wang, M. L.; Guo, B.; Xue, Z. Y.; Zhu, C. Z.; Xu, J. High-performance recyclable furan-based epoxy resin and its carbon fiber composites with dense hydrogen bonding. Chinese J. Polym. Sci. 2024, 42, 73–86

Chang-Bo Zhao, Lu-Kun Feng, Hui Xie, et al. High-Performance Recyclable Furan-based Epoxy Resin and Its Carbon Fiber Composites with Dense Hydrogen Bonding[J]. Chinese Journal of Polymer Science, 2024,42(1):73-86.
Zhao, C. B.; Feng, L. K.; Xie, H; Wang, M. L.; Guo, B.; Xue, Z. Y.; Zhu, C. Z.; Xu, J. High-performance recyclable furan-based epoxy resin and its carbon fiber composites with dense hydrogen bonding. Chinese J. Polym. Sci. 2024, 42, 73–86 DOI： 10.1007/s10118-023-3045-9.

Chang-Bo Zhao, Lu-Kun Feng, Hui Xie, et al. High-Performance Recyclable Furan-based Epoxy Resin and Its Carbon Fiber Composites with Dense Hydrogen Bonding[J]. Chinese Journal of Polymer Science, 2024,42(1):73-86. DOI： 10.1007/s10118-023-3045-9.

摘要

A new monomer (FCN) containing furan and Schiff base structure was designed to formulate recyclable and high-performance epoxy resins with high density of hydrogen bonding, while the resin performance was further examined in carbon-fiber composites.

Abstract

The emerging biomass-based epoxy vitrimers hold great potential to fulfill the requirements for sustainable development of society. Since the existence of dynamic chemical bonds in vitrimers often reduces both the thermal and mechanical properties of epoxy resins, it is challenging to produce recyclable epoxy vitrimers with both excellent mechanical properties and good thermal stability. Herein, a monomer 4-(((5-(hydroxymethyl)furan-2-yl)methylene)amino)phenol (FCN) containing furan ring with potential to form high density of hydrogen bonding among repeating units is designed and copolymerized with glycerol triglycidyl ether to yield epoxy resin (FCN-GTE), which intrinsically has dual hydrogen bond networks, dynamic imine structure and resultant high performance. Importantly, as compared to the BPA-GTE, the FCN-GTE exhibits significantly improved mechanical properties owing to the increased density of hydrogen bond network and physical crosslinking interaction. Furthermore, density functional theory (DFT) calculation and ,in situ, FTIR analysis is conducted to decipher the formation mechanism of hydrogen bond network. In addition, the FCN-GTE possesses superior UV shielding, chemical degradation, and recyclability because of the existence of abundant imine bonds. Notably, the FCN-GTE-based carbon fiber composites could be completely recycled in an amine solution. This study provides a facile strategy for synthesizing recyclable biomass-based high-performance epoxy vitrimers and carbon fiber composites.

关键词

Keywords

FuranHydrogen bond networkDynamic Schiff baseCarbon fiber compositesRecycling

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