Facile and Cost-Efficient Synthesis of Photovoltaic Polymers <italic style="font-style: italic">via</italic> Direct Arylation Coupling

Xiao-Chen Wang; Yuan Zhang; Jia-Xin Yang; Jin-Jun Shao; Ming-Feng Wang; Yong-Fang Li

doi:10.1007/s10118-023-2990-7

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Facile and Cost-Efficient Synthesis of Photovoltaic Polymers via Direct Arylation Coupling

REVIEW | Updated：2023-11-10

- Facile and Cost-Efficient Synthesis of Photovoltaic Polymers via Direct Arylation Coupling
- Facile and Cost-Efficient Synthesis of Photovoltaic Polymers via Direct Arylation Coupling
- 高分子科学（英文版） 2023年41卷第11期页码：1663-1685
- Affiliations：
  
  a.School of Materials Science and Engineering, Shaanxi Normal University, Xi'an 710119, China
  b.Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM), School of Flexible Electronics (Future Technologies), Nanjing Tech University, Nanjing 211816, China
  c.School of Science and Engineering, The Chinese University of Hong Kong, Shenzhen 518172, China
  d.Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
- Author bio：
  
  wangxc@snnu.edu.cn (X.C.W.)
  wangmingfeng@cuhk.edu.cn (M.F.W.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 51773046), the Fundamental Research Funds for the Central Universities, the School of Materials Science and Engineering, Shaanxi Normal University, and the Project of Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry Chemical Engineering and Materials Science, Soochow University.;Xiao-Chen Wang studied material science at the Beijing University of Chemical Technology (BUCT) and Institute of Chemistry, Chinese Academy of Sciences (ICCAS), and received his Ph.D. degree from the BUCT in 2012. After postdoctoral studies at Nanyang Technological University (NTU), Singapore, he joined National Center for Nanoscience and Technology (NCNST) in 2014, as an associate professor. In 2020, he was appointed as a Professor at School of Materials Science and Engineering, Shaanxi Normal University. His research interests include the design and synthesis of conjugated polymers for optoelectronic applications.Ming-Feng Wang received his bachelor degree in Chemistry in 2001 and MSc degree in Polymer Chemistry and Physics in 2004 under the supervision of Professor Xi Zhang from Jilin University. Then he joined Professor Mitchell A. Winnik’s group and obtained his Ph.D. degree in Polymer Chemistry and Materials in 2009 from the University of Toronto. He was awarded with a Postdoctoral Fellowship from the Natural Sciences and Engineering Research Council of Canada (NSERC) and worked in Professor Fred Wudl’s group at the University of California, Santa Barbara. In 2012, he joined the faculty of Nanyang Technological University, Singapore, as an elite Nanyang Assistant Professor in the School of Chemical and Biomedical Engineering. In 2020, he joined the Chinese University of Hong Kong, Shenzhen, as an Associate Professor in the School of Science and Engineering. His research interest focuses on polymeric materials with bioinspired structures and advanced functions for optoelectronic devices and biomedical applications.
- DOI：10.1007/s10118-023-2990-7
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Wang, X. C.; Zhang, Y.; Yang, J. X.; Shao, J. J.; Wang, M. F.; Li, Y. F. Facile and cost-efficient synthesis of photovoltaic polymers via direct arylation coupling. Chinese J. Polym. Sci. 2023, 41, 1663–1685

Xiao-Chen Wang, Yuan Zhang, Jia-Xin Yang, et al. Facile and Cost-Efficient Synthesis of Photovoltaic Polymers via Direct Arylation Coupling[J]. Chinese Journal of Polymer Science, 2023,41(11):1663-1685.
Wang, X. C.; Zhang, Y.; Yang, J. X.; Shao, J. J.; Wang, M. F.; Li, Y. F. Facile and cost-efficient synthesis of photovoltaic polymers via direct arylation coupling. Chinese J. Polym. Sci. 2023, 41, 1663–1685 DOI： 10.1007/s10118-023-2990-7.

Xiao-Chen Wang, Yuan Zhang, Jia-Xin Yang, et al. Facile and Cost-Efficient Synthesis of Photovoltaic Polymers via Direct Arylation Coupling[J]. Chinese Journal of Polymer Science, 2023,41(11):1663-1685. DOI： 10.1007/s10118-023-2990-7.

摘要

This review provides an overview of the history of preparing representative photovoltaic polymers utilized in polymer solar cells through direct arylation reactions and discusses the activity and selectivity of C−H bonds in typical building blocks under different reaction conditions.

Abstract

As the high calibre candidate of lightweight and flexible solar cells, polymer solar cells (PSCs) have made tremendous progress in recent years. However, the active photovoltaic materials in PSCs are mainly synthesized by metal-mediated coupling reaction requiring harsh reaction conditions, multiple-step synthesis, and cumbersome purification, which is not cost-efficient and may bring toxicity concerns. It is not favorable to the production of photovoltaic polymers and PSC devices on a large scale, and therefore unsuitable for the PSCs industrialization. Direct arylation coupling reaction ,via, aromatic C―H bonds activation enables the synthesis of conjugated polymers under mild conditions and simultaneously reduces synthetic steps, difficulty, and toxic reaction byproducts. This review provides an overview of the history of preparing representative photovoltaic polymers utilized in PSCs through direct arylation reactions and discusses the activity and selectivity of C―H bonds in typical building blocks under different reaction conditions. Especially, the impact of direct arylation condition on defect formation and photovoltaic performance of the photovoltaic polymers is addressed and compared with conventional Stille coupling methods.

关键词

Keywords

Photovoltaic polymersDirect arylation couplingC―H bonds activationPolymer solar cells (PSCs)Organic solar cells (OSCs)Low-cost

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DOI：10.1007/s10118-023-2990-7

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