Functionalized Hyperbranched Aliphatic Polyester Polyols: Synthesis, Properties and Applications

Aleksei Maksimov; Gennadii Kutyrev

doi:10.1007/s10118-022-2823-0

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Functionalized Hyperbranched Aliphatic Polyester Polyols: Synthesis, Properties and Applications

REVIEW | Updated：2022-11-16

- Functionalized Hyperbranched Aliphatic Polyester Polyols: Synthesis, Properties and Applications
- Functionalized Hyperbranched Aliphatic Polyester Polyols: Synthesis, Properties and Applications
- 高分子科学（英文版） 2022年40卷第12期页码：1567-1585
- Affiliations：
  
  Kazan National Research Technological University, Department of General Chemical Technologies, Kazan 420015, Russia
- Author bio：
  
  c6u92@yandex.ru
- Funds：
- DOI：10.1007/s10118-022-2823-0
  中图分类号：
- 收稿：2022-03-17，
  
  修回：2022-6-6，
  
  录用：2022-6-23，
  
  网络首发：2022-09-21，
  
  纸质出版：2022-12-01
- Accepted：
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Maksimov, A.; Kutyrev, G. Functionalized hyperbranched aliphatic polyester polyols: synthesis, properties and applications. Chinese J. Polym. Sci. 2022, 40, 1567–1585

Aleksei Maksimov, Gennadii Kutyrev. Functionalized Hyperbranched Aliphatic Polyester Polyols: Synthesis, Properties and Applications[J]. Chinese Journal of Polymer Science, 2022, 40(12): 1567-1585.
Maksimov, A.; Kutyrev, G. Functionalized hyperbranched aliphatic polyester polyols: synthesis, properties and applications. Chinese J. Polym. Sci. 2022, 40, 1567–1585 DOI： 10.1007/s10118-022-2823-0.

Aleksei Maksimov, Gennadii Kutyrev. Functionalized Hyperbranched Aliphatic Polyester Polyols: Synthesis, Properties and Applications[J]. Chinese Journal of Polymer Science, 2022, 40(12): 1567-1585. DOI： 10.1007/s10118-022-2823-0.

摘要

Functionalized hyperbranched aliphatic polyesters have a spatially unloaded core (ethoxylated pentaerythritol

orange color) and a shell of branched dendrons (monomer 2

2-dihydroxypropanoic acid

yellow color)

in which terminal oxygen-

nitrogen-

silicon-

sulfur- and organophosphorus functional fragments are predominantly located in the surface layer (red color).

Abstract

Recently

hyperbranched polymers (HBPs)

which differ significantly in structure and properties from linear

cross-linked and branched analogs

have become increasingly important. HBP have a spatial unloaded core and a shell of branched monomer units (dendrons)

in which functional groups are predominantly located in the surface layer. The size of macromolecules ranges from 2 nm to 100 nm. Currently

there are a fairly large number of publications in the literature devoted to the modification of hyperbranched polyester polyols with various functional groups and the assessment of the potential for their use. However

there are no review articles on this topic in recent years. In this regard

it is relevant to generalize the latest achievements in the field of synthesis

properties and application of hyperbranched polyester polyols with terminal oxygen

nitrogen

silicon

sulfur and organophosphorus fragments. The advantage of hyperbranched polyester polyols of the Boltorn H series is their industrial availability

biodegradability

nanoscale

non-toxicity and high solubility in various polar solvents due to short monomer units

as well as the presence of reactive terminal hydroxyl groups. Functionalization of hyperbranched polyester polyols at hydroxyl groups is mainly carried out by addition of acid anhydrides

iso(thio)cyanates

alkenes

lactides

lactones

lactams

epoxy compounds or reactions with halogenated compounds (alkyl halides

acid chlorides). In some cases

for the functionalization of polyester polyols special linkers are used

such as acid chlorides of unsaturated or dicarboxylic acids

diisocyanates

etc

which provide covalent bonding of the hyperbranched polymer with the target functional group. The obtained derivatives of hyperbranched polyesters are widely used in such areas as biomedicine

pharmacy

paints and varnishes

they are also used as catalysts

membranes

multifunctional coatings

plasticizers and polymer stabilizers.

关键词

Keywords

references

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