Bubble-templated Construction of Three-dimensional Ceramic Network for Enhanced Thermal Conductivity of Silicone Rubber Composites

Shou-Jun Li; Jing-Chao Li; Pei-Zhi Ji; Wen-Feng Zhang; Yong-Lai Lu; Li-Qun Zhang

doi:10.1007/s10118-021-2581-4

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Bubble-templated Construction of Three-dimensional Ceramic Network for Enhanced Thermal Conductivity of Silicone Rubber Composites

RAPID COMMUNICATION | Updated：2021-05-20

- Bubble-templated Construction of Three-dimensional Ceramic Network for Enhanced Thermal Conductivity of Silicone Rubber Composites
- Bubble-templated Construction of Three-dimensional Ceramic Network for Enhanced Thermal Conductivity of Silicone Rubber Composites
- Chinese Journal of Polymer Science 2021年39卷第7期页码：789-795
- Affiliations：
  
  a.State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China
  b.Beijing Key Laboratory of Wood Science and Engineering & MOE Key Laboratory of Wooden Material Science and Application, Beijing Forestry University, Beijing 100083, China
  c.Key Laboratory of Carbon Fiber and Functional Polymers, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029, China
  d.Engineering Research Center of Elastomer Materials Energy Conservation and Resources, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029, China
- Author bio：
  
  luyonglai@mail.buct.edu.cn
- Funds：
  
  The authors would like to appreciate the financial support from the Joint Foundation of Ministry of Education for equipment pre-research (No. 6141A020222XX) and Post-doctoral Science Fund (No. 2020M680405).
- DOI：10.1007/s10118-021-2581-4
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Shou-Jun Li, Jing-Chao Li, Pei-Zhi Ji, 等. Bubble-templated Construction of Three-dimensional Ceramic Network for Enhanced Thermal Conductivity of Silicone Rubber Composites[J]. Chinese Journal of Polymer Science, 2021,39(7):789-795.

Shou-Jun Li, Jing-Chao Li, Pei-Zhi Ji, et al. Bubble-templated Construction of Three-dimensional Ceramic Network for Enhanced Thermal Conductivity of Silicone Rubber Composites[J]. Chinese Journal of Polymer Science, 2021,39(7):789-795.
Shou-Jun Li, Jing-Chao Li, Pei-Zhi Ji, 等. Bubble-templated Construction of Three-dimensional Ceramic Network for Enhanced Thermal Conductivity of Silicone Rubber Composites[J]. Chinese Journal of Polymer Science, 2021,39(7):789-795. DOI： 10.1007/s10118-021-2581-4.

Shou-Jun Li, Jing-Chao Li, Pei-Zhi Ji, et al. Bubble-templated Construction of Three-dimensional Ceramic Network for Enhanced Thermal Conductivity of Silicone Rubber Composites[J]. Chinese Journal of Polymer Science, 2021,39(7):789-795. DOI： 10.1007/s10118-021-2581-4.

摘要

Abstract

With the continuous development of the electronics industry, the energy density of modern electronic devices increases constantly, thus releasing a lot of heat during operation. Modern electronic devices take higher and higher request to the thermal interface materials. Achieving high thermal conductivity needs to establish an interconnecting thermal conductivity network in the matrix. For this purpose, the suspension of Al,2,O,3, and curdlan was first foamed to construct a bubble-templated continuous ceramic framework. Owing to the rapid gelation property of curdlan, we can easily remove moisture by hot air drying. Finally, the high thermally conductive composites are prepared by vacuum impregnation of silicone rubber. The result showed that composites prepared by our method have higher thermal conductivity than the samples obtained by traditional method. The thermal conductivity of the prepared composite material reached 1.253 W·m,–1,·K,–1, when the alumina content was 69.6 wt%. This facile method is expected to be applied to the preparation of high-performance thermal interface materials.

关键词

Keywords

Thermally conductive networkAluminaCurdlanThermal conductivity

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