Recent Progress in Two-dimensional Nanomaterials Following Graphene for Improving Fire Safety of Polymer (Nano)composites

Wei Cai; Bi-Bo Wang; Xin Wang; Yu-Lu Zhu; Zhao-Xin Li; Zhou-Mei Xu; Lei Song; Wei-Zhao Hu; Yuan Hu

doi:10.1007/s10118-021-2575-2

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Recent Progress in Two-dimensional Nanomaterials Following Graphene for Improving Fire Safety of Polymer (Nano)composites

REVIEW | Updated：2021-05-27

- Recent Progress in Two-dimensional Nanomaterials Following Graphene for Improving Fire Safety of Polymer (Nano)composites
- Recent Progress in Two-dimensional Nanomaterials Following Graphene for Improving Fire Safety of Polymer (Nano)composites
- Chinese Journal of Polymer Science 2021年39卷第8期页码：935-956
- Affiliations：
  
  a.State Key Laboratory of Fire Science, University of Science and Technology of China, Hefei 230000, China
  b.Suzhou Advanced Research Institute, University of Science and Technology of China, Suzhou 215000, China
- Author bio：
  
  hwz1988@ustc.edu.cn (W.Z.H)
  yuanhu@ustc.edu.cn (Y.H.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 51761135113, 51911530127 and 51973203) and the Fundamental Research Funds for the Central Universities (No. WK2320000043).
- DOI：10.1007/s10118-021-2575-2
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Wei Cai, Bi-Bo Wang, Xin Wang, 等. Recent Progress in Two-dimensional Nanomaterials Following Graphene for Improving Fire Safety of Polymer (Nano)composites[J]. Chinese Journal of Polymer Science, 2021,39(8):935-956.

Wei Cai, Bi-Bo Wang, Xin Wang, et al. Recent Progress in Two-dimensional Nanomaterials Following Graphene for Improving Fire Safety of Polymer (Nano)composites[J]. Chinese Journal of Polymer Science, 2021,39(8):935-956.
Wei Cai, Bi-Bo Wang, Xin Wang, 等. Recent Progress in Two-dimensional Nanomaterials Following Graphene for Improving Fire Safety of Polymer (Nano)composites[J]. Chinese Journal of Polymer Science, 2021,39(8):935-956. DOI： 10.1007/s10118-021-2575-2.

Wei Cai, Bi-Bo Wang, Xin Wang, et al. Recent Progress in Two-dimensional Nanomaterials Following Graphene for Improving Fire Safety of Polymer (Nano)composites[J]. Chinese Journal of Polymer Science, 2021,39(8):935-956. DOI： 10.1007/s10118-021-2575-2.

摘要

Abstract

The high fire safety of polymer nanocomposites is being pursued by research institutions around the world. In addition to intrinsic flame retardancy strategy, the additive-type flame retardants have attracted increasing attention due to low commercial cost and easy fabrication craft. However, traditional additive-type flame retardants usually need high addition amount to achieve a desirable effect, which causes many side-effects on the overall performance of polymer materials, such as deteriorated mechanical property and processability. At present, two-dimensional (2D) nanomaterials have also been applied to reduce the fire hazards of polymer (nano)composites with the coupling of barrier function and catalysis as well as carbonization effect. Even though most research work mainly focus on graphene-based flame retardants, more emerging two-dimensional nanomaterials are taking away research attention, due to their complementary and unique properties, mainly including hexagonal boron nitride (h-BN), molybdenum disulfide (MoS,2,), metal organic frameworks (MOF), carbon nitride (CN), titanium carbide (MXene) and black phosphorene (BP). In this review, except for graphene, the flame retardant mechanism involving different layered nanomaterials are also reviewed. Meanwhile, the functionalization method and flame retardancy effect of different layered nanomaterials are emphatically discussed for offering an effective reference to solve the fire hazards of polymer materials. Moreover, this work objectively evaluates the practical significance of polymer/layered nanomaterials composites for industrial application.

关键词

Keywords

Polymer (nano)compositesLayered nanomaterialsFire safetyFlame retardant mechanism

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