Construction of Supramolecular Chirality in Polymer Systems: Chiral Induction, Transfer and Application

Xiao-Xiao Cheng; Teng-Fei Miao; Lu Yin; Wei Zhang; Xiu-Lin Zhu

doi:10.1007/s10118-021-2561-8

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Construction of Supramolecular Chirality in Polymer Systems: Chiral Induction, Transfer and Application

FEATURE ARTICLE | Updated：2021-05-31

- Construction of Supramolecular Chirality in Polymer Systems: Chiral Induction, Transfer and Application
- Construction of Supramolecular Chirality in Polymer Systems: Chiral Induction, Transfer and Application
- Chinese Journal of Polymer Science 2021年39卷第11期页码：1357-1375
- Affiliations：
  
  a.State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China
  b.State Key Laboratory of Radiation Medicine and Protection, Soochow University, Suzhou 215123, China
- Author bio：
  
  weizhang@suda.edu.cn
- Funds：
  
  The authors are grateful for the financial support from the National Natural Science Foundation of China (Nos. 21971180 and 92056111), Nature Science Key Basic Research of Jiangsu Province for Higher Education (No. 19KJA360006), Postgraduate Research & Practice Innovation Program of Jiangsu Province (No. KYCX20_2655), College Students’ Innovation and Entrepreneurship Program (No. 201910285021Z), the Priority Academic Program Development (PAPD) of Jiangsu Higher Education Institutions and the Program of Innovative Research Team of Soochow University. Prof. W. Zhang thanks Mr. J.Z. Wang in University of Waterloo for English editing.
- DOI：10.1007/s10118-021-2561-8
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Xiao-Xiao Cheng, Teng-Fei Miao, Lu Yin, 等. Construction of Supramolecular Chirality in Polymer Systems: Chiral Induction, Transfer and Application[J]. Chinese Journal of Polymer Science, 2021,39(11):1357-1375.

Xiao-Xiao Cheng, Teng-Fei Miao, Lu Yin, et al. Construction of Supramolecular Chirality in Polymer Systems: Chiral Induction, Transfer and Application[J]. Chinese Journal of Polymer Science, 2021,39(11):1357-1375.
Xiao-Xiao Cheng, Teng-Fei Miao, Lu Yin, 等. Construction of Supramolecular Chirality in Polymer Systems: Chiral Induction, Transfer and Application[J]. Chinese Journal of Polymer Science, 2021,39(11):1357-1375. DOI： 10.1007/s10118-021-2561-8.

Xiao-Xiao Cheng, Teng-Fei Miao, Lu Yin, et al. Construction of Supramolecular Chirality in Polymer Systems: Chiral Induction, Transfer and Application[J]. Chinese Journal of Polymer Science, 2021,39(11):1357-1375. DOI： 10.1007/s10118-021-2561-8.

摘要

Abstract

Chirality, commonly found in organisms, biomolecules and nature such as ,L,-amino acids and ,D,-sugars, has been extensively studied in chemistry and biomedical science. Hence, the demand for simple and efficient construction of chiral structures, especially chiral polymers, has been rapidly growing due to their potential applications in chemosensors, asymmetric catalysis and biological materials. However, most chiral polymers reported are prepared directly from chiral monomers/chiral catalysts, the corresponding strategies usually involve tedious and expensive design and synthesis. Fortunately, chirality induction strategies (such as circularly polarized light, chiral solvation and chiral gelation ,etc,.) have been known to be highly versatile and efficient in producing chirality from achiral polymers. In this feature article, the current research on chirality induction, transfer and application in achiral polymer systems is summarized. Furthermore, this article discusses some basic concepts, seminal studies, recent advances, the structural design principles, as well as perspectives in the construction and applications of chiral polymers derived from achiral monomers, with the hope to attract more interest from researchers and further advance the development of chiral chemistry.

关键词

Keywords

ChiralityChirality inductionAchiral polymerSupramolecular chemistrySelf-assembly

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