Geminal Cross Coupling (GCC) Reaction for AIE Materials

Qi Yu; Ya-Long Wang; Ze-Qiang Chen; Peng-Ju Zhao; Cheng Fan; Chong Li; Ming-Qiang Zhu

doi:10.1007/s10118-019-2207-2

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Geminal Cross Coupling (GCC) Reaction for AIE Materials

REVIEW | Updated：2021-02-18

- Geminal Cross Coupling (GCC) Reaction for AIE Materials
- Geminal Cross Coupling (GCC) Reaction for AIE Materials
- Chinese Journal of Polymer Science 2019年37卷第4期页码：327-339
- Affiliations：
  
  1.Wuhan National Laboratory for Optoelectronics, School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, China
- Author bio：
  
  chongli@hust.edu.cn (C.L.)
  mqzhu@hust.edu.cn (M.Q.Z.)
- Funds：
  
  This work was financially supported by the National Basic Research Program (973) of China (Nos. 2015CB755602 and 2013CB922104), the National Natural Science Foundation of China (Nos. 51673077, 21474034, and 51603078), the Fundamental Research Funds for the Central Universities (HUST: 2016YXMS029 and HUST: 2018KFYXKJC033), and the Nature Science Foundation of Hubei Province (No. 2018CFB574). We also thank the Analytical and Testing Center of Huazhong University of Science and Technology, the Center of Micro-Fabrication and Characterization (CMFC) and the Center for Nanoscale Characterization & Devices (CNCD) of WNLO for use of their facilities.
- DOI：10.1007/s10118-019-2207-2
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Qi Yu, Ya-Long Wang, Ze-Qiang Chen, 等. Geminal Cross Coupling (GCC) Reaction for AIE Materials[J]. Chinese Journal of Polymer Science, 2019,37(4):327-339.

Qi Yu, Ya-Long Wang, Ze-Qiang Chen, et al. Geminal Cross Coupling (GCC) Reaction for AIE Materials[J]. Chinese Journal of Polymer Science, 2019,37(4):327-339.
Qi Yu, Ya-Long Wang, Ze-Qiang Chen, 等. Geminal Cross Coupling (GCC) Reaction for AIE Materials[J]. Chinese Journal of Polymer Science, 2019,37(4):327-339. DOI： 10.1007/s10118-019-2207-2.

Qi Yu, Ya-Long Wang, Ze-Qiang Chen, et al. Geminal Cross Coupling (GCC) Reaction for AIE Materials[J]. Chinese Journal of Polymer Science, 2019,37(4):327-339. DOI： 10.1007/s10118-019-2207-2.

摘要

Abstract

Tetraphenylethylene (TPE) derivatives are typical aggregation-induced emission (AIE) molecules, which have been widely investigated and applicated. The Rathore’s procedures and McMurry reaction are the two frequently used methods for synthesizing the TPE derivatives. The complex processes and low tolerance of active function groups make the TPE with limited structures and properties in some degree. Very recently, a novel strategy, named geminal cross coupling (GCC) reaction, is developed for designing and synthesizing various topological small molecules and polymers with rich optical properties beyond simple TPE compounds, and becomes a powerful synthesis method to AIE materials. This review overviews the current progresses of AIE molecules and polymers prepared by GCC as well as their applications. We believe that GCC reaction will have a bright future in the development of the next generation of tetraarylethylene (TAE)-kind AIE materials.

关键词

Keywords

GCC reactionAIETetraarylethyleneConjugated polymerImaging

references

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