HEAT-RESISTANT PYRIDINE-BASED POLY(ETHER-ESTER)S: SYNTHESIS, CHARACTERIZATION AND PROPERTIES

Shahram Mehdipour-Ataei; Ali Mahmoodi

doi:10.1007/s10118-013-1192-0

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HEAT-RESISTANT PYRIDINE-BASED POLY(ETHER-ESTER)S: SYNTHESIS, CHARACTERIZATION AND PROPERTIES

PAPER | Updated：2023-01-03

- HEAT-RESISTANT PYRIDINE-BASED POLY(ETHER-ESTER)S: SYNTHESIS, CHARACTERIZATION AND PROPERTIES
- HEAT-RESISTANT PYRIDINE-BASED POLY(ETHER-ESTER)S: SYNTHESIS, CHARACTERIZATION AND PROPERTIES
- Chinese Journal of Polymer Science 2013年31卷第1期页码：171-178
- Affiliations：
  
  Department of Chemistry, Islamic Azad University, Karaj Branch, Karaj, Iran
- Author bio：
  
  *Shahram Mehdipour-Ataei, E-mail: s.mehdipour@ippi.ac.ir
- Funds：
- DOI：10.1007/s10118-013-1192-0
  中图分类号：
- 收稿：2012-02-24，
  
  修回：2012-04-07，
  
  录用：2012-04-12，
  
  纸质出版：2013-01
- Accepted：
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Shahram Mehdipour-Ataei, Ali Mahmoodi. HEAT-RESISTANT PYRIDINE-BASED POLY(ETHER-ESTER)S: SYNTHESIS, CHARACTERIZATION AND PROPERTIES[J]. Chinese Journal of Polymer Science, 2013,31(1):171-178.

Shahram Mehdipour-Ataei, Ali Mahmoodi. HEAT-RESISTANT PYRIDINE-BASED POLY(ETHER-ESTER)S: SYNTHESIS, CHARACTERIZATION AND PROPERTIES[J]. Chinese Journal of Polymer Science, 2013, 31(1): 171-178.
Shahram Mehdipour-Ataei, Ali Mahmoodi. HEAT-RESISTANT PYRIDINE-BASED POLY(ETHER-ESTER)S: SYNTHESIS, CHARACTERIZATION AND PROPERTIES[J]. Chinese Journal of Polymer Science, 2013,31(1):171-178. DOI： 10.1007/s10118-013-1192-0.

Shahram Mehdipour-Ataei, Ali Mahmoodi. HEAT-RESISTANT PYRIDINE-BASED POLY(ETHER-ESTER)S: SYNTHESIS, CHARACTERIZATION AND PROPERTIES[J]. Chinese Journal of Polymer Science, 2013, 31(1): 171-178. DOI： 10.1007/s10118-013-1192-0.

摘要

Abstract

A pyridine-based diacid was synthesized

via

nucleophilic substitution reaction of 4-hydroxy benzoic acid with 2

6- dichloropyridine in the presence of potassium carbonate. The diacid was characterized using FT-IR and

H-NMR spectroscopic methods and also with elemental analysis. Polycondensation reaction of the diacid with different diols including 1

4-dihydroxy benzene

5-dihydroxy naphthalene

bis-phenol A and bis-phenol-P resulted in preparation of pyridine-based poly(ether-ester)s. The polymers were characterized and their physical and thermal properties including inherent viscosity

molecular weight

solubility

thermal stability

thermal behavior and crystallinity were studied. They revealed high heat-resistance and improved solubility in polar solvents. Structure-property relations for the prepared polyester were also studied.

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