"SERGEANTS AND SOLDIERS RULE" IN HELICAL SUBSTITUTEDACETYLENE COPOLYMER EMULSIONS

Xuan Liu; Ci Song; Xiao-feng Luo; Wan-tai Yang; Jian-ping Deng

doi:10.1007/s10118-013-1189-8

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"SERGEANTS AND SOLDIERS RULE" IN HELICAL SUBSTITUTEDACETYLENE COPOLYMER EMULSIONS

PAPER | Updated：2023-01-03

- "SERGEANTS AND SOLDIERS RULE" IN HELICAL SUBSTITUTEDACETYLENE COPOLYMER EMULSIONS
- "SERGEANTS AND SOLDIERS RULE" IN HELICAL SUBSTITUTEDACETYLENE COPOLYMER EMULSIONS
- Chinese Journal of Polymer Science 2013年31卷第1期页码：179-186
- Affiliations：
  
  State Key Laboratory of Chemical Resource Engineering, College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
- Author bio：
  
  **Jian-ping Deng (邓建平), E-mail: dengjp@mail.buct.edu.cn
- Funds：
  
  National Natural Science Foundation of China(21174010;20974007);Fundamental Research Funds for the Central Universities(ZZ1117)
- DOI：10.1007/s10118-013-1189-8
  中图分类号：
- 收稿：2012-03-14，
  
  修回：2012-04-23，
  
  录用：2012-04-25，
  
  纸质出版：2013-01
- Accepted：
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Xuan Liu, Ci Song, Xiao-feng Luo, 等. "SERGEANTS AND SOLDIERS RULE" IN HELICAL SUBSTITUTEDACETYLENE COPOLYMER EMULSIONS[J]. Chinese Journal of Polymer Science, 2013,31(1):179-186.

Xuan Liu, Ci Song, Xiao-feng Luo, et al. "SERGEANTS AND SOLDIERS RULE" IN HELICAL SUBSTITUTEDACETYLENE COPOLYMER EMULSIONS[J]. Chinese Journal of Polymer Science, 2013, 31(1): 179-186.
Xuan Liu, Ci Song, Xiao-feng Luo, 等. "SERGEANTS AND SOLDIERS RULE" IN HELICAL SUBSTITUTEDACETYLENE COPOLYMER EMULSIONS[J]. Chinese Journal of Polymer Science, 2013,31(1):179-186. DOI： 10.1007/s10118-013-1189-8.

Xuan Liu, Ci Song, Xiao-feng Luo, et al. "SERGEANTS AND SOLDIERS RULE" IN HELICAL SUBSTITUTEDACETYLENE COPOLYMER EMULSIONS[J]. Chinese Journal of Polymer Science, 2013, 31(1): 179-186. DOI： 10.1007/s10118-013-1189-8.

摘要

Abstract

The "sergeants and soldiers rule" occurring in helical copolymer emulsions derived from an achiral monomer (M1) and a chiral monomer (M2) was observed. TEM

GPC

and

H-NMR techniques in combination demonstrate the formation of nanoparticles constituted by the copolymers. CD and UV-Vis spectra show the (co)polymer chains in the nanoparticles adopt helical structures of a predominant helicity

and the copolymers follow the "sergeants and soldiers rule" in forming helical structure.

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