SELF-ASSEMBLY OF LINEAR TRIBLOCK COPOLYMERS UNDER CYLINDRICAL NANOPORE CONFINEMENTS
PAPER|Updated:2023-01-03
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SELF-ASSEMBLY OF LINEAR TRIBLOCK COPOLYMERS UNDER CYLINDRICAL NANOPORE CONFINEMENTS
SELF-ASSEMBLY OF LINEAR TRIBLOCK COPOLYMERS UNDER CYLINDRICAL NANOPORE CONFINEMENTS
Chinese Journal of Polymer Science2013年31卷第1期 页码:122-138
Affiliations:
a.Department of Physics, Wenzhou University, Wenzhou 325035, China
b.Department of Physics, Zhejiang University, Hangzhou 310027, China
Author bio:
**Shi-ben Li (李士本), E-mail: shibenli@wzu.edu.cn
Funds:
General Program of National Natural Science Foundation of China(21174131;20974081;21074096;21104060);Natural Science Foundation of Zhejiang Province(Y4090174;Y6100033)
Wen-juan Qiu, Shi-ben Li, Yong-yun Ji, 等. SELF-ASSEMBLY OF LINEAR TRIBLOCK COPOLYMERS UNDER CYLINDRICAL NANOPORE CONFINEMENTS[J]. Chinese Journal of Polymer Science, 2013,31(1):122-138.
Wen-juan Qiu, Shi-ben Li, Yong-yun Ji, et al. SELF-ASSEMBLY OF LINEAR TRIBLOCK COPOLYMERS UNDER CYLINDRICAL NANOPORE CONFINEMENTS[J]. Chinese Journal of Polymer Science, 2013, 31(1): 122-138.
Wen-juan Qiu, Shi-ben Li, Yong-yun Ji, 等. SELF-ASSEMBLY OF LINEAR TRIBLOCK COPOLYMERS UNDER CYLINDRICAL NANOPORE CONFINEMENTS[J]. Chinese Journal of Polymer Science, 2013,31(1):122-138.DOI: 10.1007/s10118-013-1183-1.
Wen-juan Qiu, Shi-ben Li, Yong-yun Ji, et al. SELF-ASSEMBLY OF LINEAR TRIBLOCK COPOLYMERS UNDER CYLINDRICAL NANOPORE CONFINEMENTS[J]. Chinese Journal of Polymer Science, 2013, 31(1): 122-138.DOI: 10.1007/s10118-013-1183-1.
SELF-ASSEMBLY OF LINEAR TRIBLOCK COPOLYMERS UNDER CYLINDRICAL NANOPORE CONFINEMENTS
The self-assembly of linear ABC triblock copolymers under cylindrical confinements is investigated in twodimensional space using the real-space self-consistent field theory. The effects of confinement degrees and preferential strengths on the triblock copolymer phase behaviors with special polymer parameters are first considered. On one hand
different confinement degrees cause different phase behaviors in nanopores with the neutral surfaces. Moreover
the strongly preferential surface fields can surpass the confinement degrees and volume fractions in determing the confined phase behaviors. On the other hand
in contrast
confined morphologies are more sensitive to the variations in the A-preferential surface field strength. Subsequently
the incompatibility degrees between different blocks are systematically varied under cylindrical nanopore confinements. Under cylindrical nanopore confinements
the morphologies are very sensitive to the variations in the incompatibility degrees. Meanwhile
nanopore confinements can affect order-disorder and order-order transition points in the bulk. The corresponding free
internal
and entropic energies as well as the order parameters are also quantificationally examined to deeply investigate the confined phase mechanisms
and a number of morphological transitions are confirmed to be of first-order. These findings may guide the design of novel nanostructures based on triblock copolymers by introducing confinements.
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相关作者
Ling Zhao
Zhi-Yuan Yin
Jia-Di Jiang
Er-Qiang Chen
Shuang Yang
Bin Zhao
Mei-Jiao Liu
Chao Wang
相关机构
Beijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Center for Soft Mater Science and Engineering, College of Chemistry and Molecular Engineering, Peking University
Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University
Department of Physics, Taizhou University
Key Laboratory of Computational Physical Science, Fudan University
Department of Chemistry, Zhejiang Sci-Tech University