EFFECT OF POLYMERIZATION CONDITIONS ON THE LADDERLIKE STRUCTURE OF POLYPHENYLSILSESQUIOXANE

LI Guizhi; 施良和; SHI Lianghe; YE Meiling

Your Location：

Home >

Browse articles >

EFFECT OF POLYMERIZATION CONDITIONS ON THE LADDERLIKE STRUCTURE OF POLYPHENYLSILSESQUIOXANE

Papers | Updated：2021-06-21

- EFFECT OF POLYMERIZATION CONDITIONS ON THE LADDERLIKE STRUCTURE OF POLYPHENYLSILSESQUIOXANE
- EFFECT OF POLYMERIZATION CONDITIONS ON THE LADDERLIKE STRUCTURE OF POLYPHENYLSILSESQUIOXANE
- 高分子科学（英文版） 1996年14卷第1期页码：41-47
- Affiliations：
  
  1.   Polymer Physics Laboratory
  2.   Institute of Chemistry
  3.   Academia Sinica
  4.   Beijing 100080
- Author bio：
- Funds：
- DOI：
  中图分类号：
Scan for full text
LI Guizhi, 施良和, SHI Lianghe, 等. EFFECT OF POLYMERIZATION CONDITIONS ON THE LADDERLIKE STRUCTURE OF POLYPHENYLSILSESQUIOXANE[J]. 高分子科学（英文版）, 1996,14(1):41-47.

LI Guizhi, SHI Lianghe, YE Meiling. EFFECT OF POLYMERIZATION CONDITIONS ON THE LADDERLIKE STRUCTURE OF POLYPHENYLSILSESQUIOXANE[J]. 1996,14(1):41-47.
LI Guizhi, 施良和, SHI Lianghe, 等. EFFECT OF POLYMERIZATION CONDITIONS ON THE LADDERLIKE STRUCTURE OF POLYPHENYLSILSESQUIOXANE[J]. 高分子科学（英文版）, 1996,14(1):41-47. DOI：

LI Guizhi, SHI Lianghe, YE Meiling. EFFECT OF POLYMERIZATION CONDITIONS ON THE LADDERLIKE STRUCTURE OF POLYPHENYLSILSESQUIOXANE[J]. 1996,14(1):41-47. DOI：

摘要

<,正,>, The ladderlike structure of PPSQ synthesized by using four kinds of catalysts （MgF,2,LiF, KOH and DCC） at different polymerization conditions has been investigated by IRand NMR. In the system using MgF,2, as the main catalyst, the most important factorwhich affects the ladderlike structure of PPSQ is the composition of the dual catalysts,MgF,2, and DCC. PPSQ prepared by using KOH as the catalyst has the highest regularityof ladderlike structure among all samples. PPSQ with different degree of ladder regularitycan be obtained by choice of polymerization conditions.

Abstract

The ladderlike structure of PPSQ synthesized by using four kinds of catalysts （MgF,2,LiF, KOH and DCC） at different polymerization conditions has been investigated by IRand NMR. In the system using MgF,2, as the main catalyst, the most important factorwhich affects the ladderlike structure of PPSQ is the composition of the dual catalysts,MgF,2, and DCC. PPSQ prepared by using KOH as the catalyst has the highest regularityof ladderlike structure among all samples. PPSQ with different degree of ladder regularitycan be obtained by choice of polymerization conditions.

关键词

Keywords

references

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

暂无数据