THIRD ORDER NONLINEAR OPTICAL PROPERTIES OF PERNIGRANILINE SOLUTION IN CONCENTRATED SULFURIC ACID*

WAN Meixiang; Li Ming; MI Xin; JIANG Qian; YE Peixian

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THIRD ORDER NONLINEAR OPTICAL PROPERTIES OF PERNIGRANILINE SOLUTION IN CONCENTRATED SULFURIC ACID*

Papers | Updated：2021-06-21

- THIRD ORDER NONLINEAR OPTICAL PROPERTIES OF PERNIGRANILINE SOLUTION IN CONCENTRATED SULFURIC ACID*
- THIRD ORDER NONLINEAR OPTICAL PROPERTIES OF PERNIGRANILINE SOLUTION IN CONCENTRATED SULFURIC ACID*
- 高分子科学（英文版） 1996年14卷第1期页码：80-85
- Affiliations：
  
  1.   Institute of Chemistry
  2.   Academia Sinica
  3.   Beijing 100080
  4.   Institute of Physics
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WAN Meixiang, Li Ming, MI Xin, 等. THIRD ORDER NONLINEAR OPTICAL PROPERTIES OF PERNIGRANILINE SOLUTION IN CONCENTRATED SULFURIC ACID*[J]. 高分子科学（英文版）, 1996,14(1):80-85.

WAN Meixiang, Li Ming, MI Xin, et al. THIRD ORDER NONLINEAR OPTICAL PROPERTIES OF PERNIGRANILINE SOLUTION IN CONCENTRATED SULFURIC ACID*[J]. 1996,14(1):80-85.
WAN Meixiang, Li Ming, MI Xin, 等. THIRD ORDER NONLINEAR OPTICAL PROPERTIES OF PERNIGRANILINE SOLUTION IN CONCENTRATED SULFURIC ACID*[J]. 高分子科学（英文版）, 1996,14(1):80-85. DOI：

WAN Meixiang, Li Ming, MI Xin, et al. THIRD ORDER NONLINEAR OPTICAL PROPERTIES OF PERNIGRANILINE SOLUTION IN CONCENTRATED SULFURIC ACID*[J]. 1996,14(1):80-85. DOI：

摘要

<,正,>, The fully oxidized state of polyaniline （PANI）, pernigraniline （PN）, was synthesizedby oxidation of the emeraldine base form of PANI dissolved in NMP solvent with m-chloroperoxybenzoic acid. The resulted PN was characterized by FTIR and UV-Visiblespectra. The third-order nonlinear optical properties of PN in concentrated sulfuric acid（PN/H,2,SO,4,） were measured by a degenerated four wave mixing （DFWM） method. The re-sults obtained suggest that the soliton-pair intermediate state associated with thedegenerated state does not play a major role in the third order nonlinear optical prop-erties of PANI.

Abstract

The fully oxidized state of polyaniline （PANI）, pernigraniline （PN）, was synthesizedby oxidation of the emeraldine base form of PANI dissolved in NMP solvent with m-chloroperoxybenzoic acid. The resulted PN was characterized by FTIR and UV-Visiblespectra. The third-order nonlinear optical properties of PN in concentrated sulfuric acid（PN/H,2,SO,4,） were measured by a degenerated four wave mixing （DFWM） method. The re-sults obtained suggest that the soliton-pair intermediate state associated with thedegenerated state does not play a major role in the third order nonlinear optical prop-erties of PANI.

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