1. Department of Chamistry, Wuhan University, Wuhan) KUMANOTANI JU
2. Wuhan University
3. Wuhan
4. Faculty of Engineering
5. Ehime University
6. Japan
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ZHANG Lina, DU Yumin, KUMANOTANI JU. LIGHT SCATTERING OF POLYSACCHARIDE FROM LACQUER IN AQUEOUS SOLUTION[J]. 高分子科学(英文版), 1989,7(3):252-257.
ZHANG Lina, DU Yumin, KUMANOTANI JU. LIGHT SCATTERING OF POLYSACCHARIDE FROM LACQUER IN AQUEOUS SOLUTION[J]. 1989,7(3):252-257.
<,正,>, The polysaccharide having weight-average molecular weight M,w,=1. 09×10,5, isolated from the sap of lac trees (Vietnam), was separated into 12 fractions by aqueous-phase preparative gel permeation chromatography. The molecular weights and molecular weight distributions of the fractions were measured in aqueous 0.08M KCl/0.01 M NaAc and 0.4M KCl/0.05M NaAc at pH =7. 6 by light scattering, viscometry and gel permeation chromatography. The Mark-Houwink equation in aqueous 0.08M KCl/0.01M NaAc at 30℃was found to be [η]= 2.28×10,-2, M,w,0.52, (cm,3,/g), which indicated the polysaccharide chain in the aqueous solution to be a spherical random coil.
The polysaccharide having weight-average molecular weight M,w,=1. 09×10,5, isolated from the sap of lac trees (Vietnam), was separated into 12 fractions by aqueous-phase preparative gel permeation chromatography. The molecular weights and molecular weight distributions of the fractions were measured in aqueous 0.08M KCl/0.01 M NaAc and 0.4M KCl/0.05M NaAc at pH =7. 6 by light scattering, viscometry and gel permeation chromatography. The Mark-Houwink equation in aqueous 0.08M KCl/0.01M NaAc at 30℃ was found to be [η]= 2.28×10,-2, M,w,0.52, (cm,3,/g), which indicated the polysaccharide chain in the aqueous solution to be a spherical random coil.
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