School of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, China
yfzhu@zstu.edu.cn (Y.F.Z.)
hywang@zstu.edu.cn (H.Y.W.)
收稿:2026-02-28,
修回:2026-04-19,
录用:2026-04-25,
网络首发:2026-08-19,
纸质出版:2026-06
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Ni, X. Q.; Xu, X. Y.; Zhu, Y. F.; Wang, H. Y. High-strength and electrically stable aramid nanofibers/multi-walled carbon nanotubes/polyaniline hybrid fibers for flexible electromagnetic absorption performance. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-026-3727-1
Xiao-Qi Ni, Xiang-Yang Xu, Yao-Feng Zhu, et al. High-strength and Electrically Stable Aramid Nanofibers/Multi-walled Carbon Nanotubes/Polyaniline Hybrid Fibers for Flexible Electromagnetic Absorption Performance[J/OL]. Chinese Journal of Polymer Science, 2026, 441-10.
Ni, X. Q.; Xu, X. Y.; Zhu, Y. F.; Wang, H. Y. High-strength and electrically stable aramid nanofibers/multi-walled carbon nanotubes/polyaniline hybrid fibers for flexible electromagnetic absorption performance. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-026-3727-1 DOI:
Xiao-Qi Ni, Xiang-Yang Xu, Yao-Feng Zhu, et al. High-strength and Electrically Stable Aramid Nanofibers/Multi-walled Carbon Nanotubes/Polyaniline Hybrid Fibers for Flexible Electromagnetic Absorption Performance[J/OL]. Chinese Journal of Polymer Science, 2026, 441-10. DOI: 10.1007/s10118-026-3727-1.
The rapid advancement of communication technologies and wearable applications has increased the demand for high-performance flexible electromagnetic wave absorption materials. Conventional conductive fibers are often constrained by their poor wearability
weak interfacial stability
and limited absorption efficiency
which restrict their reliability and practical applicability in dynamic environments. Herein
a flexible and robust electromagnetic-absorbing fiber was successfully fabricated
via
wet spinning techniques
which integrates multi-walled carbon nanotubes (MWCNTs)
polyaniline (PANI)
and aramid nanofibers (ANFs). Polymerization of PANI on the MWCNTs surface is employed to optimize impedance matching and enhance interfacial compatibility
while ANFs serve as a continuous structural skeleton
improving the mechanical strength and spinnability. The resulting composite fibers exhibited a tensile strength of (202.0±8.0) MPa and an elongation at break of 13.6%±0.9%
stable electrical conductivity under mechanical deformation
and ultrasonic cleaning. Notably
the fiber architecture enables superior electromagnetic wave absorption
achieving a minimum reflection loss of −62.07 dB and an effective bandwidth of 3.24 GHz compare
d to the powder counterparts
owing to the extended propagation path and multiple scattering within the aligned fiber network. In addition
the composite fibers demonstrated self-extinguishing behavior during combustion
reflecting their inherent flame-retardant characteristics. This study provides a feasible strategy for developing flexible
high-performance electromagnetic wave (EMW)-absorbing fibers for next-generation protective textile materials.
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