Circularly Polarized Luminescence Based on Helical Polymers: Structure-Property Relationships and Regulation Mechanisms

Ao-Qi Wang; Xiao-Bin Gao; Biao Zhao; Jian-Ping Deng

doi:10.1007/s10118-026-3712-8

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Circularly Polarized Luminescence Based on Helical Polymers: Structure-Property Relationships and Regulation Mechanisms

Special Topic: Chirality in Polymers | Updated：2026-08-31

- Circularly Polarized Luminescence Based on Helical Polymers: Structure-Property Relationships and Regulation Mechanisms
- Circularly Polarized Luminescence Based on Helical Polymers: Structure-Property Relationships and Regulation Mechanisms
- Chinese Journal of Polymer Science 2026年44卷第9期页码：2810-2823
- Affiliations：
  
  Key Laboratory of Chemical Resource Engineering, College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
- Author bio：
  
  zhaobiao@buct.edu.cn (B.Z.)
  dengjp@mail.buct.edu.cn (J.P.D.)
- Funds：
  
  This study was financially supported by the National Natural Science Foundation of China (No. 52273165).;Biao Zhao is currently an associate professor at Beijing University of Chemical Technology (BUCT, China). He received his Ph.D. degree in the College of Materials Science and Engineering from BUCT in 2019, under the supervision of Prof. Jianping Deng. From 2019 to 2021, he worked as a Postdoctoral Fellow in Beijing Advanced Innovation Center for Soft Matter Science and Engineering at BUCT. His current research focuses on chiral polymer functional materials and photoelectric devices.Jian-Ping Deng is currently a professor at Beijing University of Chemical Technology (BUCT, China). His current research interests cover design and synthesis of chiral polymers, chiral hybrid materials, and biobased/biomimetic chiral polymeric materials, and exploration of chiral applications thereof.The authors declare no interest conflict.
- DOI：10.1007/s10118-026-3712-8
  中图分类号：
- 收稿：2026-03-12，
  
  录用：2026-04-13，
  
  网络首发：2026-06-26，
  
  纸质出版：2026-09-05
- Accepted：
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Wang, A. Q.; Gao, X. B.; Zhao, B.; Deng, J. P. Circularly polarized luminescence based on helical polymers: structure-property relationships and regulation mechanisms. Chinese J. Polym. Sci. 2026, 44, 2810–2823

Ao-Qi Wang, Xiao-Bin Gao, Biao Zhao, et al. Circularly Polarized Luminescence Based on Helical Polymers: Structure-Property Relationships and Regulation Mechanisms[J]. Chinese Journal of Polymer Science, 2026, 44(9): 2810-2823.
Wang, A. Q.; Gao, X. B.; Zhao, B.; Deng, J. P. Circularly polarized luminescence based on helical polymers: structure-property relationships and regulation mechanisms. Chinese J. Polym. Sci. 2026, 44, 2810–2823 DOI： 10.1007/s10118-026-3712-8.

Ao-Qi Wang, Xiao-Bin Gao, Biao Zhao, et al. Circularly Polarized Luminescence Based on Helical Polymers: Structure-Property Relationships and Regulation Mechanisms[J]. Chinese Journal of Polymer Science, 2026, 44(9): 2810-2823. DOI： 10.1007/s10118-026-3712-8.

摘要

This schematic categorizes helical-polymer-based CPL materials into monocomponent

multicomponent

and hybrid systems

while elucidating the pivotal mechanisms that dictate chiroptical amplification

including chirality transfer

responsive inversion

and photonic modulation. These insights provide a systemic blueprint for rational integration of high-performance chiroptical systems with tailored properties.

Abstract

Circularly polarized luminescence (CPL) materials have attracted considerable attention because of their unique chiroptical properties and promising applications. However

the simultaneous achievement of a high luminescence dissymmetry factor (

lum

)

high photoluminescence quantum yield

excellent processability

and environmental stability remains challenging. Chiral helical polymers

featuring single-handed helical conformations

have emerged as versatile and powerful platforms for constructing high-performance CPL systems by utilizing their inherent chiral amplification effects

tunable conformational dynamics

and ability to form hierarchically ordered structures. This review systematically summarizes recent advances in CPL materials based on chiral helical polymers

focusing on the regulation of chiroptical properties through polymer conformation

mesoscopic ordered structures

and photophysical pathways. CPL systems are categorized into th

ree main classes: monocomponent chiral helical polymers

multi-component organic composites

and organic-inorganic hybrids. For each category

representative molecular design strategies

fabrication methodologies

and CPL performance were elaborated

emphasizing the underlying structure-property relationships. The key mechanisms governing CPL generation and amplification are discussed in depth

including chirality transfer

solvent- and state-dependent chiral inversion

selective absorption/filtering

and cholesteric liquid-crystal-mediated photonic amplification. Furthermore

representative breakthroughs

such as near-infrared CPL

room-temperature phosphorescence

and long-persistent CPL

are highlighted. Finally

the current challenges and future directions are outlined

providing a guideline for the rational design and practical application of next-generation helical polymer-based CPL materials.

关键词

Keywords

references

Zhang, Y.; Yu, S.; Han, B.; Zhou, Y.; Zhang, X.; Gao, X.; Tang, Z. Circularly polarized luminescence in chiral materials. Matter 2022 , 5 , 837−875..

Sánchez-Carnerero, E. M.; Agarrabeitia, A. R.; Moreno, F.; Maroto, B. L.; Muller, G.; Ortiz, M. J.; de la Moya S. Circularly polarized luminescence from simple organic molecules. Chem. Eur. J. 2015 , 21 , 13488−13500..

Tanaka, H.; Inoue, Y.; Mori, T. Circularly polarized luminescence and circular dichroisms in small organic molecules: correlation between excitation and emission dissymmetry factors. ChemPhotoChem 2018 , 2 , 386−402..

Wu, H.; Zhou, Y.; Yin, L.; Hang, C.; Li, X.; Ågren, H.; Yi, T.; Zhang, Q .; Zhu, L. Helical self-assembly-induced singlet–triplet emissive switching in a mechanically sensitive system. J. Am. Chem. Soc. 2017 , 139 , 785−791..

Zhang, C.; Li, S.; Dong, X. Y.; Zang, S. Q. Circularly polarized luminescence of agglomerate emitters. Aggregate 2021 , 2 , e48..

Sánchez-Carnerero, E. M.; Moreno, F.; Maroto, B. L.; Agarrabeitia, A. R.; Ortiz, M. J.; Vo, B. G.; Muller, G.; Moya, S. D. l. Circularly polarized luminescence by visible-light absorption in a chiral O-BODIPY dye: unprecedented design of CPL organic molecules from achiral chromophores. J. Am. Chem. Soc. 2014 , 136 , 3346−3349..

Zheng, H.; Li, W.; Li, W.; Wang, X.; Tang, Z.; Zhang, S. X. A.; Xu, Y. Uncovering the circular polarization potential of chiral photonic cellulose films for photonic applications. Adv. Mater. 2018 , 30 , 1705948..

Shi, Y.; Han, J.; Jin, X.; Miao, W.; Zhang, Y.; Duan, P. Chiral luminescent liquid crystal with multi-state-reversibility: breakthrough in advanced anti-counterfeiting materials. Adv. Sci. 2022 , 9 , 2201565..

Liu, M.; Yang, C.; Li, S.; Zhang, X.; Hu, W. Recent advances in organic stimuli-responsive tunable circularly polarized luminescence materials. J. Mater. Chem. C 2025 , 13 , 12584−12611..

Mavragani, N.; Gálico, D. A.; Kitos, A. A.; Murugesu, M. Near-infrared magnetic circularly polarized luminescence and slow magnetic relaxation in a tetrazinyl-bridged erbium metallocene. J. Am. Chem. Soc. 2025 , 147 , 1387−1391..

Wu, X.; Yan, X.; Chen, Y.; Zhu, W.; Chou, P. T. Advances in organic materials for chiral luminescence-based OLEDs. Trends Chem. 2023 , 5 , 734−747..

Zinna, F.; Giovanella, U.; Bari, L. D. Highly circularly polarized electroluminescence from a chiral europium complex. Adv. Mater. 2015 , 27 , 1791−1795..

Zhang, M. J.; Guo, Q; Li, Z. Y.; Zhou, Y. J.; Zhao, S. S.; Tong, Z; Wang, Y. X.; Li, G. E.; Jin, S.; Yu, S. H. Processable circularly polarized luminescence material enables flexible stereoscopic 3d imaging. Sci. Adv. 2023 , 9 , eadi9944..

Schadt, M. Liquid crystal materials and liquid crystal displays. Annu. Rev. 1997 , 27 , 305−379..

Dhbaibi, K.; Abella, L.; Meunier-Della-Gatta, S.; Roisnel, T.; Vanthuyne, N.; Jamoussi, B.; Pieters, G.; Racine, B.; Quesnel, E.; Autschbach, J.; Crassous, J.; Favereau, L. Achieving high circularly polarized luminescence with push–pull helicenic systems: from rationalized design to top-emission CP-OLED applications. Chem. Sci. 2021 , 12 , 5522−5533..

Chekini, M.; Prince, E.; Zhao, L.; Mundoor, H.; Smalyukh, I. I.; Kumacheva, E. Chiral Carbon dots synthesized on cellulose nanocrystals. Adv. Opt. Mater. 2019 , 8 , 1901911..

Loskutova, A.; Seitkali, A.; Aliyev, D.; Bukasov, R. Quantum dot-based luminescent sensors: review from analytical perspective. Int. J. Mol. Sci. 2025 , 26 , 6674..

Xu, B.; Jin, C.; Park, J. S.; Liu, H.; Lin, X.; Cui, J.; Chen, D.; Qiu, J. Emerging near-infrared luminescent materials for next-generation broadband optical communications. InfoMat. 2024 , 6 , e12550..

Heffern, M. C.; Matosziuk, L. M.; Meade, T. J. Lanthanide probes for bioresponsive imaging. Chem. Rev. 2013 , 114 , 4496−4539..

Tan, R.; Wu, J.; Wang, C.; Zhao, Z.; Zhang, X.; Zhong, C.; Tang, Z.; Zheng, R.; Du, B.; He, Y.; Sun, Y.; Zhou, P. The develop of persistent luminescence nanoparticles with excellent performances in cancer targeted bioimaging and killing: a review. J. Nanobiotechnol. 2025 , 23 , 299..

Zhao, W.; He, Z.; Tang, B. Z. Room-temperature phosphorescence from organic aggregates. Nat. Rev. Mater. 2020 , 5 , 869−885..

Sato, I.; Sugie, R.; Matsueda, Y.; Furumura, Y.; Soai, K. Asymmetric synthesis utilizing circularly polarized light mediated by the photoequilibrium of chiral olefins in conjunction with asymmetric autocatalysis. Angew. Chem. Int. Ed. 2004 , 43 , 4490−4492..

Zhou, L.; He, K.; Liu, N.; Wu, Z. Q. Recent advances in asymmetric organocatalysis based on helical polymers. Polym. Chem. 2022 , 13 , 3967−3974..

Ikai, T.; Ando, M.; Ito, M.; Ishidate, R.; Suzuki, N.; Maeda, K.; Yashima, E. Emergence of highly enantioselective catalytic activity in a helical polymer mediated by deracemization of racemic pendants. J. Am. Chem. Soc. 2021 , 143 , 12725−12735..

Kawasaki, T; Sato, M; Ishiguro, S; Saito, T; Morishita, Y; Sato, I; Nishino, H; Inoue, Y; Soai, K. Enantioselective synthesis of near enantiopure compound by asymmetric autocatalysis triggered by asymmetric photolysis with circularly polarized light. J. Am. Chem. Soc. 2005 , 127 , 3274−3275..

Ni, H.; Chan, W.-L.; Lu, Y. Phosphine-catalyzed asymmetric organic reactions. Chem. Rev. 2018 , 118 , 9344−9411..

He, C.; Yang, G.; Kuai, Y.; Shan, S.; Yang, L.; Hu, J.; Zhang, D.; Zhang, Q.; Zou, G. Dissymmetry enhancement in enantioselective synthesis of helical polydiacetylene by application of superchiral light. Nat. Commun. 2018 , 9 , 5117..

Liu, Q.; Ren, H.; Wei, Q.; Li, M. Multifunctional chiral halide perovskites: advancing chiro-optics, chiro-optoelectronics, and spintronics. Adv. Sci. 2025 , 12 , e09155..

Wang, Y.; Niu, D.; Ouyang, G.; Liu, M. Double helical π-aggregate nanoarchitectonics for amplified circularly polarized luminescence. Nat. Commun. 2022 , 13 , 1710..

Ma, S.; Zhao, B.; Deng, J. Helical polymer working as a chirality amplifier to generate and modulate multicolor circularly polarized luminescence in small molecular fluorophore/polymer composite films. ACS Cent. Sci. 2023 , 9 , 1409−1418..

Li, J.; Hou, C.; Huang, C.; Xu, S.; Peng, X.; Qi, Q.; Lai, W. Y.; Huang, W. Boosting circularly polarized luminescence of organic conjugated systems via twisted intramolecular charge transfer. Research (Wash. D C) 2020 , 2020 , 3839160..

Yu, M.; Huang, R.; Guo, J.; Zhao, Z.; Tang, B. Z. Promising applications of aggregation-induced emission luminogens in organic optoelectronic devices. PhotoniX 2020 , 1 , 11..

He, Y.; Lin, S.; Guo, J.; Li, Q. Circularly polarized luminescent self-organized helical superstructures: from materials and stimulus-responsiveness to applications. Aggregate 2021 , 2 , e141..

Zhang, X.; Xu, Y.; Valenzuela, C.; Zhang, X.; Wang, L.; Feng, W.; Li, Q. Liquid crystal-templated chiral nanomaterials: from chiral plasmonics to circularly polarized luminescence. Light-Sci. Appl. 2022 , 11 , 223..

Yang, X.; Jin, X.; Zhao, T.; Duan, P. Circularly polarized luminescence in chiral nematic liquid crystals: generation and amplification. Mater. Chem. Front. 2021 , 5 , 4821−4832..

Zhong, H.; Zhang, Y.; Deng, J. Optically active porous hybrid particles constructed by alkynylated cellulose nanocrystals, helical substituted polyacetylene, and inorganic silica for enantio-differentiating towards naproxen. Chirality 2022 , 34 , 48−60..

Sang, Y.; Han, J.; Zhao, T.; Duan, P.; Liu, M. Circularly polarized luminescence in nanoassemblies: generation, amplification, and application. Adv Mater. 2020 , 32 , 1900110..

Kumar, J.; Nakashima, T.; Kawai, T. Circularly polarized luminescence in chiral molecules and supramolecular assemblies. Phys. Chem. Lett. 2015 , 6 , 3445−3452..

Wong, H. Y.; Lo, W. S.; Yim, K. H.; Law, G. L. Chirality and chiroptics of lanthanide molecular and supramolecular assemblies. Chem 2019 , 5 , 3058−3095..

Zhao, J.; Xing, P. Regulation of circularly polarized luminescence in multicomponent supramolecular coassemblies. ChemPhotoChem 2022 , 6 , e202100124..

[Zhong, H.; Gao, X.; Zhao, B.; Deng, J. “Matching Rule” for generation, modulation and amplification of circularly polarized luminescence. Acc. Chem. Res . 2024, 57 , 1188-1201..

Ikai, T.; Shimizu, S.; Awata, S.; Kudo, T.; Yamada, T.; Maeda, K.; Kanoh, S. Synthesis and chiroptical properties of a π-conjugated polymer containing glucose-linked biphenyl units in the main chain capable of folding into a helical conformation. Polym. Chem. 2016 , 7 , 7522−7529..

Arashiba, K.; Eizawa, A.; Tanaka, H.; Nakajima, K.; Yoshizawa, K.; Nishibayashi, Y. Catalytic nitrogen fixation via direct cleavage of nitrogen–nitrogen triple bond of molecular dinitrogen under ambient reaction conditions. Bull. Chem. Soc. Jpn. 2017 , 90 , 1111−1118..

Ikai, T.; Awata, S; Shinohara, K.-i. Synthesis of a helical π-conjugated polymer with a dynamic hydrogen-bonded network in the helical cavity and its circularly polarized luminescence properties. Polym. Chem. 2018 , 9 , 1541−1546..

Ikai, T.; Shimizu, S.; Awata, S; Shinohara, K.-i. Chiral amplification in π-conjugated helical polymers with circularly polarized luminescence. Macromolecules 2018 , 51 , 2328−2334..

Ikai, T.; Minami, S.; Awata, S.; Shimizu, S.; Yoshida, T.; Okubo, M; Shinohara, K.-i. Helicity control of π-conjugated foldamers containing d-glucose-based single enantiomeric units as a chiral source. Polym. Chem. 2018 , 9 , 5504−5510..

Ikai, T.; Takayama, K.; Wada, Y.; Minami, S.; Apiboon, C; Shinohara, K.-i. Synthesis of a one-handed helical polythiophene: a new approach using an axially chiral bithiophene with a fixed syn-conformation. Chem. Sci. 2019 , 10 , 4890−4895..

[Xu, T.-T.; Li, S.-Y.; Li, T.-T.; Zong, Y.; Chen, Z.; Li u, N; Wu, Z.-Q. “One-Stop” polymer circularly polarized luminescence platform: easy construction of full-color circularly polarized luminescent materials. Polym. Chem . 2025, 16 , 4062-4068..

Jiang, T.; Zhang, Y.; Hua, L.; Li, H.; Zhao, J.; Yan, S; Ren, Z. Helical polyisocyanides with thermally activated delayed fluorescence pendants for efficient circularly polarized light emission and detection. Mater. Sci. Eng. R Rep. 2024 , 160 , 100818..

Zhong, H.; Zhao, B; Deng,J. Solvent-dependent chirality transmission and amplification from cellulose derivative to achiral helical polymer for achieving full-color and white circularly polarized luminescence. Angew. Chem. Int. Ed. 2025 , 64 , e202418463..

Pan, M.; Zhao, R.; Zhao, B; Deng, J. Two chirality transfer channels assist handedness inversion and amplification of circularly polarized luminescence in chiral helical polyacetylene thin films. Macromolecules 2021 , 54 , 5043−5052..

Zhao, B.; Pan, K; Deng, J. Intense circularly polarized luminescence contributed by helical chirality of monosubstituted polyacetylenes. Macromolecules 2018 , 51 , 7104−7111..

Lu, N.; Gao, X.; Pan, M.; Zhao, B; Deng, J. Aggregation-induced emission-active chiral helical polymers show strong circularly polarized luminescence in thin films. Macromolecules 2020 , 53 , 8041−8049..

Wang, S.; Sun, X.; Zeng, H.; Xie, S.; Zhang, J; Wan, X. Postpolymerization modification-induced chiral self-assembly of substituted poly(phenylacetylene)s based on cis–transoid to cis–cisoid helical transition. Macromolecules 2025 , 58 , 1235−1244..

Yu, P.; Zhao, W.; Huang, Y.; Zeng, H.; Wan, X; Zhang, J. Edge-directed rapid chiral assembly of gold nanorods by 2D hexagonal nanosheets of helical poly(phenylacetylene)s and the synergistic communication of circularly polarized luminescence. J. Mater. Chem. C 2025 , 13 , 7502−7508..

Wang, S.; Hu, D.; Guan, X.; Cai, S.; Shi, G.; Shuai, Z.; Zhang, J.; Peng, Q; Wan, X. Brightening up circularly polarized luminescence of monosubstituted polyacetylene by conformation control: mechanism, switching, and sensing. Angew. Chem. Int. Ed. 2021 , 60 , 21918−21926..

[Cai, S.; Huang, Y.; Xie, S.; Wang, S.; Guan, Y.; Wan, X; Zhang, J. 2D hexagonal assemblies of amphiphilic double-helical poly(phenylacetylene) homopolymers with enhanced circularly polarized luminescence and chiral self-sorting. Angew. Chem. Int. Ed . 2022, 61 , e202214293..

Wang, S.; Xie, S.; Zeng, H.; Du, H.; Zhang, J; Wan, X. Self-reporting activated ester-amine reaction for enantioselective multi-channel visual detection of chiral amines. Angew. Chem. Int. Ed. 2022 , 61 , e202202268..

Tarrío, J. J.; Rodríguez, R.; Fernández, B.; Quiñoá, E; Freire, F. Dissymmetric chiral poly(diphenylacetylene)s: secondary structure elucidation and dynamic luminescence. Angew. Chem. Int. Ed. 2022 , 61 , e202115070..

Tarrío, J. J.; Hermida, B.; Rodríguez, R.; Crassous, J.; Quiñoá, E; Freire, F. Consecutive complex aggregation pathway in covalent helical polymer-metal complexes: nanospheres with controlled P/M macroscopic chirality. Small 2025 , 21 , 2409379..

Zou, H.; Liu, W.; Wang, C.; Zhou, L.; Liu, N; Wu, Z.-Q. Polyfluorene-block-poly(phenyl isocyanide) copolymers: one-pot synthesis, helical assembly, and circularly polarized luminescence. Macromolecules 2023 , 56 , 1875−1883 ..

Li, S.-Y.; Duan, B.-H.; Liu, N.; Luo, J.; Chen, Z; Wu, Z.-Q. Helical star-shaped bottlebrush polymers: from controlled synthesis to tunable photoluminescence and circularly polarized luminescence. ACS Macro Lett. 2024 , 13 , 1396−1402..

Xu, L.; Gao, B. R.; Xu, X. H.; Zhou, L.; Liu, N; Wu, Z. Q. Controlledsynthesis of cyclic-helical polymers with circularly polarized luminescence. Angew. Chem. Int. Ed. 2022 , 61 , e202204966..

Yang, K.; Ma, S.; Wu, Y.; Zhao, B; Deng, J. Circularly polarized fluorescence energy transfer for constructing multicolor circularly polarized luminescence films with controllable handedness. Chem. Mater. 2023 , 35 , 1273−1282..

Suharman; Nakayama, S.; Kushida, S.; Rani, S.; Yospanya, W.; Pranee, P.; Oda, R.; Yamagishi, H; Yamamoto, Y. Induced blue, green, and red-colour circularly polarized luminescence from single dye-doped homochiral poly(lactic acid) microspheres. J. Mater. Chem. C 2025 , 13 , 13659−13663..

Liu, Y.; Yang, S.; Zhao, B; Deng, J. Nonconventional fluorescence-based circularly po larized luminescent core/shell particles: maleic anhydride copolymer as the core and chiral helical polyacetylene as the shell. ACS Macro Lett. 2023 , 12 , 530−535..

Ji, Y.; Yang, K.; Zhao, B.; Pan, K; Deng, J. Fluorescence-selective absorption and circularly polarized fluorescence energy transfer assist the generation of multicolor circularly polarized luminescence in chiral helical polyacetylene-based janus nanofibers. ACS Macro Lett. 2024 , 13 , 673−680..

Song, L.; Dong, Y.; Zhao, B.; Wu, Y; Deng, J. Reversible photochromism for dynamically tuning full-color circularly polarized luminescence toward multi-level anti-counterfeiting application. Adv. Opt. Mater. 2024 , 12 , 2400215..

Li, S.-Y.; Zong, Y.; Liu, B.-H.; Liu, N; Wu, Z.-Q. Helix-induced full-color circularly polarized luminescence films withmultiple information encryption and multi-stimuli responsiveness. Chem. Sci. 2025 , 16 , 5036−5042..

Wang, Y.; Zhong, H.; Zhao, B; Deng, J. High internal phase emulsion for constructing chiral helical polymer-based circularly polarized luminescent porous materials. ACS Appl. Mater. Interfaces 2024 , 16 , 17918−17926..

Wang, X.; Gao, X.; Zhong, H.; Yang, K.; Zhao, B; Deng, J. Three-level chirality transfer and amplification in liquid crystal supramolecular assembly for achieving full-color and white circularly polarized luminescence. Adv. Mater. 2025 , 37 , 2412805..

Yang, H.; Ma, S.; Zhao, B; Deng, J. Brightening up full-color and white circularly polarized luminescence through chiral induction and circularly polarized light excitation. ACS Appl. Mater. Interfaces 2023 , 15 , 13668−13677..

Yuan, J.; He, X.; Chen, L.; Lu, X; Lu, Q. Dynamic covalent bonds-mediated color-switchable circularly polarized luminescence in helical assemblies of achiral liquid crystal block copolymer films. Angew. Chem. Int. Ed. 2025 , 64 , e202419924..

Wade, J.; Brandt, J. R.; Reger, D.; Zinna, F.; Amsharov, K. Y.; Jux, N.; Andrews, D. L; Fuchter, M. J. 500-fold amplification of small molecule circularly polarised luminescence through circularly polarised FRET. Angew. Chem. Int. Ed. 2021 , 60 , 222−227..

Okuda, S.; Ikai, T.; Okutsu, H.; Ando, M.; Hattori, M.; Ishidate, R; Yas hima, E. Helix-sense-selective memory polymerization of biphenylylacetylenes bearing carboxy and amino groups in water. Angew. Chem. Int. Ed. 2024 , 63 , e202412752..

Kim, M.; Zhang, M.; Zhu, Y.-L.; Yan, Y.; Pu, X.; Choi, W.; Chung, S.; Cho, K.; Kim, J.; Tsukruk, V.; Yang, Z.; Kotov, N. A.; Lu, Z.-Y.; Kim, D. H; Lin, Z. Hierarchical chiral supramolecular assemblies with strong and invertible chiroptical properties. Science 2025 , 389 , eadu0296..

Zhao, B.; Gao, X.; Pan, K; Deng, J. Chiral helical polymer/perovskite hybrid nanofibers with intense circularly polarized luminescence. ACS Nano 2021 , 15 , 7463−7471..

Liu, Y.; Zhong, H.; Zhao, B.; Wu, Y; Deng, J. Hydrogen-bond-directed chirality transfer in helical polyacetylene–perovskite–PDMS elastomeric films for stretching-tunable multicolor circularly polarized luminescence. ACS Appl. Mater. Interfaces 2025 , 17 , 52488−52497..

[Liu, Y.; Yang, K.; Zhao, B.; Wu, Y; Deng, J. “Surface-Filming Assembly” strategy for facilely constructing and adjusting circularly polarized luminescence from perovskite/chiral helical polyacetylene films. Adv. Opt. Mater . 2024, 12 , 2303039..

Lu, D.; Li, M.; Gao, X.; Yu, X.; Wei, L.; Zhu, S; Xu, Y. Cellulose nanocrystal films with NIR-II circularly polarized light for cancer detection applications. ACS Nano 2022 , 17 , 461−471..

Gao, X.; Duan, M.; Zhao, B; Deng, J. Spatial isolation induced solid-state emissive chiral carbon dots for achieving efficient circularly polarized light emission and detection. Adv. Funct. Mater. 2025 , 43 , 2508648..

Gao, X.; Pan, K.; Zhao, B; Deng, J. Generation, inversion, and amplification of intrinsic circularly polarized room temperature phosphorescence in chiral carbon dots. Adv. Funct. Mater. 2025 , 35 , 2413569..

Ma, S.; Ma, H.; Yang, K.; Tan, Z. a.; Zhao, B; Deng, J. Intense circularly polarized fluorescence and room-temperature phosphorescence in carbon dots/chiral helical polymer composite films. ACS Nano 2023 , 17 , 6912−6921..

Yang, K.; Zhang, R.; Liu, Y.; Zhao, B.; Wu, Y; Deng, J. Circularly polarized phosphorescence energy transfer combined with chirality-selective absorption for modulating full- color and white circularly polarized long afterglow. Angew. Chem. Int. Ed. 2024 , 63 , e202409514..

Feng, Z.; Li, J.; Yang, P.; Xu, X.; Wang, D.; Li, J.; Zhang, C.; Li, J.; Zhang, H.; Zou, G.; Chen, X. Dynamic multimodal information encryption combining programmable structural coloration and switchable circularly polarized luminescence. Nat. Commun. 2025 , 16 , 2264..

Zhang, K.; Dan, N.; Zhang, R. Y.; Wei, J.; Tian, R. X.; Zhang, Y.; Fu, H. R.; Qiu, M.; Ma, L. F.; Zang, S. Q. Multi-stimuli-responsive circularly polarized luminescence with handedness inversion and near-infrared phosphorescence in chiral metal-organic framework platform for white light emission and information encryption. Adv. Sci. 2025 , 12 , 2502784..

Li, J.; Liao, K.; Zeng, Q.; Zhang, X.; Zhang, J.; Yuan, F. Harnessing reversible 0D–1D transformation in chiral Mn(II) halides for smart circularly polarized luminescence switching and multi-level encryption. Angew. Chem. Int. Ed. 2026 , 65 , e25831..

Nie, X.; Wang, C.; Lu, X.; Lai, G.; Li, Z.; Peng, D.; Chen, W.; Zhu, D.; Pan, C. Circularly polarized mechanoluminescence for force-insensitive optical information decryption. Adv. Funct. Mater. 2025 , 36 , e26708..

Liu, C.; Liu, L.; Song, Y.; Tian, G.; Cheng, Y. Color-tunable circularly polarized room-temperature phosphorescence by intermolecular phosphorescence resonance energy transfer in a chiral co-assembled liquid crystal polymer network. The J. Phys. Chem. Lett. 2025 , 16 , 9568−9576..

Ji, S.; Zhou, Y.; Xiong, L.; Liu, X.; Zhu, T.; Zhan, X.; Yan, Y.; Yao, J.; Wang, K; Zhao, Y. S. Nonreciprocal circularly polarized lasing from organic achiral microcrystals. J. Am. Chem. Soc. 2025 , 147 , 16674−16680..

Fu, H.-R.; Ren, D.-D.; Zhang, K.; Wang, S.; Yang, X.-J.; Ding, Q.-R; Wu, Y.-P. Hierarchical chiral MOFs with the induced chirality of AIE ligands exhibiting non-reciprocal CPL. Chem. Commun. 2024 , 60 , 6182−6185..

Jia, D.; Pu, X.; Zhu, D; Wang, X. Dynamic assembly endows flexible iridescent cnc-based photonic composite film with emergent nonreciprocal chiroptical capability. Carbohydr. Polym. 2025 , 368 , 124241..

Li, P.; Zhao, B.; Pan, K; Deng, J. Synergism between LDLB and true CD to achiev e angle-dependent chiroptical inversion and switchable polarized luminescence emission in nonreciprocal nanofibrous films. Nanoscale 2023 , 15 , 5345−5359..

Zhang, R.; Song, L.; Yin, W.; Zhao, B; Deng, J. Generation and modulation of nonreciprocal chirality to realize nonreciprocal CPL emission in polyurethane films. Sci. China Chem. 2025 , 68 , 3247−3259..

Zinna, F.; Albano, G.; Taddeucci, A.; Colli, T.; Aronica, L. A.; Pescitelli, G; Di Bari, L. Emergent nonreciprocal circularly polarized emission from an organic thin film. Adv. Mater. 2020 , 32 , 2002575..

Jin, L.; Mo, W.; Wang, Z; Hong, W. Vortex-enabled nonreciprocal circularly polarized luminescence in achiral polymer systems. Adv. Funct. Mater. 2026 , 36 , e21524..

Li, P; Deng, J. Switchable chiroptical flexible films based on chiral helical superstructure: handedness inversion and dissymmetric adjustability by stretching. Adv. Funct. Mater. 2021 , 31 , 2105315..

[Yin, W.; Don g, Y.; Zhang, R.; Zhao, B; Deng, J. anisotropic artifacts coupled with light-scattering generating “non-reciprocal-like” CD/CPL signals in polyurethane films. Macromolecules 2025, 58 , 9660−9671..

Albano, G.; Pescitelli, G; Di Bari, L. Reciprocal and non-reciprocal chiroptical features in thin films of organic dyes. ChemNanoMat 2022 , 8 , e202200219..

Ugras, T. J.; Yao, Y; Robinson, R. D. Can we still measure circular dichroism with circular dichroism spectrometers: the dangers of anisotropic artifacts. Chirality 2023 , 35 , 846−855..

Kitzmann, W. R.; Freudenthal, J.; Reponen, A.-P. M.; VanOrman, Z. A; Feldmann, S. Fundamentals, advances, and artifacts in circularly polarized luminescence (CPL) spectroscopy. Adv. Mater. 2023 , 35 , 2302279..

Kuroda, R.; Harada, T; Shindo, Y. A Solid-state dedicated circular dichroism spectrophotometer: development and application. Rev. Sci. Instrum. 2001 , 72 , 3802−3810..

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