Porous Organic Polymers for Photocatalytic Hydrogen Peroxide Production: Recent Advances and Future Perspectives

Jia-Wei Xie; Bi-En Tan

doi:10.1007/s10118-026-3697-3

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Porous Organic Polymers for Photocatalytic Hydrogen Peroxide Production: Recent Advances and Future Perspectives

REVIEW | Updated：2026-08-05

- Porous Organic Polymers for Photocatalytic Hydrogen Peroxide Production: Recent Advances and Future Perspectives
- Porous Organic Polymers for Photocatalytic Hydrogen Peroxide Production: Recent Advances and Future Perspectives
- Chinese Journal of Polymer Science 2026年44卷页码：1-25
- Affiliations：
  
  a.Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education), Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
  b.Huazhong University of Science and Technology, Wuhan 430074, China
- Author bio：
  
  bien.tan@mail.hust.edu.cn
- Funds：
  
  This work was financially supported by the Program for the National Natural Science Foundation of China (No. 22475076)，the Key Research and Development Program of Wuhan (No. 2025011202030399) and Key Research and Development and Technology Transfer Projects of Inner Mongolia Autonomous Region of China (No. 2025KJHZ0008).;Bi-En Tan is a professor at the School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology (HUST). He received his PhD in 1999 from the College of Materials at South China University of Technology. He then joined Beijing Institute of Aeronautical Materials for postdoctoral research in National Laboratory of Advanced Composites (1999–2001). He worked as a PDRA at the University of Liverpool (2001–2007). He then returned to China and joined HUST in September 2007 as a professor. His main research interests include polymeric materials, microporous materials, hydrogen storage, metal nanoparticles, emulsion-templated materials, and high through-put materials methodology.The authors declare no interest conflict.
- DOI：10.1007/s10118-026-3697-3
  中图分类号：
- 收稿：2026-03-10，
  
  录用：2026-04-03，
  
  网络首发：2026-08-05，
  
  纸质出版：2026-09-05
- Accepted：
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Xie, J. W.; Tan, B. E. Porous organic polymers for photocatalytic hydrogen peroxide production: recent advances and future perspectives. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-026-3697-3

Jia-Wei Xie, Bi-En Tan. Porous Organic Polymers for Photocatalytic Hydrogen Peroxide Production: Recent Advances and Future Perspectives[J/OL]. Chinese Journal of Polymer Science, 2026, 441-25.
Xie, J. W.; Tan, B. E. Porous organic polymers for photocatalytic hydrogen peroxide production: recent advances and future perspectives. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-026-3697-3 DOI：

Jia-Wei Xie, Bi-En Tan. Porous Organic Polymers for Photocatalytic Hydrogen Peroxide Production: Recent Advances and Future Perspectives[J/OL]. Chinese Journal of Polymer Science, 2026, 441-25. DOI： 10.1007/s10118-026-3697-3.

摘要

Abstract

Hydrogen peroxide (H

) is a green chemical with extensive applications in chemical synthesis and environmental remediation. While the industrial anthraquinone process remains the dominant production method

solar-driven photocatalytic H

production has emerged as a promising strategy to complement or optimize current production models

particularly for on-site applications. Among various porous organic polymers (POPs)

covalent organic frameworks (COFs)

and covalent triazine frameworks (CTFs) have attracted significant attention as a premier platform due to their modular construction and precise molecular-level tunability. Here

we systematically summarize recent progress in POPs-based photocatalysts

with a primary focus on the structural and functional modification of COFs and CTFs. We first elucidate the fundamental principles and existing challenges of photocatalytic H

production. Subsequently

the research landscape of various POPs materials in photocatalysis is discussed. Taking COFs and CTFs as representative examples

we then highlight advanced modification strategies

including the design of donor-acceptor (D-A) structures

functional group engineering

and the construction of heterostructures. These strategies effectively facilitate efficient charge separation

extend carrier lifetimes

and improve mass transport

thereby enhancing solar-to-chemical conversion efficiency. Finally

we summarize the current state of the field and offer perspectives on future research directions for POPs-based photocatalytic H

production.

关键词

Keywords

references

Freese, T.; Meijer, J. T.; Feringa, B. L.; Beil, S. B. An organic perspective on photocatalytic production of hydrogen peroxide. Nat. Catal. 2023 , 6 , 553−558..

Zeng, X.; Liu, Y.; Hu, X.; Zhang, X. Photoredox catalysis over semiconductors for light-driven hydrogen peroxide production. Green Chem. 2021 , 23 , 1466−1494..

Guo, Y.; Tong, X.; Yang, N. Photocatalytic and electrocatalytic generation of hydrogen peroxide: principles, catalyst design and performance. Nano-Micro Lett. 2023 , 15 , 77..

Zhao, W.; Yan, P.; Li, B.; Bahri, M.; Liu, L.; Zhou, X.; Clowes, R.; Browning, N. D.; Wu, Y.; Ward, J. W.; Cooper, A. I. Accelerated synthesis and discovery of covalent organic framework photocatalysts for hydrogen peroxide production. J. Am. Chem. Soc. 2022 , 144 , 9902−9909..

Lu, Z.; Chen, G.; Siahrostami, S.; Chen, Z.; Liu, K.; Xie, J.; Liao, L.; Wu, T.; Lin, D.; Liu, Y.; Jaramillo, T. F.; Nørskov, J. K.; Cui, Y. High-efficiency oxygen reduction to hydrogen peroxide catalysed by oxidized carbon materials. Nat. Catal. 2018 , 1 , 156−162..

Yi, K.; Li, C.; Hu, S.; Yuan, X.; Logan, B. E.; Yang, W. High H 2 O 2 production in membrane-free electrolyzer via anodic bubble shielding towards robust rural disinfection. Nat. Commun. 2025 , 16 , 1893..

Mehta, S.; Kaur, S.; Garg, K.; Singh, M.; Nagaiah, T. C. Unveiling an In situ H 2 O 2 production: rechargeable zinc-H 2 O 2 battery powering 26 LEDs. Angew. Chem., Int. Ed. 2025 , 64 , e202505593..

Zou, X.; Shi, Q.; Cheng, M.; Huang, D.; Zhang, G.; Wang, W.; Wang, G.; Liu, H.; Chen, Y.; Chen, A.; Deng, S. Met al–organic framework-based materials for photocatalytic hydrogen peroxide production: insights into mechanism, modification strategies, and environmental applications. Adv. Energy Mater. 2025 , 15 , 2501424..

Xiang, E.; Jiang, Y.; Liu, F.; Li, J.; Li, R. The catalytic mechanism, design strategy, and future challenge for photocatalytic hydrogen peroxide generation with an emphasis on covalent organic frameworks. Renew. Sustain. Energy Rev. 2026 , 226 , 116391..

Gu, X.; Lin, S.; Qi, K.; Yan, Y.; Li, R.; Popkov, V.; Almjasheva, O. Application of tungsten oxide and its composites in photocatalysis. Sep. Purif. Technol. 2024 , 345 , 127299..

Wang, X.; University, F.; Xue, S.; University, F.; Huang, M.; University, F.; Lin, W.; University, F.; Hou, Y.; University, F.; Yu, Z.; University, F.; Anpo, M.; University, F.; Yu, J. C.; Zhang, J.; University, F.; Wang, X.; University, F. Pressure-induced engineering of surface oxygen vacancies on metal oxides for heterogeneous photocatalysis. J. Am. Chem. Soc. 2025 , 147 , 4945−4951..

Jin, Z.; Lu, M.; Jiang, C.; Wu, S.; Tang, L.; Hu, C.; Liu, L.; Fang, L.; Cheng, Z. Mechanocatalytic H 2 O 2 production using ferroelectric KSr 2 Nb 3 Ta 2 O 15 nanorods. Nano Energy 2025 , 138 , 110892..

[Tang, G.; Zhang, J.; Bie, C.; Zheng, X.; Jiang, C.; Yu, J. In situ soft X-ray absorption spectroscopy investigation on charge transfer mechanism in COF/CdS S-scheme photocatalyst. Adv. Mater . 2025 , 37 , e14576..

Hu, J.; Zhu, M.; Ali Ghazi, Z.; Cao, Y. Restoration mechanism of photocatalytic H 2 O 2 /H 2 production stability of ZnO/ZnS S-scheme heterojunction. Chin. J. Catal. 2025 , 71 , 319−329..

Wang, W.; Chen, Z.; Li, C.; Cheng, B.; Yang, K.; Zhang, S.; Luo, G.; Yu, J.; Cao, S. Graphene quantum dot-modified Mn 0.2 Cd 0.8 S for efficient overall photosynthesis of H 2 O 2 . Adv. Funct. Mater. 2025 , 35 , 2422307..

Bhanderi, D.; Lakhani, P.; Modi, C. K. Graphitic carbon nitride (g-C 3 N 4 ) as an emerging photocatalyst for sustainable environmental applications: a comprehensive review. RSC Sustainability 2024 , 2 , 265−287..

Rogolino, A.; Linley, S.; Kwarteng, P. K.; Bonke, S. A.; Pulignani, C.; Reisner, E. Floatable carbon nitride-plastic composite for paired photocatalysis at the liquid-liquid interface. Chem 2025 , 12 , 102827..

Sun, P.; Zhong, K.; Huang, X.; Wu, G.; Miao, Z.; Chen, Z.; Mo, Z.; Yang, J.; Xu, H. Synergistic utilization of photogenerated electrons and holes in carbon nitride nanosheet assembly for enhanced photocatalytic H 2 O 2 production. Appl. Catal., B 2025 , 366 , 124998..

Liang, S.; Wang, C.; Wu, Q.; Wang, R.; Li, Y.; Du, J.; Zhang, X. Aldehyde-modified C 3 N 4 boosts solution plasma catalysis for H 2 O 2 production. Appl. Catal., B 2026 , 385 , 126334..

Wang, S.; Li, X.; Yuan, C.; Sun, Z.; Lu, Y.; Pei, S.; Wu, Y.; Wang, C. C.; Wang, B. Asymmetric electric field-induced modulation on MOFs for boosting heterogeneous photo-fenton process: porous coordination structure and selective oxidation. Appl. Catal., B 2025 , 379 , 125717..

Wu, P.; Du, F.; Xue, Q.; Li, H.; Fu, M. C.; Zhou, X.; Wang, F. Photothermal-catalyzed hydrogen peroxide production enabled by go ld-organic frameworks. Adv. Funct. Mater. 2026 , 36 , 2420941..

Yang, D.-H.; Tao, Y.; Ding, X.; Han, B.-H. Porous organic polymers for electrocatalysis. Chem. Soc. Rev. 2022 , 51 , 761−791..

Liu, X.; Liu, C.-F.; Xu, S.; Cheng, T.; Wang, S.; Lai, W.-Y.; Huang, W. Porous organic polymers for high-performance supercapacitors. Chem. Soc. Rev. 2022 , 51 , 3181−3225..

Zhu, Y.; Xu, P.; Zhang, X.; Wu, D. Emerging porous organic polymers for biomedical applications. Chem. Soc. Rev. 2022 , 51 , 1377−1414..

Wang, Y.; Yang, Y.; Deng, Q.; Chen, W.; Zhang, Y.; Zhou, Y.; Zou, Z. Recent progress of amorphous porous organic polymers as heterogeneous photocatalysts for organic synthesis. Adv. Funct. Mater. 2023 , 33 , 2307179..

Zhang, T.; Gregoriou, V. G.; Gasparini, N.; Chochos, C. L. Porous organic polymers in solar cells. Chem. Soc. Rev. 2022 , 51 , 4465−4483..

Song, W.; Wen, Y.; Cho, Y.; Zhang, X.; Kang, D.; Shin, E.; Yu, D.-G.; Li, G.; Liao, Y.; Kim, I.-D. Advances and prospects in multifunctional composite fibrous materials utilizing porous organic polymers. Adv. Mater. 2025 , 36 , e13138..

[Li, D.; Shi, T.; Ran, S.; Zeng, L.; Xu, C. Rapid sintering of porous organic polymer powders into mechanically strong monoliths for efficient CO 2 capture. Adv. Funct. Mater . 2025 , e14603..

Hou, H.; Zeng, X.; Zhang, X. Production of hydrogen peroxide by photocatalytic processes. Angew. Chem., Int. Ed. 2020 , 59 , 17356−17376..

Low, J.; Yu, J.; Jaroniec, M.; Wageh, S.; Al-Ghamdi, A. A. Heterojunction photocatalysts. Adv. Mater. 2017 , 29 , 1601694..

Chen, L.; Wang, L.; Wan, Y.; Zhang, Y.; Qi, Z.; Wu, X.; Xu, H. Acetylene and diacetylene functionalized covalent triazine frameworks as metal-free photocatalysts for hydrogen peroxide production: a new two-electron water oxidation pathway. Adv. Mater. 2020 , 32 , 1904433..

Tang, X.; Li, F.; Li, F.; Jiang, Y.; Yu, C. Single-atom catalysts for the photocatalytic and electrocatalytic synthesis of hydrogen peroxide. Chin. J. Catal. 2023 , 52 , 79−98..

Luo, H.; Shan, T.; Zhou, J.; Huang, L.; Chen, L.; Sa, R.; Yamauchi, Y.; You, J.; Asakura, Y.; Yuan, Z.; Xiao, H. Controlled synthesis of hollow carbon ring incorporated g-C 3 N 4 tubes for boosting photocatalytic H 2 O 2 production. Appl. Catal., B 2023 , 337 , 122933..

Zhu, Q.; Su, J.; Lin, G.; Li, G.; Zhuo, Z.; Wang, W.; Li, J.; Xu, X. Surface indium vacancies promote photocatalytic H 2 O 2 production over In 2 S 3 . Nat. Commun. 2025 , 16 , 10501..

Zhou, J.; Shan, T.; Zhang, F.; Boury, B.; Huang, L.; Yang, Y.; Liao, G.; Xiao, H.; Chen, L. A novel dual-channel carbon nitride homojunction with nanofibrous carbon for significantly boosting photocatalytic hydrogen peroxide production. Adv. Fiber Mater. 2024 , 6 , 387−400..

Huang, G.-Z.; Xia, Y.-S.; Yang, F.; Long, W.-J.; Liu, J.-J.; Liao, J.-P.; Zhang, M.; Liu, J.; Lan, Y.-Q. On–off switching of a photo catalytic overall reaction through dynamic spin-state transition in a hofmann clathrate system. J. Am. Chem. Soc. 2023 , 145 , 26863−26870..

Kandelhard, F.; Neumann, S.; Lützow, K.; Filiz, V.; Georgopanos, P. Reaction kinetic modeling of the synthesis of polymers of intrinsic microporosity. Adv. Funct. Mater. 2025 , 35 , 2413358..

Willner, B. J.; Aitchison, C. M.; Podjaski, F.; Lu, W.; Tian, J.; Durrant, J. R.; McCulloch, I. Correlation between the molecular properties of semiconducting polymers of intrinsic microporosity and their photocatalytic hydrogen production. J. Am. Chem. Soc. 2024 , 146 , 30813−30823..

Hu, J.; Yang, S.; Wang, X.; Zhang, D.; Tan, B. High pore volume hyper-cross-linked polymers via mixed-solvent knitting: a route to superior hierarchical porosity for methane storage and delivery. Macromolecules 2024 , 57 , 5507−5519..

Tan, L.; Tan, B. Hypercrosslinked porous polymer materials: design, synthesis, and applications. Chem. Soc. Rev. 2017 , 46 , 3322−3356..

Ma, H.; Chen, Y.; Li, X.; Li, B. Advanced applications and challenges of electropolymerized conjugated microporous polymer films. Adv. Funct. Mater. 2021 , 31 , 2101861..

Lee, J. M.; Cooper, A. I. Advances in conjugated microporous polymers. Chem. Rev. 2020 , 120 , 2171−2214..

Zhang, W.; Zuo, H.; Cheng, Z.; Shi, Y.; Guo, Z.; Meng, N.; Thomas, A.; Liao, Y. Macroscale conjugated microporous polymers: controlling versatile functionalities over several dimensions. Adv. Mater. 2022 , 34 , 2104952..

Zheng, Y.; You, S.; Li, S.; Ding, Z.; Yuan, R.; Long, J.; Xu, C. All-conjugated microporous polymer heterojunction with hierarchical hollow sphere architecture for photocatalytic H 2 O 2 production. Adv. Funct. Mater. 2025 , 36 , e08538..

[Mei, J.-H.; Zeng, Y.-R.; Gong, Y.-N.; Shi, W.-J.; Zhong, D.-C.; Lu, T.-B. π–π stacking as electron-transfer channels in hydrogen-bonded organic frameworks for boosting photocatalysis. Angew. Chem., Int. Ed . 2025 , 64 , e202507332..

Wang, W.; Song, J.; Ren, W.; Wu, J.; Chang, Q.; Li, N.; Yang, J.; Hu, S. Photocatalytic synthesis of high-concentration hydrogen peroxide by efficient photothermal synergy. Chem. Eng. J. 2024 , 490 , 151796..

Zhao, H.; Zhou, Z.; Feng, X.; Liu, C.; Wu, H.; Zhou, W.; Wang, H. Hydrogen-bonded organic framework for red light-mediated photocatalysis. Nano Res. 2023 , 16 , 8809−8816..

Ma, C.; Qin, L.; Zhou, T.; Zhang, J. Customized structures of hydrogen-bonded organic frameworks towards photocatalysis. Energy Environ. Sci. 2024 , 17 , 8992−9026..

Talebian-Kiakalaieh, A.; Liang, T.; Guo, M.; She, P.; Ran, J. Recent achievement of hydrogen-bonded organic framework-based single-atom catalysts and covalent organic framework-based dual-atom catalysts in photocatalytic applications. Mater. Mater. Sci. Eng., R 2025 , 165 , 100993..

Hu, X.; Tan, B. Covalent organic frameworks as photocatalysts for sustainable solar-to-hydrogen peroxide conversion. Chem. Mater. 2025 , 31 , 9614−9632..

Shu, C.; Yang, X.; Liu, L.; Hu, X.; Sun, R.; Yang, X.; Cooper, A. I.; Tan, B.; Wang, X. Mixed-linker strategy for the construction of sulfone-containing D–a–a covalent organic frameworks for efficient photocatalytic hydrogen peroxide production. Angew. Chem., Int. Ed. 2024 , 63 , e202403926..

Guo, Y.; Yang, X.; Sun, R.; Hu, X.; Shu, C.; Yang, X.; Gao, H.; Wang, X.; Tan, B. A dual-active covalent triazine framework film for efficient visible-light-driven hydrogen peroxide production. Small 2024 , 20 , 2403743..

Sun, R.; Tan, B. Covalent triazine frameworks (CTFs): synthesis, crystallization, and photocatalytic water splitting. Chem. - Eur. J. 2023 , 29 , e202203077..

Tian, Y.; Zhu, G. Porous aromatic frameworks (PAFs). Chem. Rev. 2020 , 120 , 8934−8986..

Zou, J.; Trewin, A.; Ben, T.; Qiu, S. High uptake and fast transportation of LiPF 6 in a porous aromatic framework for solid-state Li-ion batteries. Angew. Chem., Int. Ed. 2020 , 59 , 769−774..

Hu, J.; Zhang, Z.; Deng, T.; Cui, F.-C.; Shi, X.; Tian, Y.; Zhu, G. Porous aromatic frameworks enabling polyiodide confinement toward high capacity and long lifespan zinc–iodine batteries. Adv. Mater. 2024 , 36 , 2401091..

Côté, A. P.; Benin, A. I.; Ockwig, N. W.; O’Keeffe, M.; Matzger, A. J.; Yaghi, O. M. Porous, crystalline, covalent organic frameworks. Science 2005 , 310 , 1166−1170..

Wang, K.; Yang, L.-M.; Wang, X.; Guo, L.; Cheng, G.; Zhang, C.; Jin, S.; Tan, B.; Cooper, A. Covalent triazine frameworks via a low-temperature polycondensation approach. Angew. Chem., Int. Ed. 2017 , 56 , 14149−14153..

Zhi, Q.; Liu, W.; Jiang, R.; Zhan, X.; Jin, Y.; Chen, X.; Yang, X.; Wang, K.; Cao, W.; Qi, D.; Jiang, J. Piperazine-linked metalphthalocyanine frameworks for highly efficient visible-light-driven H 2 O 2 photosynthesis. J. Am. Chem. Soc. 2022 , 144 , 21328−21336..

Chen, B.; Pan, Y.; Deng, Y.; Hou, Y.; Liang, H.; Wang, N.; Luo, J.; Chen, K.; Wang, X. Pyridine heterocycle driven microenvironment regulation of β-ketoenamine COFs for enhanced photocatalytic H 2 O 2 production. Adv. Funct. Mater. 2026 , 36 , e23735..

Wu, W.; Li, Z.; Liu, S.; Zhang, D.; Cai, B.; Liang, Y.; Wu, M.; Liao, Y.; Zhao, X. Pyridine-based covalent organic frameworks with pyridyl-imine structures for boosting photocatalytic H 2 O 2 production via one-step 2e − oxygen reduction. Angew. Chem., Int. Ed. 2024 , 63 , e202404563..

Sun, R.; Hu, X.; Yang, X.; Guo, Y.; Shu, C.; Yang, X.; Gao, H.; Wang, X.; Tan, B. Carbazole-containing covalent triazine frameworks for efficient hydrogen peroxide photosynthesis from natural sunlight. Chem. Eng. J. 2024 , 490 , 151332..

Li, Y.; Zhou, H.; Yang, Q.; Li, B.; Lu, Y.; Xu, A.; Su, Q.; Wu, Q.; Su, Z. Engineering β-ketoenamine-based covalent organic frameworks with tetrazine units for efficient photocatalytic hydrogen peroxide production. Chem. Eng. J. 2025 , 525 , 170189..

Wang, C.; Qiu, T. Y.; Zhao, Y. N.; Lang, Z. L.; Li, Y. G.; Su, Z. M.; Tan, H. Q. Phosphorus-alkynyl functionalized covalent triazine/heptazine-based frameworks for high-performance photocatalytic hydrogen peroxide production. Adv. Energy Mater. 2023 , 13 , 2301634..

Luo, Y.; Zhang, B.; Liu, C.; Xia, D.; Ou, X.; Cai, Y.; Zhou, Y.; Jiang, J.; Han, B. Sulfone-modified covalent organic frameworks enabling efficient photocatalytic hydrogen peroxide generation via one-step two-electron O 2 reduction. Angew. Chem., Int. Ed. 2023 , 62 , e202305355..

Liu, Y.; Li, L.; Sang, Z.; Tan, H.; Ye, N.; Sun, C.; Sun, Z.; Luo, M.; Guo, S. Enhanced hydrogen peroxide photosynthesis in covalent organic frameworks through induced asymmetric electron distribution. Nat. Synth. 2024 , 4 , 134−141..

Chang, J. N.; Li, Q.; Shi, J. W.; Zhang, M.; Zhang, L.; Li, S.; Chen, Y.; Li, S. L.; Lan, Y. Q. Oxidation-reduction molecular junction covalent organic frameworks for full reaction photosynthesis of H 2 O 2 . Angew. Chem., Int. Ed. 2023 , 62 , e202218868..

Wang, H.; Yang, C.; Chen, F.; Zheng, G.; Han, Q. A crystalline partially fluorinated triazine covalent organic framework for efficient photosynthesis of hydrogen peroxide. Angew. Chem., Int. Ed. 2022 , 61 , e202202328..

Liu, Y.; Guo, Y.; Sathishkumar, N.; Liu, M.; Li, L.; Sang , Z.; Feng, R.; Sun, Z.; Sun, C.; Luo, M.; Deng, X.; Lu, G.; Guo, S. Halogen atom-induced local asymmetric electron in covalent organic frameworks boosts photosynthesis of hydrogen peroxide from water and air. Matter 2025 , 8 , 102076..

Cao, D.;, Du, J.;, Li, J.;, Sun, Q.;, Guan, J.;, Liu, J. Hydroxyl-functionalized donor–acceptor covalent organic frameworks for efficient photocatalytic hydrogen peroxide production under visible light. ACS Catal. 2025 , 15 , 3584−3594..

Xu, H.; Wang, Y.; Xu, Y.; Wang, Q.; Zhuang, M.; Liao, Q.; Xi, K. Integrating multipolar structures and carboxyl groups in sp 2 -carbon conjugated covalent organic frameworks for overall photocatalytic hydrogen peroxide production. Angew. Chem., Int. Ed. 2024 , 63 , e202408802..

Shi, B.; Pang, X.; Li, S.; Wu, H.; Shen, J.; Wang, X.; Fan, C.; Cao, L.; Zhu, T.; Qiu, M.; Yin, Z.; Kong, Y.; Liu, Y.; Zhang, M.; Liu, Y.; Pan, F.; Jiang, Z. Short hydrogen-bond network confined on COF surfaces enables ultrahigh proton conductivity. Nat. Commun. 2022 , 13 , 6666..

Li, Z.; Cai, B.; Zou, Y.; Zhang, D.; Liang, Y.; Zhou, Y.; Ma, Y.; Wang, X.; Shi, B.; Chen, W.-K.; Liu, Y.; Zhao, X. Pyridyl-imine-functionalized donor–acceptor covalent organic frameworks for optimal photosynthesis of hydrogen peroxide. Adv. Energy Mater. 2025 , 15 , 2500341..

Li, G.; Zhang, M.; Chen, Y.; Cai, S.; Chen, Y.; Hu, X.; Long, B.; Deng, G.-J.; Song, T. Engineering covalent organic frameworks with acceptor modulation and spatially segregated redox center for high-efficiency H 2 O 2 photosynthesis in seawater. Appl. Catal., B 2026 , 387 , 126481..

Yang, J.; Zhao, Z.; Liu, X.; Yang, H.; Yang, J.; Zhou, M.; Li, S.; Liu, X.; Xu, X.; Cheng, C. Homologous heteropolyaromatic covalent organic frameworks for enhancing photocatalytic hydrogen peroxide production and aerobic oxidation. Nat. Commun. 2025 , 16 , 7654..

Guo, H.; Wang, S.; Chen, X.; Kou, J.; He, G.; Dong, Z.; Yan, Y. Engineering a covalent organic framework-based type-II heterojunction for enhanced photocatalytic H 2 O 2 synthesis. Nat. Synth. 2025 , 4 , 1610−1620..

Wu, X.; Sayed, M.; Wang, G.; Yu, W.; Zhu, B. COF-based S-scheme heterojunction photocatalyst. Adv. Mater. 2026 , 38 , e11322..

Li, L.; Xu, L.; Hu, Z.; Yu, J. C. Enhanced mass transfer of oxygen through a gas–liquid–solid interface for photocatalytic hydrogen peroxide production. Adv. Funct. Mater. 2021 , 31 , 2106120..

Qiao, C.; Xian, W.; Lai, Z.; Huang, Z.; Guo, Q.; Wang, S.; Dai, Z.; Xiong, Y.; Meng, X.; Ma, S.; Sun, Q. Covalent organic framework membranes with asymmetric wettability for efficient photocatalytic H 2 O 2 synthesis. Angew. Chem., Int. Ed. 2025 , 64 , e202519513..

[Yu, Z.; Yu, F.; Xu, M.; Feng, S.; Qiu, J.; Hua, J Amidoxime-functionalized sp 2 -carbon-conjugated covalent organic frameworks for overall photocatalytic hydrogen peroxide production. Adv. Sci . 2025 , 12 , 2415194..

Cheng, J.; Wu, Y.; Zhang, W.; Wang, L.; Wu, X.; Xu, H. Unlocking topological effects in covalent organic frameworks for high-performance photosynthesis of hydrogen peroxide. Adv. Mater. 2025 , 37 , 2410247..

[Li, Z.; Zhang, Y.; Jin, Y.; Tian, Z.; Huang, Y.; Wang, X.; Zhi, Y.; Zhang, Q. Synergistic optimization of optical abso rption and charge separation via linker engineering in covalent organic frameworks. Adv. Funct. Mater . 2026 , e30314..

Luan, T.-X.; Wei, Q.; Xin, C.; Wong, S. Y.; Li, Y.; Zheng, Y.; Li, Y.; Liu, G.; Yu, W. W.; Loh, X. J.; Li, X.; Li, P.-Z. Remarkably enhancing H 2 O 2 photogeneration by modulating pore-microenvironment of a photoactive covalent organic framework. Adv. Mater. 2026 , 38 , e15517..

Krishnaraj, C.; Jena, H. S.; Bourda, L.; Laemont, A.; Pachfule, P.; Roeser, J.; Chandran, C. V.; Borgmans, S.; Rogge, S. M. J.; Leus, K.; Stevens, C. V.; Martens, J. A.; Van Speybroeck, V.; Breynaert, E.; Thomas, A.; Van Der Voort, P. Strongly reducing (diarylamino)benzene-based covalent organic framework for metal-free visible light photocatalytic H 2 O 2 generation. J. Am. Chem. Soc. 2020 , 142 , 20107−20116..

Shiraishi, Y.; Kanazawa, S.; Sugano, Y.; Tsukamoto, D.; Sakamoto, H.; Ichikawa, S.; Hirai, T. Highly selective production of hydrogen peroxide on graphitic carbon nitride (g-C 3 N 4 ) photocatalyst activated by visible light. ACS Catal. 2014 , 4 , 774−780..

Yang, Y.; Zhang, C.; Huang, D.; Zeng, G.; Huang, J.; Lai, C.; Zhou, C.; Wang, W.; Guo, H.; Xue, W.; Deng, R.; Cheng, M.; Xiong, W. Boron nitride quantum dots decorated ultrathin porous g-C 3 N 4 : intensified exciton dissociation and charge transfer for promoting visible-light-driven molecular oxygen activation. Appl. Catal., B 2019 , 245 , 87−99..

Zhou, L.; Feng, J.; Qiu, B.; Zhou, Y.; Lei, J.; Xing, M.; Wang, L.; Zhou, Y.; Liu, Y.; Zhang, J. Ultrathin g-C 3 N 4 nanosheet with hierarchical pores and desirable energy band for highly efficient H 2 O 2 production. Appl. Catal., B 2020 , 267 , 118396..

Das, P.; Chakraborty, G.; Roeser, J.; Vogl, S.; Rabeah, J.; Thomas, A. Integrating bifunctionality and chemical stability in covalent organic frameworks via one-pot multicomponent reactions for solar-driven H 2 O 2 production. J. Am. Chem. Soc. 2023 , 145 , 2975−2984..

Feng, S.; Cheng, H.; Chen, F.; Liu, X.; Wang, Z.; Xu, H.; Hua, J. Rational design of covalent organic frameworks with redox-active catechol moieties for high-performance overall photosynthesis of hydrogen peroxide. ACS Catal. 2024 , 14 , 7736−7745..

Chen, Y.; Liu, R.; Guo, Y.; Wu, G.; Sum, T. C.; Yang, S.-W.; Jiang, D. Hierarchical assembly of donor–acceptor covalent organic frameworks for photosynthesis of hydrogen peroxide from water and air. Nat. Synth. 2024 , 3 , 998−1010..

Wang, H.; Almatrafi, E.; Wang, Z.; Yang, Y.; Xiong, T.; Yu, H.; Qin, H.; Yang, H.; He, Y.; Zhou, C.; Zeng, G.; Xu, P. Self-assembly hybridization of COFs and g-C 3 N 4 : decipher the charge transfer channel for enhanced photocatalytic activity. J. Colloid Interface Sci. 2022 , 608 , 1051−1063..

[Cheng, H.; Lv, H.; Cheng, J.; Wang, L.; Wu, X.; Xu, H Rational design of covalent heptazine frameworks with spatially separated redox centers for high-efficiency photocatalytic hydrogen peroxide production. Adv. Mater . 2022 , 34 , 2107480..

Liu, R.; Tan, K.-T.; Gong, Y.; Chen, Y.; Li, Z.; Xie, S.; He, T.; Lu, Z.; Yang, H.; Jiang, D. Covalent organic frameworks: an ideal platform for designing ordered materials and advanced applications. Chem. Soc. Rev. 2021 , 50 , 120−242..

Mou, Y.; Wu, X.; Qin, C.; Chen, J.; Zhao, Y.; Jiang, L.; Zhang, C.; Yuan, X.; Huixiang Ang, E.; Wang, H. Linkage microenvironment of azoles-related covalent organic frameworks precisely regulates ph otocatalytic generation of hydrogen peroxide. Angew. Chem., Int. Ed. 2023 , 62 , e202309480..

Sun, C.; Han, Y.; Guo, H.; Zhao, R.; Liu, Y.; Lin, Z.; Xiao, Z.; Sun, Z.; Luo, M.; Guo, S. Proton reservoir in covalent organic framework compensating oxygen reduction reaction enhances hydrogen peroxide photosynthesis. Adv. Mater. 2025 , 37 , 2502990..

Zadehnazari, A.; Auras, F.; Abbaspourrad, A. Ultrafast charge dynamics in nitrogen-rich covalent organic frameworks for hydrogen peroxide photosynthesis. Adv. Funct. Mater. 2025 , 35 , 2503961..

Meng, J.; Huang, Y.; Liao, Y.; Zhou, Q.; Wei, Y.; Wang, X.; Gao, L.; Dai, W. L. Ag-doping modulates the built-in electric field in S-scheme heterojunction of ZnIn 2 S 4 /covalent organic framework for efficient photocatalytic hydrogen peroxide production from pure water. J. Colloid Interface Sci. 2025 , 700 , 138603..

Qiu, J.; Meng, K.; Zhang, Y.; Cheng, B.; Zhang, J.; Wang, L.; Yu, J. COF/In 2 S 3 S-scheme photocatalyst with enhanced light absorption and H 2 O 2 -production activity and fs-TA investigation. Adv. Mater. 2024 , 36 , 2400288..

Li, L.; Lv, X.; Xue, Y.; Shao, H.; Zheng, G.; Han, Q. Custom-design of strong electron/proton extractor on COFs for efficient photocatalytic H 2 O 2 production. Angew. Chem., Int. Ed. 2024 , 63 , e202320218..

Sun, J.; Sekhar Jena, H.; Krishnaraj, C.; Singh Rawat, K.; Abednatanzi, S.; Chakraborty, J.; Laemont, A.; Liu, W.; Chen, H.; Liu, Y. Y.; Leus, K.; Vrielinck, H.; Van Speybroeck, V.; Van Der Voort, P. Pyrene-based covalent organic frameworks for photocatalytic hydrogen peroxide production. Angew. Chem., Int. Ed. 2023 , 62 , e202216719..

Yang, Y.; Kang, J.; Li, Y.; Liang, J.; Liang, J.; Jiang, L.; Chen, D.; He, J.; Chen, Y.; Wang, J. Enhanced photocatalytic hydrogen peroxide production activity of imine-linked covalent organic frameworks via modification with functional groups. New J. Chem. 2022 , 46 , 21605−21614..

Wu, S.; Chen, L.; He, H.; Pang, Y.; Zhang, Y.; Liu, J.; Gou, Y.; Wang, R.; Jin, C.; Wang, B. Boosted hydrogen peroxide production photocatalyzed by thiophene-based D-a covalent triazine frameworks via modulating two-electron oxygen reduction pathway. J. Catal. 2024 , 438 , 115713..

Gao, P.; Wu, C.; Wang, S.; Zheng, G.; Han, Q. Efficient photosynthesis of hydrogen peroxide by triazole-modified covalent triazine framework nanosheets. J. Colloid Interface Sci. 2023 , 650 , 40−46..

Wu, C.; Teng, Z.; Yang, C.; Chen, F.; Yang, H.-B.; Wang, L.; Xu, H.; Liu, B.; Zheng, G.; Han, Q. Polarization engineering of covalent triazine frameworks for highly efficient photosynthesis of hydrogen peroxide from molecular oxygen and water. Adv. Mater. 2022 , 34 , 2110266..

Chen, C.; Liu, X.; Jiang, J.; Tang, L.; Sun, F.; Liu, X. Hydroxy functional groups modulate S-scheme MIL-125-NH 2 @COF heterojunctions for regulated photocatalytic production of hydrogen peroxide. J. Mater. Chem. A 2026 , 14 , 2369−2378..

Zhang, J.; Yuan, C.; Zhang, Y.; Sun, C.; Yu, J.; Zhang, L. Harnessing S-scheme BiOCl/COF heterojunctions for sustainable and efficient photocatalytic hydrogen peroxide synthesis under visible light. J. Colloid Interface Sci. 2025 , 692 , 137544..

Liu, Y.; Li, L.; Tan, H.; Ye, N.; Gu, Y.; Zhao, S.; Zhang, S.; Luo, M.; Guo, S. Fluorination of covalent organic framework reinforcing the confinement of pd nanoclusters enhances hydrogen peroxide photosynthesis. J. Am. Chem. Soc. 2023 , 145 , 19877−19884..

Yang, K.; Chen, L.; Xiong, K.; Yang, J.; Adeli, M.; Li, S.; Wang, M.; Cheng, C.; Zhao, C. Bisite sulfonate-functionalized covalent organic frameworks with efficient and dynamic proton transportation for accelerating H 2 O 2 photosynthesis. Adv. Funct. Mater. 2026 , 36 , e20900..

Zuo, Q.; Chu, B.; Ye, X.; Li, F.; Li, L.; Xu, Q.; University, K. Enzyme-click postsynthetic modification of covalent organic frameworks for photocatalytic H 2 O 2 production. J. Am. Chem. Soc. 2025 , 147 , 34681−34689..

Wang, K.; Ahn, D. D.; Rampal, N.; Thomassian, J.; Sabeva, N. S.; Kannan, O.; Borgs, C.; Chayes, J. T.; Yaghi, O. M. Synthesis of highly crystalline covalent organic frameworks using large language models. J. Am. Chem. Soc. 2026 , 148 , 10094−10104..

Shu, C.; Wang, L.; Yang, X.; Xie, W.; Xie, P.; Wang, X.; Yang, X.; Rao, J.; Wang, K.; Chen, L.; Tan, B.; Wang, X. Synthesis of covalent organic frameworks for photocatalytic hydrogen peroxide production guided by large language models. Nat. Commun. 2026 , 17 , 3046..

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