Surface Functionalization Modification of Metal Organic Frameworks with Polymer <italic style="font-style: italic">via</italic> Metal-free Atom Transfer Radical Polymerization for Oil-water Separation

Hong-Ye Li; Zi-An Wang; Li-Ping Wang; Guang Li

doi:10.1007/s10118-026-3667-9

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Surface Functionalization Modification of Metal Organic Frameworks with Polymer via Metal-free Atom Transfer Radical Polymerization for Oil-water Separation

RESEARCH ARTICLE | Updated：2026-07-27

- Surface Functionalization Modification of Metal Organic Frameworks with Polymer via Metal-free Atom Transfer Radical Polymerization for Oil-water Separation
- Surface Functionalization Modification of Metal Organic Frameworks with Polymer via Metal-free Atom Transfer Radical Polymerization for Oil-water Separation
- Chinese Journal of Polymer Science 2026年44卷第8期页码：2797-2808
- Affiliations：
  
  School of Materials Science and Engineering, Liaocheng University, Liaocheng 252059, China
- Author bio：
  
  wangliping5@163.com (L.P.W.)
  lglzsd@126.com (G.L.)
- Funds：
  
  This work was financially supported by the Natural Science Foundation of Shandong Province (No. ZR2022ME139), the Research Foundation of Liaocheng University (No. 318012012) and the Key Research and Development Program of Shandong Province—Project for Enhancing the Innovation Capacity of Teschnology-based Small and Medium-sized Enterprises (No. 2024TSGC0957).;The authors declare no interest conflict.Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-026-3667-9.The data that support the findings of this study are available from the corresponding author upon reasonable request.
- DOI：10.1007/s10118-026-3667-9
  中图分类号：
- 收稿：2026-04-22，
  
  录用：2026-05-16，
  
  网络首发：2026-07-09，
  
  纸质出版：2026-08-15
- Accepted：
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Li, H. Y.; Wang, Z. A.; Wang, L. P.; Li, G. Surface functionalization modification of metal organic frameworks with polymer via metal-free atom transfer radical polymerization for oil-water separation. Chinese J. Polym. Sci. 2026, 44, 2797–2808

Hong-Ye Li, Zi-An Wang, Li-Ping Wang, et al. Surface Functionalization Modification of Metal Organic Frameworks with Polymer via Metal-free Atom Transfer Radical Polymerization for Oil-water Separation[J]. Chinese Journal of Polymer Science, 2026, 44(8): 2797-2808. DOI: 10.1007/s10118-026-3667-9.
Li, H. Y.; Wang, Z. A.; Wang, L. P.; Li, G. Surface functionalization modification of metal organic frameworks with polymer via metal-free atom transfer radical polymerization for oil-water separation. Chinese J. Polym. Sci. 2026, 44, 2797–2808 DOI： 10.1007/s10118-026-3667-9.

Hong-Ye Li, Zi-An Wang, Li-Ping Wang, et al. Surface Functionalization Modification of Metal Organic Frameworks with Polymer via Metal-free Atom Transfer Radical Polymerization for Oil-water Separation[J]. Chinese Journal of Polymer Science, 2026, 44(8): 2797-2808. DOI: 10.1007/s10118-026-3667-9. DOI：

摘要

PMMA were grafted from the surface of ZIF-8-Br using SI-metal-free ATRP. Compared to ZIF-8-NH

ZIF-8-

-PMMA exhibits improved water stability and hydrophobicity. The fabric modified with ZIF-8-

-PMMA exhibits superhydrophobicity

and the oil-water separation efficiency reaches 96%.

Abstract

We present a method for modifying metal organic frameworks (MOFs) surface functionalization using metal-free atom transfer radical polymerization (ATRP). Amino-functionalized zeolitic imidazolate frameworks-8 (ZIF-8-NH

) was synthesized at room temperature

and ZIF-8-Br was obtained by the reaction of the amino group in ZIF-8-NH

with the acyl bromide group in 2-bromoisobutyl bromide (BIBB)

thereby introducing secondary bromine groups onto the surface of ZIF-8-NH

. Then

ZIF-8-

-poly(methyl methacrylate) (ZIF-8-

-PMMA) hybrid materials were synthesized using ZIF-8-Br as an initiator

via

surface-initiated metal-free atom transfer radical polymerization (metal-free ATRP). The structural and morphological evolutions were monitored using Fourier transform infrared spectroscopy (FTIR)

X-ray photoelectron spectroscopy (XPS)

X-ray powder diffraction (XRD) and scanning electron microscopy (SEM) measurements. Thermogravimetry (TG) analysis verified that ZIF-8-

PMMA had excellent thermal stability

and the water stability test demonstrated that after grafting PMMA from the ZIF-8-NH

surface

the hydrophobicity and water stability were improved significantly. The BET results proved that ZIF-8-

PMMA had a high specific surface area of 835.24 m

/g. By immobilizing ZIF-8-

-PMMA hybrid material on fabrics

the modified fabrics exhibit excellent superhydrophobicity

with the water contact angle as high as 159.2

. Attributed to the synergistic effect of the micro- and nano-graded porous structure and low-surface-energy PMMA coatings

ZIF-8-

-PMMA hybrid material modified fabrics achieves highly efficient oil-water separation

with excellent adsorption effects on both light and heavy oils. Among them

the heavy oil can pass through the modified fabric within seconds with an oil-water separation efficiency of 96%. This method will further expand the scope of application of metal-free ATRP technology and MOFs materials.

关键词

Keywords

references

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Surface Functionalization Modification of Metal Organic Frameworks with Polymer via Metal-free Atom Transfer Radical Polymerization for Oil-water Separation

DOI：10.1007/s10118-026-3667-9

摘要

Abstract

关键词

Keywords

references