Hetero-structured Poly(vinylidene fluoride)/CsCuCl<sub>3</sub> Nanofiber Composite Film <italic style="font-style: italic">via</italic> Coaxial Electrospinning for Human-Machine Interaction

Yi-Kai Zhao; Yi Zou; Jie-Chun Zhou; Jin-Rong Huang; Jian-Wen Chen; Jin-Rui Huang; Yu-Tian Zhu

doi:10.1007/s10118-026-3587-8

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Hetero-structured Poly(vinylidene fluoride)/CsCuCl₃ Nanofiber Composite Film via Coaxial Electrospinning for Human-Machine Interaction

RESEARCH ARTICLE | Updated：2026-04-16

- Hetero-structured Poly(vinylidene fluoride)/CsCuCl₃ Nanofiber Composite Film via Coaxial Electrospinning for Human-Machine Interaction
- Hetero-structured Poly(vinylidene fluoride)/CsCuCl₃ Nanofiber Composite Film via Coaxial Electrospinning for Human-Machine Interaction
- Chinese Journal of Polymer Science 2026年44卷页码：1-12
- Affiliations：
  
  a.Key Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, Zhejiang Key Laboratory of Organosilicon Material Technology, College of Material Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121, China
  b.Key Laboratory of Biomass Energy and Material, Jiangsu Province, Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Nanjing 210042, China
- Author bio：
  
  jinronghuang@hznu.edu.cn (J.R.H.)
  jwchen@hznu.edu.cn (J.W.C.)
  ytzhu@hznu.edu.cn (Y.T.Z.)
- Funds：
  
  This work was financially supported by the Key Project of Jiangsu Provincial Key Laboratory of Biomass Energy and Materials (No. JSBEM-S-202303), the National Natural Science Foundation of China (No. 52273070), and the Natural Science Fund of Zhejiang Province (No. LRG25E030003).;The authors declare no interest conflict.Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-026-3587-8.Data supporting the findings of this study are available from the corresponding author upon reasonable request.
- DOI：10.1007/s10118-026-3587-8
  中图分类号：
- 收稿：2025-12-29，
  
  录用：2026-01-23，
  
  网络首发：2026-04-16，
  
  纸质出版：2026-05-05
- Accepted：
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Zhao, Y. K.; Zou, Y.; Zhou, J. C.; Huang, J. R.; Chen, J. W.; Huang, J. R.; Zhu, Y. T. Hetero-structured poly(vinylidene fluoride)/CsCuCl₃ nanofiber composite film via coaxial electrospinning for human-machine interaction. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-026-3587-8

Yi-Kai Zhao, Yi Zou, Jie-Chun Zhou, et al. Hetero-structured Poly(vinylidene fluoride)/CsCuCl₃ Nanofiber Composite Film via Coaxial Electrospinning for Human-Machine Interaction[J/OL]. Chinese Journal of Polymer Science, 2026, 441-12.
Zhao, Y. K.; Zou, Y.; Zhou, J. C.; Huang, J. R.; Chen, J. W.; Huang, J. R.; Zhu, Y. T. Hetero-structured poly(vinylidene fluoride)/CsCuCl₃ nanofiber composite film via coaxial electrospinning for human-machine interaction. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-026-3587-8 DOI：

Yi-Kai Zhao, Yi Zou, Jie-Chun Zhou, et al. Hetero-structured Poly(vinylidene fluoride)/CsCuCl₃ Nanofiber Composite Film via Coaxial Electrospinning for Human-Machine Interaction[J/OL]. Chinese Journal of Polymer Science, 2026, 441-12. DOI： 10.1007/s10118-026-3587-8.

摘要

Abstract

Polymer-based piezoelectric films can be assembled into piezoelectric nanogenerators (PENGs)

which can simultaneously serve as flexible pressure sensors and energy harvesting devices. However

the low piezoelectric output of PENGs is a major limitation for their practical applications. Herein

we propose a coaxial electrospinning strategy to generate a core-shell structured nanofiber film

which could significantly enhance the piezoelectric output compared to the traditional nanofiber film

via

conventional single-axial electrospinning. Notably

the as-prepared PENGs based on the core-shell structured CsCuCl

/poly(vinylidene fluoride) (PVDF) nanofiber composite film (2 wt%) produced

via

coaxial spinneret exhibit a 60% increase in output voltage (increase from 48 V to 75 V) and a 50% increase in short-circuit current (increase from 0.2 μA to 0.3 μA) compared to those prepared using a single-needle spinneret. More interestingly

this enhancement in piezoelectric performance is a universal phenomenon because the coaxial electrospinning process can induce greater polymer chain alignment in the shell layer and lead to increased crystallinity and a higher proportion of the piezoelectric-active

-phase. Owing to their enhanced piezoelectric output and high sensitivity to subtle pressure variations

the resulting PENGs demonstrate promising potential for human-machine interaction applications. This study offers a novel and broadly applicable approach to boost the piezoelectric performance of polymer-based PENGs.

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Keywords

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Hetero-structured Poly(vinylidene fluoride)/CsCuCl3 Nanofiber Composite Film via Coaxial Electrospinning for Human-Machine Interaction

DOI：10.1007/s10118-026-3587-8

摘要

Abstract

关键词

Keywords

references

Hetero-structured Poly(vinylidene fluoride)/CsCuCl₃ Nanofiber Composite Film via Coaxial Electrospinning for Human-Machine Interaction

Hetero-structured Poly(vinylidene fluoride)/CsCuCl₃ Nanofiber Composite Film via Coaxial Electrospinning for Human-Machine Interaction