

FOLLOWUS
a.School of Chemical Engineering, Changchun University of Technology, Changchun 130012, China
b.Changchun Sahala Biochemical Technology Company, Changchun 130012, China
lvxueccut@126.com
Received:01 April 2026,
Accepted:21 May 2026,
Online First:28 August 2026,
Published:2026-07
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Jia, H. W.; Lv, X.; Ma, Y. M.; Xu, W.; Yang, X. N. Multifunctional property enhancement of 2-acrylamido-2-methyl-1-propanesulfonic acid/acrylic acid hydrogels with dual-ionic liquid functionalized carbon nanotubes. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-026-3754-y
Hui-Wen Jia, Xue Lv, Yan-Ming Ma, et al. Multifunctional Property Enhancement of 2-Acrylamido-2-methyl-1-propanesulfonic Acid/Acrylic Acid Hydrogels with Dual-ionic Liquid Functionalized Carbon Nanotubes[J/OL]. Chinese Journal of Polymer Science, 2026, 441-11.
Jia, H. W.; Lv, X.; Ma, Y. M.; Xu, W.; Yang, X. N. Multifunctional property enhancement of 2-acrylamido-2-methyl-1-propanesulfonic acid/acrylic acid hydrogels with dual-ionic liquid functionalized carbon nanotubes. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-026-3754-y DOI:
Hui-Wen Jia, Xue Lv, Yan-Ming Ma, et al. Multifunctional Property Enhancement of 2-Acrylamido-2-methyl-1-propanesulfonic Acid/Acrylic Acid Hydrogels with Dual-ionic Liquid Functionalized Carbon Nanotubes[J/OL]. Chinese Journal of Polymer Science, 2026, 441-11. DOI: 10.1007/s10118-026-3754-y.
Conductive hydrogels with high mechanical strength
good adhesion
and high sensitivity are highly demanded for wearable electronics. A multifunctional hydrogel based on 2-acrylamido-2-methylpropanesulfonic acid (AMPS) and acrylic acid (AA) was synthesized
via
free-radical polymerization. The system incorporates dynamic hydrogen bonds from guanine–cytosine (G–C) base pairs and homogeneously dispersed carbon nanotubes (CNTs) modified using a dual-ionic liquid strategy. Short-chain (C
4
) and long-chain (C
12
) imidazole-based ionic liquids act synergistically to exfoliate and stabilize CNTs
facilitating uniform dispersion and strong interfacial bonding. Owing to the continuous conductive pathways formed by the CNTs
the hydrogel exhibited enhanced electrical conductivity with a gauge factor of 5.61
together with excellent short-term cyclic stability and responsiveness for monitoring dynamic human motions. The combinat
ion of covalent cross-linking
reversible hydrogen bonding
and reinforced nanofillers endows the hydrogel with high stretchability
good adhesion (5.5 kPa)
and superior fatigue resistance
showing great potential for use in flexible wearable bioelectronics.
He, Y.; Liang, Y.; Gao, W.; Duan, X.; Guan, Y. High-fidelity distributed Brillouin sensing with optical mechanisms fusion and data transfer. Eng. Sci. 2025 , 38 , 1922..
Wang, P.; Hu, M.; Wang, H.; Chen, Z.; Feng, Y.; Wang, J.; Ling, W.; Huang, Y. The evolution of flexible electronics: From nature, beyond nature, and to nature. Adv. Sci. 2020 , 7 , 2001116..
Zeng, Y.; Tang, L.; Xiao, S.; Dong, Z.; Li, X.; Wang, T.; Liu, X.; Ma, Y.; Chu, F. A multi-sensor information fusion fault diagnosis method for hydropower turbine bearings based on multi-scale spatiotemporal graph neural networks. Eng. Sci. 2025 , 38 , 1882..
Li, S.; Bi, Y.; Liu, J.; Fu, G.; Chai, H.; Sun, C.; Feng, W. High-sensitivity piezoresistive biomass-derived carbon aerogel/polydimethylsiloxane composite with extreme temperature adaptability. Energy Environ. Mater. 2026 , 9 , e70079..
Xiang, X.; He, Q.; Xia, S.; Deng, Z.; Zhang, H.; Li, H. Study of capacitance type flexible electronic devices based on polyacrylamide and reduced graphene oxide composite hydrogel. Eur. Polym. J. 2022 , 171 , 111200..
Jiang, W.; Peng, Y.; Yao, J.; Li, Z.; Wang, L.; Liu, W. Cellulose and gum Arabic based nanocomposite hydrogel sensors for health monitoring and emergency medical signaling. Int. J. Biol. Macromol. 2025 , 323 , 147111..
Zhang, J.; He, Z.; Shen, B.; Li, J.; Tang, Y.; Pang, S.; Tian, X.; Wang, S.; Li, F. Mechanically tunable composite hydrogel for multi-gesture motion monitoring. Biosensors 2025 , 15 , 412..
Ju, H.; Jeong, J.; Kwak, P.; Kwon, M.; Lee, J. Robotic flexible electronics with self-bendable films. Soft Robot. 2018 , 5 , 710−717..
Dellatolas, I.; Bantawa, M.; Damerau, B.; Guo, M.; Divoux, T.; Del Gado, E.; Bischofberger, I. Local mechanism governs global reinforcement of nanofiller-hydrogel composites. ACS Nano 2023 , 17 , 20939−20948..
Qiu, A.; Jia, Q.; Yu, H.; Oh, J.-A.; Li, D.; Hsu, H.-Y.; Kawashima, N.; Zhuge, Y.; Ma, J. Highly sensitive and flexible capacitive elastomeric sensors for compressive strain measurements. Mater. Today Commun. 2021 , 26 , 102023..
Elangwe, C. N.; Morozkina, S. N.; Olekhnovich, R. O.; Krasichkov, A.; Polyakova, V. O.; Uspenskaya, M. V. A review on chitosan and cellulose hydrogels for wound dressings. Polymers 2022 , 14 , 5163..
Elnemr, M.; Halawani, Y.; Elkaffas, R. A.; Elkaffas, R.; Samad, Y. A.; Hisham, M.; Mohammad, B.; Butt, H. Artificial intelligence-enabled 4D printed hydrogel wearables: temperature and ultraviolet monitoring. ES Mater. Manuf. 2025 , 27 , 1428..
Hu, L.; Chee, P.-L.; Sugiarto, S.; Yu, Y.; Shi, C.; Yan, R.; Yao, Z.; Shi, X.; Zhi, J.; Kai, D.; Yu, H.-D.; Huang, W. Hydrogel-based flexible electronics. Adv. Mater. 2023 , 35 , 2205326..
Liang, Y.; Qiao, L.; Qiao, B.; Guo, B. Conductive hydrogels for tissue repair. Chem. Sci. 2023 , 14 , 3091−3116..
Mecwan, M.; Li, J.; Falcone, N.; Ermis, M.; Torres, E.; Morales, R.; Hassani, A.; Haghniaz, R.; Mandal, K.; Sharma, S.;Maity, S.; Zehtabi, F.; Zamanian, B.; Herculano, R.; Akbari, M.; John, J. V.; Khademhosseini, A. Recent advances in biopolymer-based hemostatic materials. Regen. Biomater. 2022 , 9 , rbac063..
Wang, Z.; Wei, H.; Huang, Y.; Wei, Y.; Chen, J. Naturally sourced hydrogels: Emerging fundamental materials for next-generation healthcare sensing. Chem. Soc. Rev. 2023 , 52 , 2992−3034..
Yan, X.; Li, H.; Wang, T.; Li, A.; Zhu, C.; Lu, G. Engineering of coordination environment in bioinspired laccase-mimicking catalysts for monitoring of pesticide poisoning. Chem. Eng. J. 2022 , 446 , 136930..
Zhang, Z.; Fu, H.; Li, Z.; Huang, J.; Xu, Z.; Lai, Y.; Qian, X.; Zhang, S. Hydrogel materials for sustainable water resources harvesting & treatment: Synthesis, mechanism and applications. Chem. Eng. J. 2022 , 439 , 135756..
Chen, L.; Wang, W.; Lin, Z.; Lu, Y.; Chen, H.; Li, B.; Li, Z.; Xia, H.; Li, L.; Zhang, T. Conducting molybdenum sulfide/graphene oxide/polyvinyl alcohol nanocomposite hydrogel for repairing spinal cord injury. J. Nanobiotechnol. 2022 , 20 , 210..
Ho, M.; Ramirez, A. B.; Akbarnia, N.; Croiset, E.; Prince, E.; Fuller, G. G.; Kamkar, M. Direct ink writing of conductive hydrogels. Adv. Funct. Mater. 2025 , 35 , 2415507..
Wang, X.; Zheng, S.; Xiong, J.; Liu, Z.; Li, Q.; Li, W.; Yan, F. Stretch-induced conductivity enhancement in highly conductive and tough hydrogels. Adv. Mater. 2024 , 36 , 2313845..
Grosskopf, A. K.; Mann, J. L.; Baillet, J.; Lopez Hernandez, H.; Autzen, A. A. A.; Yu, A. C.; Appel, E. A. Extreme extensibility in physically cross-linked nanocomposite hydrogels leveraging dynamic polymer–nanoparticle int eractions. Macromolecules 2022 , 55 , 7498−7511..
Zhou, T.; Wang, Y.; Zhou, J.; Yao, L.; He, K.; Chen, L.; Zhang, S.; Liu, H.; Chen, X.; Cui, S. Inorganic hydrogels can be flexible and highly extensible. Adv. Mater. 2025 , 37 , 2503910..
Zhang, X.; Zhang, H.; Lv, X.; Xie, T.; Chen, J.; Fang, D.; Yi, S. One-step of ionic liquid-assisted stabilization and dispersion: Exfoliated graphene and its applications in stimuli-responsive conductive hydrogels based on chitosan. Int. J. Biol. Macromol. 2024 , 271 , 132699..
Tropp, J.; Collins, C. P.; Xie, X.; Daso, R. E.; Mehta, A. S.; Patel, S. P.; Reddy, M. M.; Levin, S. E.; Sun, C.; Rivnay, J. Conducting polymer nanoparticles with intrinsic aqueous dispersibility for conductive hydrogels. Adv. Mater. 2024 , 36 , 2306691..
Huang, C.; Jiao, H.; Dang, R. Preparation of electroconductive hydrogel and its application in the sensing field. Mater. Today Commun. 2025 , 49 , 114319..
Yang, J.; Chen, Y.; Zhao, L.; Zhang, J.; Luo, H. Constructions a nd properties of physically cross-linked hydrogels based on natural polymers. Polym. Rev. 2023 , 63 , 574−612..
Klonos, P. A.; Bikiaris, R. D.; Terzopoulou, Z.; Mouchlianiti, K.; Tsachouridis, K.; Anastasiou,A. D.; Kyritsis, A.; Kyzas, G. Z. Structure-properties relationships in new polymer nanocomposites based on the renewable poly(butylene succinate) filled with low amounts of nanoparticles of 1-3D geometries. Polymer 2024 , 296 , 126841..
Mendhe, A. C.; Rengasamy, M.; Pradeep, H.; Bhoyar, T.; Chandirasekar, K.; Kore, A.; Elayappan, V.; Mendhe, A. B.; Mandal, S.; Rajaram, K.; Barse, N. S.; Hussain, I.; Kim, M.; Jadhav, S. B.; Noh, H. S.; Kim, Y.; Sun, M.; Lee, H. Recent advances and insights into carbon-based materials synergistically enhancing MXene for supercapacitor, battery, solar cell, and electrocatalytic applications. Coord. Chem. Rev. 2026 , 550 , 217400..
Chen, G.; Guo, Y.; Hsiao, S. B.; Hou, K.; Zhu, M. Tough, conductive hydrogels with double-network based on hydrophilic polymer assistant well-dispersed carbon nanotube for innovative force sensor. Sci. China Technol. Sci. 2022 , 65 , 1160−1168..
Kim, H.; Song, H.; Çakmakçı, N.; Kang, H.; Park, J.; Shin, M.; Jeong, Y. A flex ible supercapacitor prepared with surface modified carbon nanotube film electrode and hydrogel electrolyte. Fibres. Polym. 2021 , 22 , 2673−2679..
Kumar, R.; Cho, Y. S.; Kim, S. M. Carbon nanotubes for high-performance energy storage devices. Carbon Lett. 2026 , 36 , 1−20..
[Li, Z.; Tang, M.; Bai, W.; Bai, R. Preparation of hydrophilic encapsulated carbon nanotubes with polymer brushes and its application in composite hydrogels. Langmuir 2017 , 33 , 6092−6101..
Khan, M.; Ali Shah, L.; Rahman, T. U.; Ara, L.; Yoo, H.-M. Multiple-language-responsive conductive hydrogel composites for flexible strain and epidermis sensors. ACS Appl. Polym. Mater. 2024 , 6 , 4233−4243..
Kamaliya, B.; Dave, P. N.; Macwan, P. M. Oxidized multiwalled carbon nanotube reinforced rheological examination on Gum ghatti- cl-poly (acrylic acid) hydrogels. J. Appl. Polym. Sci. 2022 , 139 , e52888..
Fu, C.; Zhou, M.; Fu, H. Agarose-sodium alginate hydrogel beads enha nced with zeolitic imidazolate frameworks/multiwalled carbon nanotubes nanoparticles for efficient adsorption and selective separation of methylene blue. J. Appl. Polym. Sci. 2024 , 141 , e55003..
Wang, Y.; Li, L.; Ma, Y.; Tang, Y.; Zhao, Y.; Li, Z.; Pu, W.; Huang, B.; Wen, X.; Cao, X.; Chen, J.; Chen, W.; Zhou, Y.; Zhang, J. Multifunctional supramolecular hydrogel for prevention of epidural adhesion after laminectomy. ACS Nano 2020 , 14 , 8202−8219..
Khademi, Z.; Nikoofar, K. Applications of catalytic systems containing DNA nucleobases (adenine, cytosine, guanine, and thymine) in organic reactions. RSC Adv. 2025 , 15 , 3192−3218..
Shi, Y.; Li, D.; Ding, J.; He, C.; Chen, X. Physiologically relevant pH- and temperature-responsive polypeptide hydrogels with adhesive properties. Polym. Chem. 2021 , 12 , 2832−2839..
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