Effects of Different Nucleating Agents, Annealing and Pre-stretching Process on the Crystallinity and Mechanical Properties of Poly(butylene carbonate)

Rong Wu; Qin-Yao Jiang; Sheng Zou; Wei Bai; Qing-Yin Wang; Gong-Ying Wang; Shao-Ying Liu

doi:10.1007/s10118-026-3680-z

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Effects of Different Nucleating Agents, Annealing and Pre-stretching Process on the Crystallinity and Mechanical Properties of Poly(butylene carbonate)

RESEARCH ARTICLE | Updated：2026-05-12

- Effects of Different Nucleating Agents, Annealing and Pre-stretching Process on the Crystallinity and Mechanical Properties of Poly(butylene carbonate)
- Chinese Journal of Polymer Science Vol. 44, Issue 8, Pages: 2704-2713(2026)
- Affiliations：
  
  a.Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, China
  b.University of Chinese Academy of Sciences, Beijing 101400, China
- Author bio：
  
  baiwei@cioc.ac.cn
- Funds：
- DOI：10.1007/s10118-026-3680-z
  CLC： [M
- Received：06 February 2026，
  
  Revised：2026-03-05，
  
  Accepted：18 March 2026，
  
  Online First：09 May 2026，
  
  Published：15 August 2026
- Accepted：
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Wu, R.; Jiang, Q. Y.; Zou, S.; Bai, W.; Wang, Q. Y.; Wang, G. Y.; Liu, S. Y. Effects of different nucleating agents, annealing and pre-stretching process on the crystallinity and mechanical properties of poly(butylene carbonate). Chinese J. Polym. Sci. 2026, 44, 2704–2713

Rong Wu, Qin-Yao Jiang, Sheng Zou, et al. Effects of Different Nucleating Agents, Annealing and Pre-stretching Process on the Crystallinity and Mechanical Properties of Poly(butylene carbonate)[J]. Chinese Journal of Polymer Science, 2026, 44(8): 2704-2713.
Wu, R.; Jiang, Q. Y.; Zou, S.; Bai, W.; Wang, Q. Y.; Wang, G. Y.; Liu, S. Y. Effects of different nucleating agents, annealing and pre-stretching process on the crystallinity and mechanical properties of poly(butylene carbonate). Chinese J. Polym. Sci. 2026, 44, 2704–2713 DOI： 10.1007/s10118-026-3680-z.

Rong Wu, Qin-Yao Jiang, Sheng Zou, et al. Effects of Different Nucleating Agents, Annealing and Pre-stretching Process on the Crystallinity and Mechanical Properties of Poly(butylene carbonate)[J]. Chinese Journal of Polymer Science, 2026, 44(8): 2704-2713. DOI： 10.1007/s10118-026-3680-z.

摘要

Nucleating agents enhance poly(butylene carbonate) (PBC) performance with annealing and stretching

improving crystallinity and mechanical properties. PBC/SiO

strength rose to 61.96 MPa (annealed) and 83.26 MPa (stretched)

though agent dispersion varies.

Abstract

Poly(butylene carbonate) (PBC)

a biodegradable aliphatic polycarbonate

is limite

d by its suboptimal thermal and mechanical properties. This study enhanced PBC by incorporating nanoscale nucleating agents combined with isothermal annealing and pre-stretching. The results indicate that the dispersion and interfacial interactions of different nucleating agents within the PBC matrix vary significantly. Among them

SiO

demonstrate good dispersion and compatibility

effectively enhancing the storage modulus and crystallization kinetics. Isothermal annealing and pre-stretching treatments further synergistically improved the crystallinity and mechanical performance of the composites: after annealing

the tensile strength of PBC/SiO

increased to 61.96 MPa

and after pre-stretching

it reached 83.26 MPa. Dynamic mechanical analysis and differential scanning calorimetry results consistently show that the incorporation of nucleating agents raises the glass transition temperature and thermal stability of the materials. This research provides systematic experimental evidence and process optimization strategies for the high-performance modification of PBC.

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references

Zhang, J.; Zhu, W.; Li, C.; Zhang, D.; Xiao, Y.; Guan, G.; Zheng, L. Effect of the biobased linear long-chain monomer on crystallization and biodegradation behaviors of poly(butylene carbonate)-based copolycarbonates. RSC Adv. 2015 , 5 , 2213−2222..

Jiao, D.; Cai, X.; Song, Q.; Zhou, R.; Peng, X.; Bao, D. Biodegradable aliphatic poly(carbonate-co-ester)s containing biobased unsaturated double bonds: synthesis and structure-property relationships. Polym. J. 2022 , 54 , 47−55..

Kim, H.; Jeon, H.; Shin, G.; Lee, M.; Jegal, J.; Hwang, S. Y.; Oh, D. X.; Koo, J. M.; Eom, Y.; Park, J. Biodegradable nanocomposite of poly(ester-co-carbonate) and cellulose nanocrystals for tough tear-resistant disposable bags. Green Chem. 2021 , 23 , 2293−2299..

Liu, L.; Lu, Y.; Xia, M.; Wang, B.; Cheng, Y.; Wei, Z. Synthesis, thermal and barrier properties of biodegradable aliphatic polycarbonates with different chain lengths. J. Therm. Anal. Calorim. 2023 , 148 , 10163−10174..

Qiu, Z.; Miao, L.; Yang, W. Crystallization and meltingbehavior of biodegradable poly(butylene succinate-co-butylene carbonate). Polym. Sci Pt B-Polym Phys. 2006 , 44 , 1556−1561..

[Tu, Z.; Lu, Y.; Liu, L.; Wang, L.; Li, Y.; Wei, Z. Modification of biodegradable poly(butylene carbonate) by biobased cis-2-butene-1,4-diol. Eur. Polym. J . 2023, 198 , 112432..

Yang, S.; Wu, R.; Bai, W.; Wang, Q.; Li, J.; Wang, G. Preparation and properties of multiblock polyester synthesized by chain extension copolymerization of poly(L-lactic acid) and poly(butylene carbonate) prepolymer. J. Polym. Environ. 2025 , 33 , 2267−2279..

[Zhang, F.; Jiang, Z.; Qiu, Z. Biobased poly(ethylene succinate)- b -poly(triethylene terephthalate) multiblock copolyesters with high melting temperature and improved crystallization rate and mechanical property. Polymer 2022, 254 , 125061..

Wang, J.; Zheng, L.; Li, C.; Zhu, W. ; Zhang, D.; Xiao, Y.; Guan, G. Fully biodegradable blends of poly(butylene succinate) and poly(butylene carbonate): Miscibility, thermal properties, crystallization behavior and mechanical properties. Polym. Test. 2012 , 31 , 39−45..

Li, Y.; Han, C.; Yu, Y.; Huang, D. Morphological, thermal, rheological and mechanical properties of poly (butylene carbonate) reinforced by stereocomplex polylactide. Int J. Biol. Macromol. 2019 , 137 , 1169−1178..

Wang, X.; Zhuang, Y.; Dong, L. Study of biodegradable polylactide/poly(butylene carbonate) blend. J. Appl. Polym. Sci. 2012 , 127 , 471−477..

Wang, X.; Zhuang, Y.; Dong, L. Properties of biodegradable poly(butylene carbonate) (PBC) composites with fumed silica nanoparticles. J. Therm. Anal. Calorim. 2013 , 114 , 77−84..

[Zhu, W. Strudy on Biodegradable Aliphatic Polycarbonates Synthesized via Transesterification . Doctoral of University of Chinese Academy of Sciences, 2011 ..

[Wu, R.; Yang, S.; Zou, S.; Li, J.; Bai, W.; Wang, Q. Refining crystallization, mechanical, and degradation properties of poly(butylene carbonate) via isothermal annealing treatment. ChemistrySelect 2025, 10 , e01806..

Wu, R.; Luo, M.; Wang, Z. Q.; Bai, W.; Wang, Q. Y. Unidirectional pre-stretching and isothermal annealing reinforced poly(butylene carbonate) sheets at room temperature. Chinese J. Polym. Sci. 2025 , 43 , 1863−1874..

Pokharkar, V.; Sivaram, S. Poly(alkylene carbonate)s by the carbonate interchange reaction of aliphatic diols with dimethyl carbonate: synthesis and characterization. Polymer 1995 , 36 , 4851−4854..

Wang, Z.; Yang, X.; Li, J.; Liu, S.; Wang, G. Synthesis of high-molecular-weight aliphatic polycarbonates from diphenyl carbonate and aliphatic diols by solid base. J. Mol. Catal. A-Chem. 2016 , 424 , 77−84..

Wang, Z. Q.; Bai, Y. S.; Jiang, W.; Yang, X. G.; Liu, S. Y.; Wang, G. Y. Structure-activity correlations of calcined Mg-Al hydrocalcites for aliphatic polycarbonate synthesis via transesterification process. Chinese J. Polym. Sci. 2016 , 35 , 130−140..

Jordan, J.; Jacob, K. I.; Tannenbaum, R.; Sharaf, M. A.; Jasiuk, I. Experimental trends in polymer nanocomposites—a review. Mat Sci Eng A-Struct 2005 , 393 , 1−11..

Fu, S. Y.; Feng, X. Q.; Lauke, B.; Mai, Y.-W. Effects of particle size, particle/matrix interface adhesion and particle loading on mechanical properties of particulate–polymer composites. Compos. Part B-Eng. 2008 , 39 , 933−961..

Schaefer, D. W.; Justice, R. S. How nano are nanocomposites. Macromolecules 2007 , 40 , 8501−8517..

Zhu, W.; Zhou, W.; Li, C.; Xiao, Y.; Zhang, D.; Guan, G.; Wang, D. Synthesis, characterization and degradation of novel biodegradable poly(butylene-co-hexamethylene carbonate) copolycarbonates. J. Macromol. Sci. A 2011 , 48 , 583−594..

Zhu, W.; Huang, X.; Li, C.; Xiao, Y.; Zhang, D.; Guan, G. High-molecular-weight aliphatic polycarbonates by melt polycondensation of dimethyl carbonate and aliphatic diols: synthesis and characterization. Polym. Int. 2011 , 60 , 1060−1067..

Lu, Y.; Tu, Z.; Cheng, Y.; Liu, L.; Leng, X.; Wei, Z.; Li, Y. Kilogram-scale production of biodegradable poly(butylene carbonate): molecular weight dependence of physical properties and enhanced crystallization by nucleating agent. J. Polym. Environ. 2022 , 31 , 1510−1524..

Du, X. C.; Li, Z. C.; Mao, A. M.; Wang, P. X.; Ma, J.; Wang, Z. Q. Synthesis and properties of poly(ethylene succinate)- b -poly(butylene carbonate) multiblock copolymers. Chinese J. Polym. Sci. 2026 , 44 , 743−755.

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