Recent Advances in Asymmetric Structural Composites for Excellent Electromagnetic Interference Shielding: A Review

Ying Zhou; Bai Xue; Lan Xie; Chang-Mei Wu; Qiang Zheng

doi:10.1007/s10118-024-3112-x

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Recent Advances in Asymmetric Structural Composites for Excellent Electromagnetic Interference Shielding: A Review

REVIEW | Updated：2024-05-11

- Recent Advances in Asymmetric Structural Composites for Excellent Electromagnetic Interference Shielding: A Review
- Chinese Journal of Polymer Science Vol. 42, Issue 6, Pages: 693-710(2024)
- Affiliations：
  
  a.Department of Polymer Materials and Engineering, College of Materials and Metallurgy, Guizhou University, Guiyang 550025, China
  b.State Key Laboratory of Public Big Data, Guizhou University, Guiyang 550025, China
  c.National Engineering Research Center for Compounding and Modification of Polymer Materials; National and Local Joint Engineering Research Center for Functional Polymer Membrane Materials and Membrane Processes, Guiyang 550014, China
  d.Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
- Author bio：
  
  mm.lanxie@gzu.edu.cn (L.X.)
  zhengqiang@zju.edu.cn (Q.Z.)
- Funds：
- DOI：10.1007/s10118-024-3112-x
  CLC：
- Received：18 December 2023，
  
  Revised：2024-2-13，
  
  Accepted：27 February 2024，
  
  Online First：10 April 2024，
  
  Published：01 June 2024
- Accepted：
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Zhou, Y.; Xue, B.; Xie, L.; Wu, C. M.; Zheng, Q. Recent advances in asymmetric structural composites for excellent electromagnetic interference shielding: a review. Chinese J. Polym. Sci. 2024, 42, 693–710

Ying Zhou, Bai Xue, Lan Xie, et al. Recent Advances in Asymmetric Structural Composites for Excellent Electromagnetic Interference Shielding: A Review[J]. Chinese Journal of Polymer Science, 2024, 42(6): 693-710.
Zhou, Y.; Xue, B.; Xie, L.; Wu, C. M.; Zheng, Q. Recent advances in asymmetric structural composites for excellent electromagnetic interference shielding: a review. Chinese J. Polym. Sci. 2024, 42, 693–710 DOI： 10.1007/s10118-024-3112-x.

Ying Zhou, Bai Xue, Lan Xie, et al. Recent Advances in Asymmetric Structural Composites for Excellent Electromagnetic Interference Shielding: A Review[J]. Chinese Journal of Polymer Science, 2024, 42(6): 693-710. DOI： 10.1007/s10118-024-3112-x.

摘要

Asymmetric structural composite development and EMI shielding mechanisms are reviewed. The structure and properties of multi-layered

porous

fibrous

and segregated asymmetric structural EMI shielding composites are accurately described. Nano-fillers with different magnetic

electrical and dielectric properties play a decisive role in the asymmetric EMI shielding composites are also described.

Abstract

Since electromagnetic pollution is detrimental to human health and the environment

numerous efforts have been successively made to achieve excellent electromagnetic interference shielding effectiveness (EMI SE)

via

designing the hierarchical structures for electromagnetic interference (EMI) shielding polymer composites. Among the plentiful structures

the asymmetric structures are currently a hot spot

principally categorizing into multi-layered

porous

fibrous

and segregated asymmetric structures

which endows the high EMI shielding performance for polymer composites incorporated with magnetic

conductive

and/or dielectric micro/nano-fillers

due to the “absorption-reflection-reabsorption” shielding mechanism. Therefore

this review provides the retrospection and summary of the efforts with respect to abundant asymmetric structures and multifunctional micro/nano-fillers for enhancing EMI shielding properties

which is conducive to the booming development of polymeric EMI shielding materials for the promising prospect in modern electronics and 5-generation (5G) technology.

关键词

Keywords

references

Zhang, Y.; Gu, J. A perspective for developing polymer-based electromagnetic interference shielding composites. Nano-Micro Lett. 2022 , 14 , 89..

Choi, Y. S.; Yoo, Y. H.; Kim, J. G.; Kim, S. H. A comparison of the corrosion resistance of Cu-Ni-stainless steel multilayers used for EMI shielding. Surf. Coat. Tech. 2006 , 201 , 3775−3782..

Zhang, C.; Li, Y.; Kang, W.; Liu, X.; Wang, Q. Current advances and future perspectives of additive manufacturing for functional polymeric materials and devices. SusMat 2021 , 1 , 127−147..

Geetha, S.; Satheesh, K. K. K.; Rao, C . R. K.; Vijayan, M.; Trivedi, D. C. EMI shielding: methods and materials—a review. J. Appl. Polym. Sci. 2009 , 112 , 2073−2086..

Liang, C.; Song, P.; Qiu, H.; Huang, F. Y.; Lu, Y.; Wang, L.; Kong, J.; Gu, J. Superior electromagnetic interference shielding performances of epoxy composites by introducing highly aligned reduced graphene oxide films. Compos. Part A: Appl. S. 2019 , 124 , 105512..

Liang, C.; Qiu, H.; Zhang, Y.; Liu, Y.; Gu, J. External field-assisted techniques for polymer matrix composites withelectromagnetic interference shielding. Sci. Bull. 2023 , 68 , 1938−1953..

Song, W. L.; Cao, M. S.; Lu, M. M.; Bi, S.; Wang, C. Y.; Liu, J.; Yuan, J.; Fan, L. Z. Flexible graphene/polymer composite films in sandwich structures for effective electromagnetic interference shielding. Carbon 2014 , 66 , 67−76..

Onar, N.; Akşit, A. C.; Ebeoglugil, M. F.; Birlik, I.; Celik, E.; Ozdemir, I. Structural, electrical, and electromagnetic properties of cotton fabrics coated with polyaniline and polypyrrole. J. Appl. Polym. Sci. 2009 , 114 , 2003−2010..

Chen, Y. H.; Huang, C. Y.; Roan, M. L.; Lai, F. D.; Chen, K. N.; Yeh, J. T. The copper sulfide coating on polyacrylonitrile with a chelating agent of ethylenediaminetetraacetic acid by an electroless deposition method and its EMI shielding effectiveness. J. Appl. Polym. Sci. 2010 , 115 , 570−578..

Sun, R.; Zhang, H. B.; Liu, J.; Xie, X.; Yang, R.; Li, Y.; Hong, S.; Yu, Z. Z. Highly conductive transition metal carbide/carbonitride(MXene)@polystyrene nanocomposites fabricated by electrostatic assembly for highly efficient electromagnetic interference shielding. Adv. Funct. Mater. 2017 , 27 , 1702807..

Li, Z.; Li, X.; Zong, Y.; Tan, G.; Sun, Y.; Lan, Y.; He, M.; Ren, Z.; Zheng, X. Solvothermal synthesis of nitrogen-doped graphene decorated by superparamagnetic Fe 3 O 4 nanoparticles and their applications as enhanced synergistic microwave absorbers. Carbon 2017 , 115 , 493−502..

Sankaran, S.; Deshmukh, K.; Ahamed, M. B.; Khadheer, P. S. K. Recent advances in electromagnetic interference shielding properties of metal and carbon filler reinforced flexible polymer composites: a review. Compos. Part A: Appl. S 2018 , 114 , 49−71..

Wang, Y.; Gao, X.; Wu, X.; Luo, C. Facile synthesis of Mn 3 O 4 hollow polyhedron wrapped by multiwalled carbon nanotubes as a high-efficiency microwave absorber. Ceram. Int. 2020 , 46 , 1560−1568..

Jiang, D.; Murugadoss, V.; Wang, Y.; Lin, J.; Ding, T.; Wang, Z.; Shao, Q.; Wang, C.; Liu, H.; Lu, N.; Wei, R.; Subramania, A.; Guo, Z. Electromagnetic interference shielding polymers and nanocomposites—a review. Polym. Rev. 2019 , 59 , 280−337..

Han, Y.; Ruan, K.; Gu, J. Janus (BNNS/ANF)-(AgNWs/ANF) thermal conductivity composite films with superior electromagnetic interference shielding and Joule heating performances. Nano Res. 2022 , 15 , 4747−4755..

Zhou, H.; Deng, H.; Zhang, L.; Wu, Z.; Deng, S.; Yang, W.; Zhang, Q.; Chen, F.; Fu, Q. Toward multi-functional polymer composites through selectively distributing functional fillers. Compos. Part A: Appl. S 2016 , 82 , 20−33..

Wen, C.; Zhao, B.; Liu, Y.; Xu, C.; Wu, Y.; Cheng, Y.; Liu, J.; Liu, Y.; Yang, Y.; Pan, H.; Zhang, J.; Wu, L.; Che, R. Flexible MXene-based composite films for multi-spectra defense in radar, infrared and visible light bands. Adv. Funct. Mater. 2023 , 33 , 2214223..

Sambyal, P.; Iqbal, A.; Hong, J.; Kim, M. K.; Kim, I. D.; Koo, C. M. Conductive MXene composites with liquid metal for high-performance electromagnetic interference shielding. Mater. Chem. Phys. 2023 , 295 , 127184..

Wang, W. Y.; Ma, X.; Shao, Y. W.; Qi, X. D.; Yang, J. H.; Wang, Y. Flexible, multifunctional, and thermally conductive nylon/graphene nanoplatelet composite papers with excellent EMI shielding performance, improved hydrophobicity and flame resistance. J. Mater. Chem. A 2021 , 9 , 5033−5044..

Wang, M.; Tang, X. H.; Cai, J. H.; Wu, H.; Shen, J. B.; Guo, S. Y. Construction, mechanism and prospective of conductive polymer composites with multiple interfaces for electromagnetic interference shielding: a review. Carbon 2021 , 177 , 377−402..

Li, N.; Huang, G. W.; Li, Y. Q.; Xiao, H. M.; Feng, Q. P.; Hu, N.; Fu, S. Y. Enhanced microwave absorption performance of coated carbon nanotubes by optimizing the Fe 3 O 4 nanocoating structure. ACS Appl. Mater. Interfaces 2017 , 9 , 2973−2983..

Zeng, S.; Li, X.; Li, M.; Zheng, J.; E, S.; Yang, W.; Zhao, B.; Guo, X.; Zhang, R. Flexible PVDF/CNTs/Ni@CNTs composite films possessing excellent electromagnetic interference shielding and mechanical properties under heat treatment. Carbon 2019 , 155 , 34−43..

Liang, C.; Song, P.; Qiu, H.; Zhang, Y.; Ma, X.; Qi, F.; Gu, H.; Kong, J.; Cao, D.; Gu, J. Constructing interconnected spherical hollow conductive networks in silver platelets/reduced graphene oxide foam/epoxy nanocomposites for superior electromagnetic interference shielding effectiveness. Nanoscale 2019 , 11 , 22590−22598..

Li, X. H.; Li, X.; Liao, K. N.; Min, P.; Liu, T.; Dasari, A.; Yu, Z. Z. Thermally annealed anisotropic graphene aerogels and their electrically conductive epoxy composites with excellent electromagnetic interference shielding efficiencies. ACS Appl. Mater. Interfaces 2016 , 8 , 33230−33239..

Al-Saleh, M. H.; Saadeh, W. H.; Sundararaj, U. EMI shielding effectiveness of carbon based nanostructured polymeric materials: a comparative study. Carbon 2013 , 60 , 146−156..

Gu, J.; Ruan, K. Breaking through bottlenecks for thermally conductive p olymer composites: a perspective for intrinsic thermal conductivity, interfacial thermal resistance and theoretics. Nanomicro Lett. 2021 , 13 , 110..

Li, W.; Li, X.; Chang, W.; Wu, J.; Liu, P.; Wang, J.; Yao, X.; Yu, Z. Z. Vertically aligned reduced graphene oxide/Ti 3 C 2 T x MXene hybrid hydrogel for highly efficient solar steam generation. Nano Res. 2020 , 13 , 3048−3056..

Yin, D.; Pan, Y.; Guo, Q.; Wang, Y.; Huang, J. Preparation and properties of flexible nanocellulose fibers/Ag nanoparticles composite films with excellent electromagnetic shielding performance. Appl. Phys. A-Mater. 2021 , 128 , 43..

Sorgucu, U. Enhancing the electromagnetic shielding effectiveness of alumina (Al 2 O 4 ) by coating with nano gold (AuNp). Opt. Mater. 2024 , 148 , 114795..

Gu, T.; Zeng, Z.; Wu, S.; Sun, D. X.; Zhao, C. S.; Wang, Y. Poly(L-lactic acid)/graphene composite films with asymmetric sandwich structure for thermal management and electromagnetic interference shielding. Chem. Eng. J. 2023 , 466 , 143190..

Lu, X.; Zheng, Y.; Yang, J.; Qu, J. Multifunctional paraffin wax/carbon nanotube sponge composites with simultaneous high-efficient thermal management and electromagnetic interference shielding efficiencies for electronic devices. Compos. Part B: Eng. 2020 , 199 , 108308..

Wang, L.; Chen, L.; Song, P.; Liang, C.; Lu, Y.; Qiu, H.; Zhang, Y.; Kong, J.; Gu, J. Fabrication on the annealed Ti 3 C 2 T x MXene/epoxy nanocomposites for electromagnetic interference shielding application. Compos. Part B: Eng. 2019 , 171 , 111−118..

Qin, F.; Brosseau, C. A review and analysis of microwave absorption in polymer composites filled with carbonaceous particles. J. Appl. Phys . 2012 , 111 ..

Wu, T.; Liu, Y.; Zeng, X.; Cui, T.; Zhao, Y.; Li, Y.; Tong, G. Facile hydrothermal synthesis of Fe 3 O 4 /C core-shell nanorings for efficient low-frequency microwave absorption. ACS Appl. Mater. Interfaces 2016 , 8 , 7370−7380..

González, M.; Pozuelo, J.; Baselga, J. Electromagnetic shielding materials in GHz rang e. Chem. Rec. 2018 , 18 , 1000−1009..

Singh, A. K.; Shishkin, A.; Koppel, T.; Gupta, N. A review of porous lightweight composite materials for electromagnetic interference shielding. Compos. Part B: Eng. 2018 , 149 , 188−197..

Yang, S.; Yang, P.; Ren, C.; Zhao, X.; Zhang, J. Millefeuille-inspired highly conducting polymer nanocomposites based on controllable layer-by-layer assembly strategy for durable and stable electromagnetic interference shielding. J. Colloid. Interf. Sci. 2022 , 622 , 97−108..

Li, L.; Ma, Z.; Xu, P.; Zhou, B.; Li, Q.; Ma, J.; He, C.; Feng, Y.; Liu, C. Flexible and alternant-layered cellulose nanofiber/graphene film with superior thermal conductivity and efficient electromagnetic interference shielding. Compos. Part A: Appl. S 2020 , 139 , 106134..

He, W.; Chen, G.; Li, C.; Chen, X.; Chen, Y.; Xiong, M.; Niu, X.; Zhu, M.; Li, X. Magnetically aligned CNT/magnetite heterogeneous composite membranes for electromagnetic wave shielding and heat dissipation. Mater. Res. Bull. 2022 , 149 , 111748..

Tao, Q.; Men, C.; Li, C.; Cong, S.; Hu, D.; Li, Q. A Janus-structured Fe 3 O 4 -PDMS/CNT/Cu composite film for extreme-environmental electromagnetic interference shielding. Mater. Lett. 2022 , 326 , 132892..

Hu, G.; Wu, C.; Wang, Q.; Dong, F.; Xiong, Y. Ultrathin nanocomposite films with asymmetric gradient alternating multilayer structures exhibit superhigh electromagnetic interference shielding performances and robust mechanical properties. Chem. Eng. J. 2022 , 447 , 137537..

Xu, Y.; Yang, Y.; Yan, D. X.; Duan, H.; Zhao, G.; Liu, Y. Gradient structure design of flexible waterborne polyurethane conductive films for ultraefficient electromagnetic shielding with low reflection characteristic. ACS Appl. Mater. Interfaces 2018 , 10 , 19143−19152..

Sheng, A.; Ren, W.; Yang, Y.; Yan, D. X.; Duan, H.; Zhao, G.; Liu, Y.; Li, Z. M. Multilayer WPU conductive composites with controllable electro-magnetic gradient for absorption-dominated electromagnetic interference shielding. Compos. Part A: Appl. S 2020 , 129 , 105692..

Zhou, B.; Li, Q.; Xu, P.; Feng, Y.; Ma, J.; Liu, C.; Shen, C. An asymmetric sandwich structural cellulose-based film with self-supported MXene and AgNW layers for flexible electromagnetic interference shielding and thermal management. Nanoscale 2021 , 13 , 2378−2388..

Zhang, F.; Ren, P.; Guo, Z.; Wang, J.; Chen, Z.; Zong, Z.; Hu, J.; Jin, Y.; Ren, F. Asymmetric multilayered MXene-AgNWs/cellulose nanofiber composite films with antibacterial properties for high-efficiency electromagnetic interference shielding. J. Mater. Sci. Technol. 2022 , 129 , 181−189..

Guo, Z.; Ren, P.; Lu, Z.; Hui, K.; Yang, J.; Zhang, Z.; Chen, Z.; Jin, Y.; Ren, F. Multifunctional CoFe 2 O 4 @MXene-AgNWs/cellulose nanofiber composite films with asymmetric layered architecture for high-efficiency electromagnetic interference shielding and remarkable thermal management capability. ACS Appl. Mater. Interfaces 2022 , 14 , 41468−41480..

Cao, W.; Ma, C.; Tan, S.; Ma, M.; Wan, P.; Chen, F. Ultrathin and flexible CNTs/MXene/cellulose nanofibrils composite paper for electromagnetic interference shielding. Nanomicro Lett. 2019 , 11 , 72..

Lai, Z.; Cheng, K.; Zhao, T.; Zhu, P.; Liu, D.; Liang, X.; Sun, R. A facile process to fabricate copper/nickel-coated polyurethane composite with high electromagnetic interference shie lding performance. Compos. Commun. 2023 , 38 , 101487..

Yuan, M.; Fei, Y.; Zhang, H.; Qiu, B.; Shen, L.; He, X.; Liang, M.; Zhou, S.; Chen, Y.; Zou, H. Electromagnetic asymmetric films comprise metal organic frameworks derived porous carbon for absorption-dominated electromagnetic interference shielding. Compos. Part B: Eng. 2022 , 233 , 109622..

Mai, T.; Guo, W. Y.; Wang, P. L.; Chen, L.; Qi, M. Y.; Liu, Q.; Ding, Y.; Ma, M. G. Bilayer metal-organic frameworks/MXene/nanocellulose paper with electromagnetic double loss for absorption-dominated electromagnetic interference shielding. Chem. Eng. J. 2023 , 464 , 142517..

Breuer, O.; Sundararaj, U. Big returns from small fibers: a review of polymer/carbon nanotube composites. Polym. Compos. 2004 , 25 , 630−645..

Gong, S.; Zhu, Z. H.; Meguid, S. A. Carbon nanotube agglomeration effect on piezoresistivity of polymer nanocomposites. Polymer 2014 , 55 , 5488−5499..

Gong, S.; Zhu, Z. H.; Li, J.; Meguid, S. A. Modeling and characterizatio n of carbon nanotube agglomeration effect on electrical conductivity of carbon nanotube polymer composites. J. Appl. Phys. 2014 , 116 , 194306..

Chen, Y.; Zhang, H. B.; Yang, Y.; Wang, M.; Cao, A.; Yu, Z. Z. High-performance epoxy nanocomposites reinforced with three-dimensional carbon nanotube sponge for electromagnetic interference shielding. Adv. Funct. Mater. 2016 , 26 , 447−455..

He, Q. M.; Tao, J. R.; Yang, Y.; Yang, D.; Zhang, K.; Fei, B.; Wang, M. Electric-magnetic-dielectric synergism and Salisbury screen effect in laminated polymer composites with multiwall carbon nanotube, nickel, and antimony trioxide for enhancing electromagnetic interference shielding. Compos. Part A: Appl. S. 2022 , 156 , 106901..

Balandin, A. A.; Ghosh, S.; Bao, W.; Calizo, I.; Teweldebrhan, D.; Miao, F.; Lau, C. N. Superior thermal conductivity of single-layer graphene. Nano Lett. 2008 , 8 , 902−907..

Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.; Zhang, Y.; Dubonos, S. V.; Grigorieva, I. V.; Firsov, A. A. Electric field effect in atomically thin carbon films. Science 2004 , 306 , 666−669..

Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.; Katsnelson, M. I.; Grigorieva, I. V.; Dubonos, S. V.; Firsov, A. A. Two-dimensional gas of massless Dirac fermions in graphene. Nature 2005 , 438 , 197−200..

Lin, J. H.; Lin, Z. I.; Pan, Y. J.; Huang, C. L.; Chen, C. K.; Lou, C. W. Polymer composites made of multi-walled carbon nanotubes and graphene nano-sheets: Effects of sandwich structures on their electromagnetic interference shielding effectiveness. Compos. Part B: Eng. 2016 , 89 , 424−431..

Sefadi, J. S.; Luyt, A. S.; Pionteck, J.; Piana, F.; Gohs, U. Effect of surfactant and electron treatment on the electrical and thermal conductivity as well as thermal and mechanical properties of ethylene vinyl acetate/expanded graphite composites. J. Appl. Polym. Sci. 2015 , 132 , 42396..

Konkena, B.; Vasudevan, S. Understanding aqueous dispersibility of graphene oxide and reduced graphene oxide through p K a measurements. J. Phys. Chem. Lett. 2012 , 3 , 867−872..

Zhang, Y.; Ruan, K.; Zhou, K.; Gu, J. Controlled distributed Ti 3 C 2 T x hollow microspheres on thermally conductive polyimide composite films for excellent electromagnetic interference shielding. Adv. Mater. 2023 , 35 , 2211642..

Wang, J.; Song, T.; Ming, W.; Yele, M.; Chen, L.; Zhang, H.; Zhang, X.; Liang, B.; Wang, G. High MXene loading, nacre-inspired MXene/ANF electromagnetic interference shielding composite films with ultralong strain-to-failure and excellent Joule heating performance. Nano Res. 2024 , 17 , 2061−2069..

Gong, S.; Sheng, X.; Li, X.; Sheng, M.; Wu, H.; Lu, X.; Qu, J. A multifunctional flexible composite film with excellent multi-source driven thermal management, electromagnetic interference shielding, and fire safety performance, inspired by a “brick-mortar” sandwich structure. Adv. Funct. Mater. 2022 , 32 , 2200570..

Li, M.; Sun, Y.; Feng, D.; Ruan, K.; Liu, X.; Gu, J. Thermally conductive polyvinyl alcohol composite films via introducing hetero-structured MXene@silver fillers. Nano Res. 2023 , 16 , 7820−7828..

Maleski, K.; Mochalin, V. N.; Gogotsi, Y. Dispersions of two-dimensional titanium carbide MXene in organic solvents. Chem. Mater. 2017 , 29 , 1632−1640..

Velusamy, D. B.; Kim, R. H.; Cha, S.; Huh, J.; Khazaeinezhad, R.; Kassani, S. H.; Song, G.; Cho, S. M.; Cho, S. H.; Hwang, I.; Lee, J.; Oh, K.; Choi, H.; Park, C. Flexible transition metal dichalcogenide nanosheets for band-selective photodetection. Nat. Commun. 2015 , 6 , 8063..

Sundaram, H. S.; Han, X.; Nowinski, A. K.; Ella-Menye, J. R.; Wimbish, C.; Marek, P.; Senecal, K.; Jiang, S. One-step dip coating of zwitterionic sulfobetaine polymers on hydrophobic and hydrophilic surfaces. ACS Appl. Mater. Interfaces 2014 , 6 , 6664−6671..

Carey, T.; Jones, C.; Le Moal, F.; Deganello, D.; Torrisi, F. Spray-coating thin films on three-dimensional surfaces for a semitransparent capacitive-touch device. ACS Appl. Mater. Interfaces 2018 , 10 , 19948−19956..

Jo, J. W.; Jung, J. W.; Lee, J. U.; Jo, W. H. Fabrication of highly conductive and transparent thin films from single-walled carbon nanotubes using a new non-ionic surfactant via spin coating. ACS Nano 2010 , 4 , 5382−5388..

Yun, T.; Kim, J . S.; Shim, J.; Choi, D. S.; Lee, K. E.; Koo, S. H.; Kim, I.; Jung, H. J.; Yoo, H. W.; Jung, H. T.; Kim, S. O. Ultrafast interfacial self-assembly of 2D transition metal dichalcogenides monolayer films and their vertical and in-plane heterostructures. ACS Appl. Mater. Interfaces 2017 , 9 , 1021−1028..

Zhang, Y.; Ruan, K.; Guo, Y.; Gu, J. Recent advances of MXenes-based optical functional materials. Adv. Photon. Res. 2023 , 4 , 2300224..

Liu, Q.; Zhang, Y.; Liu, Y.; Li, C.; Liu, Z.; Zhang, B.; Zhang, Q. Magnetic field-induced strategy for synergistic CI/Ti 3 C 2 T x /PVDF multilayer structured composite films with excellent electromagnetic interference shielding performance. J. Mater. Sci. Technol. 2022 , 110 , 246−259..

Wang, Y.; Zhang, W.; Wu, X.; Luo, C.; Liang, T.; Yan, G. Metal-organic framework nanoparticles decorated with graphene: a high-performance electromagnetic wave absorber. J. Magn. Magn. Mater. 2016 , 416 , 226−230..

Yang, D.; Zhang, C.; Biendicho, J. J.; Han, X.; Liang, Z.; Du, R.; Li, M.; Li, J.; Arbiol, J.; Llorca, J.; Zhou, Y.; Morante, J. R.; Cabot, A. ZnSe/N-doped carbon nanoreactor with multiple adsorption sites for stable lithium-sulfur batteries. ACS Nano 2020 , 14 , 15492−15504..

Zhang, Y.; Yang, S.; Zhang, Q.; Ma, Z.; Guo, Y.; Shi, M.; Wu, H.; Guo, S. Constructing interconnected asymmetric conductive network in TPU fibrous film: achieving low-reflection electromagnetic interference shielding and surperior thermal conductivity. Carbon 2023 , 206 , 37−44..

Zhang, Y.; Ma, Z.; Ruan, K.; Gu, J. Flexible Ti 3 C 2 T x /(aramid nanofiber/PVA) composite films for superior electromagnetic interference shielding. Research 2022 , 2022 , 9780290..

Yang, M.; Jia, X.; He, D.; Ma, Y.; Cheng, Y.; Wang, J.; Li, Y.; Wang, C. Superhydrophobic and corrosion-resistant electrospun hybrid membrane for high-efficiency electromagnetic interference shielding. ACS Appl. Electron. Mater. 2021 , 3 , 2067−2078..

Cui, C.; Xiang, C.; Geng, L.; Lai, X.; Guo, R.; Zhang, Y.; Xiao, H.; Lan, J.; Lin, S.; Jiang, S. Flexible and ultrathin electrospun regenerate cellulose nanofibers and d-Ti 3 C 2 T x (MXene) composite film for electromagnetic interference shielding. J. Alloy. Compd. 2019 , 788 , 1246−1255..

Kim, M.; Kim, S.; Seong, Y. C.; Yang, K. H.; Choi, H. Multiwalled carbon nanotube buckypaper/polyacrylonitrile nanofiber composite membranes for electromagnetic interference shielding. ACS Appl. Nano Mater. 2021 , 4 , 729−738..

Zhang, S.; Huang, X.; Xiao, W.; Zhang, L.; Yao, H.; Wang, L.; Luo, J.; Gao, J. Polyvinylpyrrolidone assisted preparation of highly conductive, antioxidation, and durable nanofiber composite with an extremely high electromagnetic interference shielding effectiveness. ACS Appl. Mater. Interfaces 2021 , 13 , 21865−21875..

Zhang, N.; Zhao, R.; He, D.; Ma, Y.; Qiu, J.; Jin, C.; Wang, C. Lightweight and flexible Ni-Co alloy nanoparticle-coated electrospun polymer nanofiber hybrid membranes for high-performance electromagnetic interference shielding. J. Alloy. Compd. 2019 , 784 , 244−255..

Lee, S.; Park, J.; Kim, M. C.; Kim, M.; Park, P.; Yoon, I. J.; Nah, J. Polyvinylidene fluoride core-shell nanofiber membranes with highly conductive shells for electromagnetic interference shielding. ACS Appl. Mater. Interfaces 2021 , 13 , 25428−25437..

Guo, Y.; Qiu, H.; Ruan, K.; Wang, S.; Zhang, Y.; Gu, J. Flexible and insulating silicone rubber composites with sandwich structure for thermal management and electromagnetic interference shielding. Compos. Sci. Technol. 2022 , 219 , 109253..

Deng, H.; Skipa, T.; Bilotti, E.; Zhang, R.; Lellinger, D.; Mezzo, L.; Fu, Q.; Alig, I.; Peijs, T. Preparation of high-performance conductive polymer fibers through morphological control of networks formed by nanofillers. Adv. Funct. Mater. 2010 , 20 , 1424−1432..

Lv, Z.; Kong, L.; Sun, P.; Lin, Y.; Wang, Y.; Xiao, C.; Liu, X.; Zhang, X.; Zheng, K.; Tian, X. Dual-functional eco-friendly liquid metal/boron nitride/silk fibroin composite film with outstanding thermal conductivity and electromagnetic shielding efficiency. Compos. Commun. 2023 , 39 , 101565..

Jia, L.; Ding, X.; Sun, J.; Zhang, X.; Tian, X. A controllable gradient structure of hydrophobic composite fabric constructed by silver nanowires and polyvinylidene fluoride microspheres for electromagnetic interference shielding with low reflection. Compos. Part A: Appl. S 2022 , 156 , 106884..

Xiao, W.; Zhang, L.; Zhang, S.; Yan, J .; Zhang, G.; Gao, J. Electrically conductive and magnetic nanofiber composites with an asymmetric structure for efficient electromagnetic interference shielding. Colloid. Surf. A 2023 , 675 , 132063..

Zhang, X.; Tang, J.; Zhong, Y.; Feng, Y.; Wei, X.; Li, M.; Wang, J. Asymmetric layered structural design with metal microtube conductive network for absorption-dominated electromagnetic interference shielding. Colloid. Surf. A 2022 , 643 , 128781..

Chen, T.; Cai, J.; Cheng, X.; Cui, S.; Zhang, D.; Gong, D. Bio-inspired flexible versatile textiles for excellent absorption-dominated electromagnetic interference shielding, thermal management, and strain sensing. Chem. Eng. J. 2023 , 477 , 147116..

Xue, B.; Li, Y.; Cheng, Z.; Yang, S.; Xie, L.; Qin, S.; Zheng, Q. Directional electromagnetic interference shielding based on step-wise asymmetric conductive networks. Nanomicro Lett. 2021 , 14 , 16..

Zhang, J.; Zhu, D.; Zhang, S.; Cheng, H.; Chen, S.; Tang, R.; Hang, Z. H.; Zhang, T.; Zhang, X.; Yang, Z. Asymmetric electromagnetic shielding performance based on spatially controlled deposition ofnickel nanoparticles on carbon nanotube sponge. Carbon 2022 , 194 , 290−296..

Yang, J.; Liao, X.; Wang, G.; Chen, J.; Guo, F.; Tang, W.; Wang, W.; Yan, Z.; Li, G. Gradient structure design of lightweight and flexible silicone rubber nanocomposite foam for efficient electromagnetic interference shielding. Chem. Eng. J. 2020 , 390 , 124589..

Yang, J.; Liao, X.; Wang, G.; Chen, J.; Song, P.; Tang, W.; Guo, F.; Liu, F.; Li, G. Heterogeneous silicon rubber composite foam with gradient porous structure for highly absorbed ultra-efficient electromagnetic interference shielding. Compos. Sci. Technol. 2021 , 206 , 108663..

Lei, Z.; Tian, D.; Liu, X.; Wei, J.; Rajavel, K.; Zhao, T.; Hu, Y.; Zhu, P.; Sun, R.; Wong, C. P. Electrically conductive gradient structure design of thermoplastic polyurethane composite foams for efficient electromagnetic interference shielding and ultra-low microwave reflectivity. Chem. Eng. J. 2021 , 424 , 130365..

Duan, H.; Zhu, H.; Gao, J.; Yan, D. X.; Dai, K.; Yang, Y.; Zhao, G.; Liu, Y.; Li, Z. M. Asymmetric conductive polymer composite foam for absorption dominated ultra-efficient electromagnetic interference shielding with extremely low reflection characteristics. J. Mater. Chem. A 2020 , 8 , 9146−9159..

Gao, Q.; Zhang, G.; Zhang, Y.; Fan, X.; Wang, Z.; Zhang, S.; Xiao, R.; Huang, F.; Shi, X.; Qin, J. Absorption dominated high-performance electromagnetic interference shielding epoxy/functionalized reduced graphene oxide/Ni-chains microcellular foam with asymmetric conductive structure. Compos. Sci. Technol. 2022 , 223 , 109419..

Li, M.; Feng, Y.; Wang, J. Asymmetric conductive structure design for stabilized composites with absorption dominated ultra-efficient electromagnetic interference shielding performance. Compos. Sci. Technol. 2023 , 236 , 110006..

Liu, G.; Yu, R.; Liu, D.; Xia, Y.; Pei, X.; Wang, W.; Min, C.; Liu, S.; Shao, R.; Xu, Z. 3D-printed TiO 2 -Ti 3 C 2 T x heterojunction/rGO/PDMS composites with gradient pore size for electromagnetic interference shielding and thermal management. Compos. Part A: Appl. S . 2022 , 160 , 107058..

Zuo, T.; Xie, C.; Wang, W.; Yu, D. Ti 3 C 2 T x MXene-ferroferric oxide/carbon nanotubes/waterborne polyurethane-based asymmetric composite aerogels for absorption-dominated electromagnetic interference shielding. ACS Appl. Nano Mater. 2023 , 6 , 4716−47 25..

Pei, X.; Liu, G.; Shi, H.; Yu, R.; Wang, S.; Liu, S.; Min, C.; Song, J.; Shao, R.; Xu, Z. Directional electromagnetic interference shielding of asymmetric structure based on dual-needle 3D printing. Compos. Sci. Technol. 2023 , 233 , 109909..

Yao, J.; Zhou, J.; Yang, F.; Peng, G.; Liu, Y.; Yao, Z.; Wu, F.; Zeng, H. Multi-functional and multi-scenario applications for MXene aerogels with synergistically enhanced asymmetric modules. Nano Res. 2024 , 17 , 3359−3368..

Zuo, T.; Wang, W.; Yu, D. MXene/Ag@ZnO/WPU/Melamine gradient composite foams prepared by a unidirectional evaporation approach for absorption-dominated electromagnetic interference shielding. J. Alloy. Compd. 2023 , 966 , 171644..

Zhang, Y. P.; Zhou, C. G.; Sun, W. J.; Wang, T.; Jia, L. C.; Yan, D. X.; Li, Z. M. Injection molding of segregated carbon nanotube/polypropylene composite with enhanced electromagnetic interference shielding and mechanical performance. Compos. Sci. Technol. 2020 , 197 , 108253..

Jia, L. C.; Jia, X. X.; Sun, W. J.; Zhan g, Y. P.; Xu, L.; Yan, D. X.; Su, H. J.; Li, Z. M. Stretchable liquid metal-based conductive textile for electromagnetic interference shielding. ACS Appl. Mater. Interfaces 2020 , 12 , 53230−53238..

Li, Y.; Tian, X.; Gao, S. P.; Jing, L.; Li, K.; Yang, H.; Fu, F.; Lee, J. Y.; Guo, Y. X.; Ho, J. S.; Chen, P. Y. Reversible crumpling of 2D titanium carbide (MXene) nanocoatings for stretchable electromagnetic shielding and wearable wireless communication. Adv. Funct. Mater. 2020 , 30 , 1907451..

Zhan, Y.; Wang, J.; Zhang, K.; Li, Y.; Meng, Y.; Yan, N.; Wei, W.; Peng, F.; Xia, H. Fabrication of a flexible electromagnetic interference shielding Fe 3 O 4 @reduced graphene oxide/natural rubber composite with segregated network. Chem. Eng. J. 2018 , 344 , 184−193..

Yu, W. C.; Wang, T.; Liu, Y. H.; Wang, Z. G.; Xu, L.; Tang, J. H.; Dai, K.; Duan, H. J.; Xu, J. Z.; Li, Z. M. Superior and highly absorbed electromagnetic interference shielding performance achieved by designing the reflection-absorption-integrated shielding compartment with conductive wall and lossy core. Chem. Eng. J. 2020 , 393 , 124644..

Sun, B.; Sun, S.; He, P.; Mi, H. Y.; Dong, B.; Liu, C.; Shen, C. As ymmetric layered structural design with segregated conductive network for absorption-dominated high-performance electromagnetic interference shielding. Chem. Eng. J. 2021 , 416 , 129083..

Liu, F.; Wei, Z.; Hu, X.; Cai, Y.; Chen, Z.; Yang, C.; Zhan, Y.; Xia, H. Asymmetric segregated network design of ultralight and thermal insulating polymer composite foams for green electromagnetic interference shielding. Compos. Commun. 2023 , 38 , 101492..

Wang, Z.; Wang, S.; Zhang, K.; Shen, Z.; Yu, E.; Zheng, S. Y.; Liu, S.; Yang, J. Heterostructured composite foam with highly efficient absorption-dominant EMI shielding capability and mechanical robustness. Compos. Commun. 2023 , 40 , 101603..

Wu, B.; Liu, R.; Yang, Y.; Zhu, H.; Yu, Y.; Huang, J.; Li, Y. Asymmetrically structured polyvinylidene fluoride composite for directional high absorbed electromagnetic interference shielding. J. Appl. Polym. Sci. 2023 , 140 , 53340..

Liang, C.; Gu, Z.; Zhang, Y.; Ma, Z.; Qiu, H.; Gu, J. Structural design strategies of polymer matrix composites for electromagnetic interference shielding: a review. Nano-Micro Lett. 2021 , 13 , 181..

Ma, T. B.; Ma, H.; Ruan, K. P.; Shi, X. T.; Qiu, H.; Gao, S. Y.; Gu, J. W. Thermally conductive poly(lactic acid) composites with superior electromagnetic shielding performances via 3D printing technology. Chinese J. Polym. Sci. 2022 , 40 , 248−255..

Wang, Y. Y.; Zhou, Z. H.; Zhou, C. G.; Sun, W. J.; Gao, J. F.; Dai, K.; Yan, D. X.; Li, Z. M. Lightweight and robust carbon nanotube/polyimide foam for efficient and heat-resistant electromagnetic interference shielding and microwave absorption. ACS Appl. Mater. Inter. 2020 , 12 , 8704−8712..

Yang, J.; Wang, H.; Zhang, Y.; Zhang, H.; Gu, J. Layered structural PBAT composite foams for efficient electromagnetic interference shielding. Nano-Micro Lett. 2023 , 16 , 31..

Wang, L.; Ma, Z.; Zhang, Y.; Chen, L.; Cao, D.; Gu, J. Polymer-based EMI shielding composites with 3D conductive networks: a mini-review. SusMat 2021 , 1 , 413−431..

Wang, T.; Kong, W. W.; Yu, W. C.; Gao, J. F.; Dai, K.; Yan, D. X.; Li, Z. M. A healable and mechanically enhanced composite with segregated conductive network structure for high-efficient electromagnetic interference shielding. Nano-Micro Lett. 2021 , 13 , 162..

Yang, J.; Chen, Y.; Yan, X.; Liao, X.; Wang, H.; Liu, C.; Wu, H.; Zhou, Y.; Gao, H.; Xia, Y.; Zhang, H.; Li, X.; Wang, T. Construction of in-situ grid conductor skeleton and magnet core in biodegradable poly(butyleneadipate- co -terephthalate) for efficient electromagnetic interference shielding and low reflection. Compos. Sci. Technol. 2023 , 240 , 110093..

Gong, K.; Peng, Y.; Liu, A.; Qi, S.; Qiu, H. Ultrathin carbon layer coated MXene/PBO nanofiber films for excellent electromagnetic interference shielding and thermal stability. Compos. Part A: Appl. S 2024 , 176 , 107857..

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