Highly Conductive Ag/pCF/MVQ Composite Rubber for Efficient Electromagnetic Interference Shielding

Yang Chen; Xiao-Ming Shao; Liang He; Yi-Nuo Xu; Qi-Yuan Yao; Ding Feng; Wen-Cai Wang

doi:10.1007/s10118-024-3108-6

Your Location：

Home >

Browse articles >

Highly Conductive Ag/pCF/MVQ Composite Rubber for Efficient Electromagnetic Interference Shielding

RESEARCH ARTICLE | Updated：2024-05-11

- Highly Conductive Ag/pCF/MVQ Composite Rubber for Efficient Electromagnetic Interference Shielding
- Chinese Journal of Polymer Science Vol. 42, Issue 6, Pages: 864-873(2024)
- Affiliations：
  
  a.State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China
  b.Key Laboratory of Beijing City for Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing 100029, China
  c.Sino-german School of Engineering, Qingdao University of Science and Technology, Qingdao 266400, China
- Author bio：
  
  wangw@buct.edu.cn
- Funds：
- DOI：10.1007/s10118-024-3108-6
  CLC：
- Published：1 June 2024，
  
  Published Online：3 April 2024，
  
  Received：3 January 2024，
  
  Revised：8 February 2024，
  
  Accepted：18 February 2024
Scan for full text
Chen, Y.; Shao, X. M.; He, L.; Xu, Y. N.; Yao, Q. Y.; Feng, D.; Wang, W. C. Highly conductive Ag/pCF/MVQ composite rubber for efficient electromagnetic interference shielding. Chinese J. Polym. Sci. 2024, 42, 864–873

Yang Chen, Xiao-Ming Shao, Liang He, et al. Highly Conductive Ag/pCF/MVQ Composite Rubber for Efficient Electromagnetic Interference Shielding. [J]. Chinese Journal of Polymer Science 42(6):864-873(2024)
Chen, Y.; Shao, X. M.; He, L.; Xu, Y. N.; Yao, Q. Y.; Feng, D.; Wang, W. C. Highly conductive Ag/pCF/MVQ composite rubber for efficient electromagnetic interference shielding. Chinese J. Polym. Sci. 2024, 42, 864–873 DOI： 10.1007/s10118-024-3108-6.

Yang Chen, Xiao-Ming Shao, Liang He, et al. Highly Conductive Ag/pCF/MVQ Composite Rubber for Efficient Electromagnetic Interference Shielding. [J]. Chinese Journal of Polymer Science 42(6):864-873(2024) DOI： 10.1007/s10118-024-3108-6.

摘要

In this study

highly conductive composite rubber was prepared by dopamine-assisted electroless silver plating plus mechanical mixing. Thanks to the advantages of low density

high aspect ratio and high conductivity of the silver-plated carbon fibers

the EMI shielding effectiveness of the composite rubber filled with 45 phr of silver-plated carbon fibers reached 111 dB.

Abstract

In this study

flexible and highly conductive composite rubber at low filler content was successfully prepared through polydopamine-assisted electroless silver plating plus mechanical mixing. Firstly

carbon fibers (CF) were activated by polydopamine (PDA) to improve the surface activity by self-polymerization reaction. Next

because of the metal chelating ability of PDA

silver layer was firmly deposited on the surface of CF through a facile electroless silver plating method. Finally

flexible silver-plated carbon fibers (Ag/pCF) silicone rubber composites prepared by mechanical mixing. By using X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD)

the chemical composition and crystal structure of Ag/pCF were examined

and scanning electron microscopy (SEM) was used to assess the surface morphology of the Ag/pCF. The results showed that a uniform and dense silver layer was formed on the surface of the CF

and the conductivity of the Ag/pCF could reach 7885 S/cm. It was noteworthy that the composite rubber filled with only 45 phr Ag/pCF had a high electromagnetic interference shielding effectiveness (100 dB) due to the low density and high aspect ratio of Ag/pCF. The composite rubber has excellent potential for application in the field of electromagnetic interference shielding.

关键词

Keywords

Carbon fibersPolydopamineElectroless platingSilverElectromagnetic interference shielding

references

Kong, D.; Li, J.; Guo, A.; Xiao, X. High temperature electromagnetic shielding shape memory polymer composite.Chem. Eng. J.2021,408, 127365..

Guo, H.; Chen, Y.; Li, Y.; Zhou, W.; Xu, W.; Pang, L.; Fan, X.; Jiang, S. Electrospun fibrous materials and their applications for electromagnetic interference shielding: a review.Compos. Part A Appl. Sci. Manuf.2021,143, 106309..

Liu, J.; Yu, M. Y.; Yu, Z. Z.; Nicolosi, V. Design and advanced manufacturing of electromagnetic interference shielding materials.Mater. Today Phys.2023,66, 245−272..

Cheng, J.; Li, C.; Xiong, Y.; Zhang, H.; Raza, H.; Ullah, S.; Wu, J.; Zheng, G.; Cao, Q.; Zhang, D.; Zheng, Q.; Che, R. Recent advances in design strategies and multifunctionality of flexible electromagnetic interference shielding materials.Nanomicro. Lett.2022,14, 80..

Liang, C.; Gu, Z.; Zhang, Y.; Ma, Z.; Qiu, H.; Gu, J. Structural design strategies of polymer matrix composites for electromagnetic interference shielding: a review.Nanomicro. Lett.2021,13, 181..

Lee, S. H.; Yu, S.; Shahzad, F.; Hong, J.; Noh, S. J.; Kim, W. N.; Hong, S. M.; Koo, C. M. Low percolation 3D Cu and Ag shell network composites for EMI shielding and thermal conduction.Compos. Sci. Technol.2019,182, 107778..

Xie, Q.; Yan, Z.; Qin, F.; Wang, L.; Mei, L.; Zhang, Y.; Wang, Z.; Zhao, G.; Jiang, R. Metal carbide/Ni hybrids for high-performance electromagnetic absorption and absorption-based electromagnetic interference shielding.Inorg. Chem. Front.2020,7, 4832−4844..

Chen, X.; Liu, L.; Pan, F.; Mao, J.; Xu, X.; Yan, T. Microstructure, electromagnetic shielding effectiveness and mechanical properties of Mg-Zn-Cu-Zr alloys.Mater. Sci. Eng. B-Adv.2015,197, 67−74..

Wang, J. H.; Wu, R. Z.; Feng, J.; Zhang, J. H.; Hou, L. G.; Liu, M. D. Recent advances of electromagnetic interference shielding Mg matrix materials and their processings: a review.T. Nonferr. Metal. Soc.2022,32, 1385−1404..

Liang, C.; Liu, Y.; Ruan, Y.; Qiu, H.; Song, P.; Kong, J.; Zhang, H.; Gu, J. Multifunctional sponges with flexible motion sensing and outstanding thermal insulation for superior electromagnetic interference shielding.Compos. Part A Appl. Sci. Manuf.2020,139, 106143..

Wang, M.; Tang, X. H.; Cai, J. H.; Wu, H.; Shen, J. B.; Guo, S. Y. Fabrication, mechanisms and perspectives of conductive polymer composites with multiple interfaces for electromagnetic interference shielding: a review.Carbon2021,177, 377−402..

Yu, W. C.; Zhang, G. Q.; Liu, Y. H.; Xu, L.; Yan, D. X.; Huang, H. D.; Tang, J. H.; Xu, J. Z.; Li, Z. M. Selective electromagnetic interference shielding performance and superior mechanical strength of conductive polymer composites with oriented segregated conductive networks.Chem. Eng. J.2019,373, 556−564..

Zhang, J.; Wang, Q.; Xue, X.; Li, M.; Sun, X.; Zhao, J.; Zhang, W.; Lu, C. Waste flame-retardant polyurethane foam/ground tire rubber/carbon nanotubes composites with hierarchical segregated structures for high efficiency electromagnetic interference shielding.Compos. Part A Appl. Sci. Manuf.2023,169, 107530..

Feng, D.; Xu, D.; Wang, Q.; Liu, P. Highly stretchable electromagnetic interference (EMI) shielding segregated polyurethane/carbon nanotube composites fabricated by microwave selective sintering.J. Mater. Chem. C2019,7, 7938−7946..

Tudose, I. V.; Mouratis, K.; Ionescu, O. N.; Romanitan, C.; Pachiu, C.; Popescu, M.; Khomenko, V.; Butenko, O.; Chernysh, O.; Kenanakis, G.; Barsukov, V. Z.; Suchea, M. P.; Koudoumas, E. Novel water-based paints for composite materials used in electromagnetic shielding applications.Nanomaterials2022,12, 487..

He, L.; Shao, X.; Tian, M.; Wang, W. Superhydrophobic and durable silver-coated fabrics for efficient electromagnetic interference shielding.ACS Appl. Polym. Mater.2023,1, 851−860..

Cheng, W.; Zhang, Y.; Tao, Y.; Lu, J.; Liu, J.; Wang, B.; Song, L.; Jie, G.; Hu, Y. Durable electromagnetic interference (EMI) shielding ramie fabric with excellent flame retardancy and Self-healing performance.J. Colloid Interface Sci.2021,602, 810−821..

Tugirumubano, A.; Vijay, S. J.; Go, S. H.; Kwac, L. K.; Kim, H. G. Characterization of electromagnetic interference shielding composed of carbon fibers reinforced plastics and metal wire mesh based composites.J. Mater. Res. Technol.2019,8, 167−172..

Xu, H.; Li, Y.; Han, X.; Cai, H.; Gao, F. Carbon black enhanced wood-plastic composites for high-performance electromagnetic interference shielding.Mater. Lett.2021,285, 129077..

Song, J.; Fan, Y.; Shi, A. Bidirectionally oriented carbon fiber/silicone rubber composites with a high thermal conductivity and enhanced electromagnetic interference shielding effectiveness.Materials2023,16, 6736..

Kruzelak, J.; Kvasnicakova, A.; Hlozekova, K.; Dosoudil, R.; Goralik, M.; Hudec, I. Electromagnetic interference shielding and physical-mechanical characteristics of rubber composites filled with manganese-zinc ferrite and carbon black.Polymers2021,13, 616..

Kruzelak, J.; Kvasnicakova, A.; Hlozekova, K.; Plavec, R.; Dosoudil, R.; Goralik, M.; Vilcakova, J.; Hudec, I. Mechanical, thermal, electrical characteristics and EMI absorption shielding effectiveness of rubber composites based on ferrite and carbon fillers.Polymers2021,13, 2937..

Fan, Z.; Guo, R.; Yang, Z.; Yang, Y.; Liu, X. The effect of the Co-blending process on the sensing characteristics of conductive chloroprene rubber/natural rubber composites.Polymers2022,14, 3326..

Zhang, H.; Zhang, G.; Gao, Q.; Zong, M.; Wang, M.; Qin, J. Electrically electromagnetic interference shielding microcellular composite foams with 3D hierarchical graphene-carbon nanotube hybrids.Compos. Part A Appl. Sci. Manuf.2020,130, 105773..

Zhang, C.; Lv, Q.; Liu, Y.; Wang, C.; Wang, Q.; Wei, H.; Liu, L.; Li, J.; Dong, H. Rational design and fabrication of lightweight porous polyimide composites containing polyaniline modified graphene oxide and multiwalled carbon nanotube hybrid fillers for heat-resistant electromagnetic interference shielding.Polymer2021,224, 123742..

Yang, H.; Yao, X.; Zheng, Z.; Gong, L.; Yuan, L.; Yuan, Y.; Liu, Y. Highly sensitive and stretchable graphene-silicone rubber composites for strain sensing.Compos. Sci. Technol.2018,167, 371−378..

Dou, Y.; Gu, H.; Sun, S.; Yao, W.; Guan, D. Synthesis of a grape-like conductive carbon black/Ag hybrid as the conductive filler for soft silicone rubber.RSC Adv.2021,12, 1184−1193..

Pazhooh, H. N.; Bagheri, R.; Adloo, A. Fabrication of semi-conductive natural rubber nanocomposites with low copper nanoparticle contents.Polymer2017,108, 135−145..

Luo, J. Q.; Zhao, S.; Zhang, H. B.; Deng, Z.; Li, L.; Yu, Z. Z. Flexible, stretchable and electrically conductive MXene/natural rubber nanocomposite films for efficient electromagnetic interference shielding.Compos. Sci. Technol.2019,182, 107754..

Ravindren, R.; Mondal, S.; Nath, K.; Das, N. C. Prediction of electrical conductivity, double percolation limit and electromagnetic interference shielding effectiveness of copper nanowirefilled flexible polymer blend nanocomposites.Compos. B Eng.2019,164, 559−569..

Hao, M.; Li, L.; Shao, X.; Tian, M.; Zou, H.; Zhang, L.; Wang, W. Fabrication of highly conductive silver-coated aluminum microspheres based on poly(catechol/polyamine) surface modification.Polymers2022,14, 2727..

Shao, X.; Xu, W.; Yu, M.; He, L.; Hao, M.; Tian, M.; Wang, W. Improved salt spray resistance of silver-plated SiO2viaself-assembled mercapto inhibitors.ACS Appl. Polym. Mater.2023,1, 1013−1023..

Yang, Y. H.; Pan, Y. X.; Feng, Z. H.; Shi, S. Evaluation of aerospace carbon fibers.New Carbon Mater.2014,29, 161−168..

Wei, J.; Liao, M.; Ma, A.; Chen, Y.; Duan, Z.; Hou, X.; Li, M.; Jiang, N.; Yu, J. Enhanced thermal conductivity of polydimethylsiloxane composites with carbon fiber.Compos. Commun.2020,17, 141−146..

Haghgoo, M.; Ansari, R.; Hassanzadeh-Aghdam, M. K.; Nankali, M. Analytical formulation for electrical conductivity and percolation threshold of epoxy multiscale nanocomposites reinforced with chopped carbon fibers and wavy carbon nanotubes considering tunneling resistivity.Compos. Part A Appl. Sci. Manuf.2019,126, 105616..

Qian, K.; Zhou, J.; Miao, M.; Wu, H.; Thaiboonrod, S.; Fang, J.; Feng, X. Highly ordered thermoplastic polyurethane/aramid nanofiber conductive foams modulated by kevlar polyanion for piezoresistive sensing and electromagnetic interference shielding.Nanomicro. Lett.2023,15, 88..

Qian, K.; Xu, Y.; Miao, M.; Deng, D.; Luo, L.; Feng, X. Engineering metalized surface of single hairviaelectroless Cu-plating strategy for self-supported nonenzymatic glucose sensor.J. Mater. Sci.2023,58, 15074−15085..

Ding, Y.; Weng, L.-T.; Yang, M.; Yang, Z.; Lu, X.; Huang, N.; Leng, Y. Insights into the aggregation/deposition and structure of a polydopamine film.Langmuir2014,30, 12258−12269..

Zhang, C.; Xiang, L.; Zhang, J.; Liu, C.; Wang, Z.; Zeng, H.; Xu, Z. K. Revisiting the adhesion mechanism of mussel-inspired chemistry.Chem. Sci.2022,13, 1698−1705..

Zhang, Z.; Si, T.; Liu, J.; Zhou, G.In-situgrown silver nanoparticles on nonwoven fabrics based on mussel-inspired polydopamine for highly sensitive sers carbaryl pesticides detection.Nanomaterials2019,9, 384..

Fu, Y.; Li, G.; Tian, M.; Wang, X.; Zhang, L.; Wang, W. Preparation of silver nanoparticle immobilized fibrillar silicate by poly(dopamine) surface functionalization.J. Appl. Polym. Sci.2014,131, 39859..

Wang, W.; Jiang, Y.; Wen, S.; Liu, L.; Zhang, L. Preparation and characterization of polystyrene/Ag core-shell microspheres—a bio-inspired poly(dopamine) approach.J. Colloid Interface Sci.2012,368, 241−249..

Jia, X.; Li, Y.; Shen, B.; Zheng, W. Evaluation, fabrication and dynamic performance regulation of green EMI-shielding materials with low reflectivity: a review.Compos. B Eng.2022,233, 109652..

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Recent Advances in Asymmetric Structural Composites for Excellent Electromagnetic Interference Shielding: A Review

Recent Advances in Bio-Inspired Versatile Polydopamine Platforms for “Smart” Cancer Photothermal Therapy

Multifunctional Waterborne Polyurethane Nanocomposite Films with Remarkable Electromagnetic Interference Shielding, Electrothermal and Solarthermal Performances

Related Author

Qiang Zheng

Ying Zhou

Bai Xue

Lan Xie

Chang-Mei Wu

Rui-Li Wang

Zhi-Yuan Ma

Dan-Ya Li

Related Institution

Department of Polymer Science and Engineering, Zhejiang University

National Engineering Research Center for Compounding and Modification of Polymer Materials; National and Local Joint Engineering Research Center for Functional Polymer Membrane Materials and Membrane Processes

State Key Laboratory of Public Big Data, Guizhou University

Department of Polymer Materials and Engineering, College of Materials and Metallurgy, Guizhou University

Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical Engineering, Shihezi University

⁰