Significantly Enhanced Energy Storage Performances of PEI-based Composites Utilizing Surface Functionalized ZrO<sub>2</sub> Nanoparticles for High-Temperature Application

Qing-Qing Liu; Qiu-Hao Lin; Xiao-Dong Qi; Nan Zhang; Ting Huang; Jing-Hui Yang; Yong Wang

doi:10.1007/s10118-024-3068-x

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Significantly Enhanced Energy Storage Performances of PEI-based Composites Utilizing Surface Functionalized ZrO₂ Nanoparticles for High-Temperature Application

RESEARCH ARTICLE | Updated：2024-02-20

- Significantly Enhanced Energy Storage Performances of PEI-based Composites Utilizing Surface Functionalized ZrO₂ Nanoparticles for High-Temperature Application
- Chinese Journal of Polymer Science Vol. 42, Issue 3, Pages: 322-332(2024)
- Affiliations：
  
  a.School of Chemistry, Southwest Jiaotong University, Chengdu 610031, China
  b.Key Laboratory of Advanced Technologies of Materials, Ministry of Education of China, Southwest Jiaotong University, Chengdu 610031, China
- Author bio：
  
  yangjinghui_84@163.com (J.H.Y.)
  yongwang1976@swjtu.edu.cn (Y.W.)
- Funds：
- DOI：10.1007/s10118-024-3068-x
  CLC：
- Received：01 September 2023，
  
  Revised：2023-11-2，
  
  Accepted：09 November 2023，
  
  Online First：07 December 2023，
  
  Published：01 March 2024
- Accepted：
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Liu, Q. Q.; Lin, Q. H.; Qi, X. D.; Zhang, N.; Huang, T.; Yang, J. H.; Wang, Y. Significantly enhanced energy storage performances of PEI-based composites utilizing surface functionalized ZrO₂ nanoparticles for high-temperature application. Chinese J. Polym. Sci. 2024, 42, 322–332 DOI: 10.1007/s10118-024-3068-x.

Qing-Qing Liu, Qiu-Hao Lin, Xiao-Dong Qi, et al. Significantly Enhanced Energy Storage Performances of PEI-based Composites Utilizing Surface Functionalized ZrO₂ Nanoparticles for High-Temperature Application[J]. Chinese Journal of Polymer Science, 2024, 42(3): 322-332. DOI: 10.1007/s10118-024-3068-x.
Liu, Q. Q.; Lin, Q. H.; Qi, X. D.; Zhang, N.; Huang, T.; Yang, J. H.; Wang, Y. Significantly enhanced energy storage performances of PEI-based composites utilizing surface functionalized ZrO₂ nanoparticles for high-temperature application. Chinese J. Polym. Sci. 2024, 42, 322–332 DOI: 10.1007/s10118-024-3068-x. DOI：

Qing-Qing Liu, Qiu-Hao Lin, Xiao-Dong Qi, et al. Significantly Enhanced Energy Storage Performances of PEI-based Composites Utilizing Surface Functionalized ZrO₂ Nanoparticles for High-Temperature Application[J]. Chinese Journal of Polymer Science, 2024, 42(3): 322-332. DOI: 10.1007/s10118-024-3068-x. DOI：

摘要

The ZrO

particles were decorated with amino group utilizing AMEO

which were applied as dielectric filler to enhance the dielectric property of PEI. The composites containing ZrO

-AMEO exhibit high breakdown strength and improved dielectric constant simultaneously

showing excellent energy storage performance at elevated temperatures.

Abstract

Polymer dielectrics with a high energy density and an available energy storage capacity have been playing an important role in advanced electronics and power systems. Nevertheless

the use of polymer dielectrics in harsh environments is limited by their low energy density at high temperatures. Herein

zirconium dioxide (ZrO

) nanoparticles were decorated with amino group utilizing 4

4-methylenebis (phenyl isocyanate) (AMEO) and successfully incorporated into polyetherimide (PEI) matrix. The dielectric properties

breakdown strength

and energy storage performances of PEI/ZrO

-AMEO nanocomposites were investigated from 25 °C to 150 °C. It is found that the combination of moderate bandgap ZrO

with modest dielectric constant and polar groups at interface with deep trap can offer an available strategy to simultaneously increase the dielectric constant and breakdown strength of polymer dielectrics. As a result

the composites containing ZrO

-AMEO exhibit excellent energy storage performance at elevated temperatures. Specially

the PEI-based composites with 3 vol% ZrO

-AMEO display a maximum discharged energy density (

) of 3.1 J/cm

at 150 °C

presenting 90% higher than that of neat PEI. This study may help to better develop the polymer-based dielectric composite applied at elevated temperatures.

关键词

Keywords

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⁰

Significantly Enhanced Energy Storage Performances of PEI-based Composites Utilizing Surface Functionalized ZrO2 Nanoparticles for High-Temperature Application

DOI：10.1007/s10118-024-3068-x

摘要

Abstract

关键词

Keywords

references

Significantly Enhanced Energy Storage Performances of PEI-based Composites Utilizing Surface Functionalized ZrO₂ Nanoparticles for High-Temperature Application