MOF-derived Porous Carbon Nanofiber Assembly as High Efficiency ORR Electrocatalysts for Zinc-air Batteries

Jin-Liang Ma; Long-Long Liu; Ren-Hai Zhao; Ding Yuan; Xin Ning

doi:10.1007/s10118-023-3006-3

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MOF-derived Porous Carbon Nanofiber Assembly as High Efficiency ORR Electrocatalysts for Zinc-air Batteries

RESEARCH ARTICLE | Updated：2023-11-27

- MOF-derived Porous Carbon Nanofiber Assembly as High Efficiency ORR Electrocatalysts for Zinc-air Batteries
- Chinese Journal of Polymer Science Vol. 41, Issue 12, Pages: 1889-1901(2023)
- Affiliations：
  
  Industrial Research Institute of Nonwovens & Technical Textiles, Shandong Center for Engineered Nonwovens, College of Textiles & Clothing, Qingdao University, Qingdao 266071, China
- Author bio：
  
  yuanding@qdu.edu.cn (D.Y.)
  xning@qdu.edu.cn (X.N.)
- Funds：
- DOI：10.1007/s10118-023-3006-3
  CLC：
- Received：29 March 2023，
  
  Revised：2023-5-15，
  
  Accepted：26 May 2023，
  
  Online First：10 July 2023，
  
  Published：01 December 2023
- Accepted：
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Ma, J. L.; Liu, L. L.; Zhao, R. H.; Yuan, D.; Ning, X. MOF-derived porous carbon nanofiber assembly as high efficiency ORR electrocatalysts for zinc-air batteries. Chinese J. Polym. Sci. 2023, 41, 1889–1901

Jin-Liang Ma, Long-Long Liu, Ren-Hai Zhao, et al. MOF-derived Porous Carbon Nanofiber Assembly as High Efficiency ORR Electrocatalysts for Zinc-air Batteries[J]. Chinese Journal of Polymer Science, 2023, 41(12): 1889-1901.
Ma, J. L.; Liu, L. L.; Zhao, R. H.; Yuan, D.; Ning, X. MOF-derived porous carbon nanofiber assembly as high efficiency ORR electrocatalysts for zinc-air batteries. Chinese J. Polym. Sci. 2023, 41, 1889–1901 DOI： 10.1007/s10118-023-3006-3.

Jin-Liang Ma, Long-Long Liu, Ren-Hai Zhao, et al. MOF-derived Porous Carbon Nanofiber Assembly as High Efficiency ORR Electrocatalysts for Zinc-air Batteries[J]. Chinese Journal of Polymer Science, 2023, 41(12): 1889-1901. DOI： 10.1007/s10118-023-3006-3.

摘要

Carbon nanofiber materials with special core-shell structure were developed by using bimetallic MOF as precursor

electrospinning

electrodeposition and high temperature carbonization. High performance ORR catalyst containing Fe-N

C active sites

Co-N

C active sites and Co nanoparticles co-exists in hollow porous carbon fibers.

Abstract

Reasonable construction of high activity and low cost non-noble metal oxygen reduction reaction (ORR) catalyst is of great importance for the wide application of zinc-air batteries (ZABs). Using bimetallic MOF as a precursor combined with electrospinning

high-temperature carbonization and electrodeposition

we successfully developed a porous carbon nanofiber (Co@Fe-CNFs-1000) with bimetallic active center as an efficient catalyst for ORR. The successful construction of this special core-shell structure directly explores the synergy between different active centers. The results showed that the synthesized Co@Fe-CNFs-1000 catalyst exhibited ORR performance comparable to that of Pt/C in 0.1 mol/L KOH electrolyte

high half-wave potential (

1/2

=0.81 V) and limiting current density (

=5.4 mA·cm

−2

). In addition

homemade liquid ZABs with Co@Fe-CNFs-1000 as the air cathode showed excellent power density (155.8 mW·cm

−2

)

specific capacity (780.6 mAh·g

−1

) and long-term stability (over 100 h at 2 mA·cm

−2

)

surpassing even Pt/C-based batteries. In addition

the flexible solid-state ZABs assembled based on Co@Fe-CNFs-1000 demonstrates excellent flexibility and durability. This work provides a new idea for constructing ORR catalysts with high activity centers.

关键词

Keywords

references

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