Highly Sensitive Thermo-fluorochromic Polymeric Elastomers <italic style="font-style: italic">via</italic> Phenanthroline-mediated Dynamic Tb/Sm-Carboxylate Coordination

Bo Liu; Qiu-Li Tan; Ming-Hui Wei; Ru-Ning Cao; Geng-Sheng Weng

doi:10.1007/s10118-026-3811-6

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Highly Sensitive Thermo-fluorochromic Polymeric Elastomers via Phenanthroline-mediated Dynamic Tb/Sm-Carboxylate Coordination

RESEARCH ARTICLE | Updated：2026-09-29

- Highly Sensitive Thermo-fluorochromic Polymeric Elastomers via Phenanthroline-mediated Dynamic Tb/Sm-Carboxylate Coordination
- Chinese Journal of Polymer Science Vol. 44, Pages: 1-14(2026)
- Affiliations：
  
  School of Materials Science and Chemical Engineering, State Key Laboratory Base of Novel Functional Materials and Preparation Science, Key Laboratory of Impact and Safety Engineering, Ministry of Education, Ningbo University, Ningbo 315211, China
- Author bio：
  
  wenggengsheng@nbu.edu.cn
- Funds：
- DOI：10.1007/s10118-026-3811-6
  CLC：
- Received：18 May 2026，
  
  Accepted：09 July 2026，
  
  Online First：29 September 2026，
  
  Published：2026-09
- Accepted：
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Liu, B.; Tan, Q. L.; Wei, M. H.; Cao, R. N.; Weng, G. S. Highly sensitive thermo-fluorochromic polymeric elastomers via phenanthroline-mediated dynamic Tb/Sm-carboxylate coordination. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-026-3811-6

Bo Liu, Qiu-Li Tan, Ming-Hui Wei, et al. Highly Sensitive Thermo-fluorochromic Polymeric Elastomers via Phenanthroline-mediated Dynamic Tb/Sm-Carboxylate Coordination[J/OL]. Chinese Journal of Polymer Science, 2026, 441-14. DOI: 10.1007/s10118-026-3811-6.
Liu, B.; Tan, Q. L.; Wei, M. H.; Cao, R. N.; Weng, G. S. Highly sensitive thermo-fluorochromic polymeric elastomers via phenanthroline-mediated dynamic Tb/Sm-carboxylate coordination. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-026-3811-6 DOI：

Bo Liu, Qiu-Li Tan, Ming-Hui Wei, et al. Highly Sensitive Thermo-fluorochromic Polymeric Elastomers via Phenanthroline-mediated Dynamic Tb/Sm-Carboxylate Coordination[J/OL]. Chinese Journal of Polymer Science, 2026, 441-14. DOI: 10.1007/s10118-026-3811-6. DOI：

摘要

Abstract

A tough and self-healable Tb

-and Sm

-containing thermo-fluorochromic (TFC-Sm/Tb) elastomer with highly sensitive and tunable temperature-responsive emission was developed. The elastomer was dynamically cross-linked by Tb

and Sm

ions through coordination with the COOH groups of the carboxylated nitrile butadiene chains

with 1

10-phenanthroline acting as the ancillary ligand. Mechanical investigations reveal that Tb

cross-linking is more effective in enhancing toughness. The TFC-Sm/Tb elastomer also has high self-healing efficiency and provides effective adhesion to the metal surface. Fluorescence spectroscopic studies showed that Tb

mainly displays an intense spin-forbidden interconfigurational 4f

→4f

excitation transition

whereas Sm

excitation is dominated by a broad Phen-to-Sm

energy transfer band from 250 nm to 380 nm. By adjusting the excitation wavelength or Sm

/Tb

molar ratio

the emission color can be easily tuned from green to red. Notably

the Tb

emission is highly tem

perature-sensitive and undergoes pronounced thermal quenching upon heating

while the Sm

emission remains nearly invariant from 25 °C to 100 °C. This distinct contrast enabled highly sensitive thermo-fluorochromism

yielding a high relative thermal sensitivity of 8.6 (%)/K. As a proof of concept

our work paves the way for the fabrication of thermofluorochromic materials with potential applications in luminescent textiles

anti-counterfeiting

and temperature-sensing fluorochromic coatings.

关键词

Keywords

references

Wang, F.; Yao, K.; Chen, C.; Wang, K.; Bai, H.; Hao, X.-L.; Wang, Q.; Dong, X.; Liu, W. Lanthanide-coordinated multifunctional hydrogel for detecting human motion and encrypting information. Adv. Funct. Mater. 2025 , 35 , 2418373..

Chen, P.; Li, Q.; Grindy, S.; Holten-Andersen, N. White-light-emitting lanthanide metallogels with tunable luminescence and reversible stimuli-responsive properties. J. Am. Chem. Soc. 2015 , 137 , 11590−11593..

Zhu, Q.; Zhang, L.; Van Vliet, K.; Miserez, A.; Holten-Andersen, N. White light-emitting multistimuli-responsive hydrogels with lanthanides and carbon dots. ACS Appl. Mater. Interfaces 2018 , 10 , 10409−10418..

Beck, J. B.; Rowan, S. J. Multistimuli, multiresponsive metallo-supramolecular polymers. J. Am. Chem. Soc. 2003 , 125 , 13922−13923..

Kumpfer, J. R.; Rowan, S. J. Thermo-, photo-, and chemo-responsive shape-memory properties from photo-cross-linked metallo-supramolecular polymers. J. Am. Chem. Soc. 2011 , 133 , 12866−12874..

Surender, E. M.; Bradberry, S. J.; Bright, S. A.; McCoy, C. P.; Williams, D. C.; Gunnlaugsson, T. Luminescent lanthanide cyclen-based enzymatic assay capable of diagnosing the onset of catheter-associated urinary tract infections both in solution and within polymeric hydrogels. J. Am. Chem. Soc. 2017 , 139 , 381−388..

Shunmugam, R.; Tew, G. N. Unique emission from polymer based lanthanide alloys. J. Am. Chem. Soc. 2005 , 127 , 13567−13572..

Wang, R.; Zhang, Y.; Lu, W.; Wu, B.; Wei, S.; Wu, S.; Wang, W.; Chen, T. Bio-inspired structure-editing fluorescent hydrogel actuators for environment-interactive information encryption. Angew. Chem. Int. Ed. 2023 , 62 , e202300417..

Hasegawa, Y.; Shoji, S.; Kitagawa, Y. Luminescent Eu(III)-based coordination polymers for photonic materials. Chem. Lett. 2022 , 51 , 185−196..

Monteiro, B.; Leal, J. P.; Mendes, R. F.; Almeida Paz, F. A.; Linden, A.; Smetana, V.; Mudring, A. V.; Avó, J.; Pereira, C. C. L. Lanthanide-based complexes as efficient physiological temperature sensors. Mater. Chem. Phys. 2022 , 277 , 125424..

Gao, D.; Lv, J.; Lee, P. S. Natural polymer in soft electronics: opportunities, challenges, and future prospects. Adv. Mater. 2022 , 34 , 2105020..

Zhou, L.-Y.; Fu, J.; He, Y. A review of 3D printing technologies for soft polymer materials. Adv. Funct. Mater. 2020 , 30 , 2000187..

Li, P.; Zhang, Y.; Zheng, Z. Polymer-assisted metal deposition (PAMD) for flexible and wearable electronics: principle, materials, printing, and devices. Adv. Mater. 2019 , 31 , 1902987..

Wang, L.; Chen, D.; Jiang, K.; Shen, G. New insights and perspectives into biological materials for flexible electronics. Chem. Soc. Rev. 2017 , 46 , 6764−6815..

Tee, B. C. K.; Ouyang, J. Soft electronically functional polymeric composite materials for a flexible and stretchable digital future. Adv. Mater. 2018 , 30 , 1802560..

Tang, J.; Gou, K.; Wang, C.; Wei, M.; Tan, Q.; Weng, G. Self-powered and 3D printable soft sensor for human health monitoring, object recognition, and contactless hand gesture recognition. Adv. Funct. Mater. 2024 , 34 , 2411172..

Dai, C.; Chen, H.; Wang, L.; Liu, Y.; Yin, Q.; Jiang, J.; Zhou, Q.; Weng, G. A highly temperature- and pressure-sensitive soft sensor self-powered by a galvanic cell design. J. Mater. Chem. A 2022 , 10 , 4408−4417..

Chen, C.; Zheng, L.; Chen, L.; Liu, X. Recent progress and challenges of flexible supercapacitor-sensor integrated systems based on conductive polymers. J. Mater. Chem. C 2025 , 13 , 16320−16349..

Zhou, X.; Wang, L.; Wei, Z.; Weng, G.; He, J. An adaptable tough elastomer with moisture-triggered switchable mechanical and fluorescent properties. Adv. Funct. Mater. 2019 , 29 , 1903543..

Wei, Z.; Thanneeru, S.; Margaret Rodriguez, E.; Weng, G.; He, J. Adaptable Eu-containing polymeric films with dynamic control of mechanical properties in response to moisture. Soft Matter 2020 , 16 , 2276−2284..

Tan, Q. L.; Gou, K.; Tang, J. Z.; Wei, M. H.; Wang, C.; Nie, Y. J.; Weng, G. S. Highly stretchable and tunable thermo-fluorochromic polymer elastomer through Eu 3+ dynamic coordination cross-linking. Chinese J. Polym. Sci. 2024 , 42 , 1449−1458..

Wei, M. H.; Xu, Y. Y.; Tan, Q. L.; Liu, B.; Nie, Y. J.; Weng, G. S. A terbium coordination cross-linked tough metallo-elastomer showing fluorochromism in response to multistimuli. Chinese J. Polym. Sci. 2025 , 43 , 2349−2361..

Balkenende, D. W. R.; Coulibaly, S.; Balog, S.; Simon, Y. C.; Fiore, G. L.; Weder, C. Mechanochemistry with metallosupramolecular polymers. J. Am. Chem. Soc. 2014 , 136 , 10493−10498..

Kumpfer, J. R.; Jin, J.; Rowan, S. J. Stimuli-responsive europium-containing metallo-supramolecular polymers. J. Mater. Chem. 2010 , 20 , 145−151..

Hong, G.; Zhang, H.; Lin, Y.; Chen, Y.; Xu, Y.; Weng, W.; Xia, H. Mechanoresponsive healable metallosupramolecular polymers. Macromolecules 2013 , 46 , 8649−8656..

Zhang, Q.; Niu, S.; Wang, L.; Lopez, J.; Chen, S.; Cai, Y.; Du, R.; Liu, Y.; Lai, J. C.; Liu, L.; Li, C. H.; Yan, X.; Liu, C.; Tok, J. B. H.; Jia, X.; Bao, Z. An elastic autonomous self-healing capacitive sensor based on a dynamic dual crosslinked chemical system. Adv. Mater. 2018 , 30 , 1801435..

Li, Z.; Hou, Z.; Fan, H.; Li, H. Organic–inorganic hierarchical self-assembly into robust luminescent supramolecular hydrogel. Adv. Funct. Mater. 2017 , 27 , 1604379..

Wang, M. X.; Yang, C. H.; Liu, Z. Q.; Zhou, J.; Xu, F.; Suo, Z.; Yang, J. H.; Chen, Y. M. Tough photoluminescent hydrogels doped with lanthanide. Macromol. Rapid Commun. 2015 , 36 , 465−471..

Wei, S.; Lu, W.; Shi, H.; Wu, S.; Le, X.; Yin, G.; Liu, Q.; Chen, T. Light-writing and projecting multicolor fluorescent hydrogels for on-demand information display. Adv. Mater. 2023 , 35 , 2300615..

Tian, B.; Chen, B.; Tian, Y.; Li, X.; Zhang, J.; Sun, J.; Zhong, H.; Cheng, L.; Fu, S.; Zhong, H.; Wang, Y.; Zhang, X.; Xia, H.; Hua, R. Excitation pathway and temperature dependent luminescence in color tunable Ba 5 Gd 8 Zn 4 O 21 :Eu 3+ phosphors. J. Mater. Chem. C 2013 , 1 , 2338−2344..

Gouveia, E.; de Araujo, M.; Gouveia-Neto, A. J. B. J. o. P. Thermal effects on light emission in Yb 3+ -sensitized rare-earth doped optical glasses. Braz. J. Phys. 2001 , 31 , 89−101..

Tian, Y.; Chen,B.; Hua, R.; Yu, N.; Liu, B.; Sun, J.; Cheng, L.; Zhong, H.; Li, X.; Zhang, J.; Tian, B.; Zhong, H. Self-assembled 3D flower-shaped NaY(WO 4 ) 2 :Eu 3+ microarchitectures: microwave-assisted hydrothermal synthesis, growth mechanism and luminescent properties. CrystEngComm 2012 , 14 , 1760−1769..

Pan, Y.; Xie, X.; Huang, Q.; Gao, C.; Wang, Y.; Wang, L.; Yang, B.; Su, H.; Huang, L.; Huang, W. Inherently Eu 2+ /Eu 3+ codoped Sc 2 O 3 nanoparticles as high-performance nanothermometers. Adv. Mater. 2018 , 30 , 1705256..

Zhang, C.; Yang, H.; Zhang, Y.; Shang, Y.; Zhang, X.; Zhao, L.-D.; Gong, S. Development and application of rare earth-doped fluorescent thermometry materials. Sci. China Mater. 2025 , 68 , 1702−1716..

Pal, P. P.; Manam, J. Photoluminescence and thermoluminescence studies of Tb 3+ doped ZnO nanorods. Mater. Sci. Eng. B 2013 , 178 , 400−408..

Tcelykh, L. O.; Yu. Kozhevnikova, V.; Goloveshkin, A. S.; Latipov, E. V.; Gordeeva, E. O.; Utochnikova, V. V. Sensing temperature with Tb-Eu-based luminescent thermometer: a novel approach to increase the sensitivity. Sens. Actuat. A Phys. 2022 , 345 , 113787..

Liu, Y.; Qian, G.; Wang, Z.; Wang, M. Temperature-dependent luminescent properties of Eu-Tb complexes synthesized in situ in gel glass. Appl. Phys. Lett. 2005 , 86 , 071907..

Ivanova, A. A.; Polikovskiy, T. A.; Gontcharenko, V. E.; Korshunov, V. M.; Kiskin, M. A.; Taydakov, I. V.; Belousov, Y. A. Precision across temperatures: Eu/tb luminescent thermometer with exceptionally high and stable sensitivity from 180 to 320 k. Sens. Actuat. Phys. 2024 , 379 , 115969..

Brites, C. D. S.; Fiaczyk, K.; Ramalho, J. F. C. B.; Sójka, M.; Carlos, L. D.; Zych, E. Widening the temperature range of luminescent thermometers through the intra- and interconfigurational transitions of Pr 3+ . Adv. Opt. Mater. 2018 , 6 , 1701318..

Cao, Z.; Wei, X.; Zhao, L.; Chen, Y.; Yin, M. Investigation of SrB 4 O 7 :Sm 2+ as a multimode temperature sensor with high sensitivity. ACS Appl. Mater. Interfaces 2016 , 8 , 34546−34551..

Ferdinandus; Arai, S.; Takeoka, S.; Ishiwata, S. i.; Suzuki, M.; Sato, H. Facilely fabricated luminescent nanoparticle thermosensor for real-time microthermography in living animals. ACS Sens. 2016 , 1 , 1222−1227..

Piñol, R.; Brites, C. D. S.; Bustamante, R.; Martínez, A.; Silva, N. J. O.; Murillo, J. L.; Cases, R.; Carrey, J.; Estepa, C.; Sosa, C.; Palacio, F.; Carlos, L. D.; Millán, A. Joining time-resolved thermometry and magnetic-induced heating in a single nanoparticle unveils intriguing thermal properties. ACS Nano 2015 , 9 , 3134−3142..

Yang, D.; Liu, D.; Tian, C.; Wang, S.; Li, H. Flexible and transparent films consisting of lanthanide complexes for ratiometric luminescence thermometry. J. Colloid Interf. Sci. 2018 , 519 , 11−17..

Miyagawa, T.; Fujie, T.; Ferdinandus; Vo Doan, T. T.; Sato, H.; Takeoka, S. Glue-free stacked luminescent nanosheets enable high-resolution ratiometric temperature mapping in living small animals. ACS Appl. Mater. Interfaces 2016 , 8 , 33377−33385..

Salas-Juárez, C. J.; Navarro, R. E.; Pérez-Rodríguez, A.; Orozco-Valencia, U.; Aceves, R. Visual temperature sensor and luminescent thermometer based on the complex Tb/Eu–TPTZ incorporated in transparent PMMA film. Sens. Actuat. A Phys. 2020 , 315 , 112293..

Oyama, K.; Takabayashi, M.; Takei, Y.; Arai, S.; Takeoka, S.; Ishiwata, S. i.; Suzuki, M. Walking nanothermometers: spatiotemporal temperature measurement of transported acidic organelles in single living cells. Lab Chip 2012 , 12 , 1591−1593..

Wu, A.; Sun, P.; Sun, N.; Yu, Y.; Zheng, L. Coassembly of a polyoxometalate and a zwitterionic amphiphile into a luminescent hydrogel with excellent stimuli responsiveness. Chem. A Euro. J. 2018 , 24 , 16857−16864..

Weng, G.; Thanneeru, S.; He, J. Dynamic coordination of Eu–iminodiacetate to control fluorochromic response of polymer hydrogels to multistimuli. Adv. Mater. 2018 , 30 , 1706526..

Wang, Z.; Ananias, D.; Carné-Sánchez, A.; Brites, C. D. S.; Imaz, I.; Maspoch, D.; Rocha, J.; Carlos, L. D. Lanthanide-organic framework nanothermometers prepared by spray-drying. Adv. Funct. Mater. 2015 , 25 , 2824−2830..

Bedyal, A. K.; Ramteke, D. D.; Kumar, V.; Swart, H. C. Excitation wavelength and Eu 3+ /Tb 3+ content ratio dependent tunable photoluminescence from NaSrBO 3 :Eu 3+ /Tb 3+ phosphor. J. Mater. Sci. Mater. Electron. 2019 , 30 , 11714−11726..

Qin, X.; Liu, X.; Huang, W.; Bettinelli, M.; Liu, X. Lanthanide-activated phosphors based on 4f-5d optical transitions: Theoretical and experimental aspects. Chem. Rev. 2017 , 117 , 4488−4527..

Ma, C.-G.; Brik, M. G.; Ryba-Romanowski, W.; Swart, H. C.; Gusowski, M. A. Spectroscopy and calculations for 4f n → 4f n–1 5d transitions of lanthanide ions in K 3 YF 6 . J. Phys. Chem. A 2012 , 116 , 9158−9180..

Gayen, S. K.; Xie, B. Q.; Cheung, Y. M. Two-photon excitation of the lowest 4f 2 -4f5d near-ultraviolet transitions in Pr 3+ :Y 3 Al 5 O 12 . Phys. Rev. B 1992 , 45 , 20−28..

Zhao, M.; Zhang, Q.; Xia, Z. Structural engineering of Eu 2+ -doped silicates phosphors for led applications. Acc. Mater. Res. 2020 , 1 , 137−145..

Yan, B.; Chen, X.; Wu, J. Induced assembly and photoluminescence of lanthanum (Tb,Eu, Dy) complexes/ZnO/polyethylene glycol hybrid phosphors. Appl. Surf. Sci. 2007 , 253 , 8575−8580..

Wegh, R. T.; Meijerink, A. Spin-allowed and spin-forbidden 4f n -4f n-1 5d transitions for heavy lanthanides in fluoride hosts. Phys. Rev. B 1999 , 60 , 10820−10830..

Zhou, X.; Jiang, S.; Xiang, G.; Tang, X.; Luo, X.; Li, L.; Zhou, X. Tunable emission color of Li 2 SrSiO 4 :Tb 3+ due to cross-relaxation process and optical thermometry invest igation. J. Am. Ceram. Soc. 2018 , 101 , 3076−3085..

Li, L.; Chen, J.; He, G.; Guo, J.; Wadhwa, A.; Du, J.; Qiao, X.; Chen, D.; Guo, H. Anti-thermal-quenching radio-luminescence and high-temperature X-ray imaging of Tb 3+ -doped glass scintillators. Sci. China Mater. 2026 , 69 , 761−771..

Zhu, Y.; Meng, Q.; Sun, W.; Lü, S. NaLa(MoO 4 ) 2 : Sm 3+ , Tb 3+ phosphor: optical temperature sensing material with a wide change range of luminescence color. J. Lumin. 2020 , 218 , 116854..

Bai, H.; Chen, X.; Sha, X.; Gao, D.; Wang, L.; Zhang, X.; Cao, Y.; Wang, Y.; Zhang, J.; Li, X.; Xu, S.; Yu, H.; Chen, B. Concentration- and temperature-dependent luminescence mechanisms and fluorescence dynamic temperature sensing of NaY(MoO 4 ) 2 :Tb 3+ phosphors. Phys. B: Condens. Matter 2024 , 695 , 416480..

Li, C.-H.; Wang, C.; Keplinger, C.; Zuo, J.-L.; Jin, L.; Sun, Y.; Zheng, P.; Cao, Y.; Lissel, F.; Linder, C.; You, X.-Z.; Bao, Z. A highly stretchable autonomous self-healing elastomer. Nat. Chem. 2016 , 8 , 618−624..

Li, C.-H.; Zuo, J.-L. Self-healing polymers based on coordination bonds. Adv. Mater. 2020 , 32 , 1903762..

[Holten-Andersen, N.; Harrington, M. J.; Birkedal, H.; Lee, B. P.; Messersmith, P. B.; Lee, K. Y. C.; Waite, J. H. pH-induced metal-ligand cross-links inspired by mussel yield self-healing polymer networks with near-covalent elastic moduli. Proc. Natl. Acad. Sci. U. S. A . 2011, 108 , 2651-2655..

Manzani, D.; Petruci, J. F. d. S.; Nigoghossian, K.; Cardoso, A. A.; Ribeiro, S. J. L. A portable luminescent thermometer based on green up-conversion emission of Er 3+ /Yb 3+ co-doped tellurite glass. Sci. Rep. 2017 , 7 , 41596..

Brites, C. D. S.; Lima, P. P.; Silva, N. J. O.; Millán, A.; Amaral, V. S.; Palacio, F.; Carlos, L. D. A luminescent molecular thermometer for long-term absolute temperature measurements at the nanoscale. Adv. Mater. 2010 , 22 , 4499−4504..

Kachou, I.; Dammak, M.; Auguste, S.; Amiard, F.; Daniel, P. A novel optical temperature sensor and energy transfer properties based on Tb 3+ /Sm 3+ Codoped SrY 2 (MoO 4 ) 4 phosphors. Dalton Trans. 2023 , 52 , 18233−18246..

Wang, T.; Li, P.; Li, H. Color-tunable luminescence of organoclay-based hybrid materials showing potential applications in white led and thermosensors. ACS Appl. Mater. Interfaces 2014 , 6 , 12915−12921..

Wang, Z.; Fu, H.; Zhan, X.; Tong, B.; Ma, G.; Hintzen, H. T. Photoluminescence and ratiometric thermo-response of Eu 2+ and Eu 3+ in BaAl 2 B 2 O 7 :Eu 2+ ,Eu 3+ phosphor materials. J. Rare Earths 2024 , 42 , 1240−1249..

Liu, P.; Zhang, Y.; Li, B.; Han, L.; Xu, Y. Trap depth engineering in MgGa 2 O 4 : Bi 3+ for muticolor dynamic anti-counterfeiting, encryption and optical temperature sensing applications. Chem. Eng. J. 2022 , 437 , 135389..

Chen, J. Y.; Chen, J. Q.; Li, L. J.; Zhang, W. N.; Chen, L. P.; Guo, H. A four-mode high-sensitive optical thermometer based on Ca 3 LiZnV 3 O 12 :Sm 3+ phosphors. Mater. Today Chem. 2023 , 29 , 101409..

Xue, J.; Yu, Z.; Noh, H. M.; Lee, B. R.; Choi, B. C.; Park, S. H.; Jeong, J. H.; Du, P.; Song, M. Designing multi-mode optical thermometers via the thermochromic LaNbO 4 :Bi 3+ /Ln 3+ (Ln = Eu, Tb, Dy, Sm) phosphors. Chem. Eng. J. 2021 , 415 , 128977..

Brites, C. D. S.; Balabhadra, S.; Carlos, L. D. Lanthanide-based thermometers: at the cutting-edge of luminescence thermometry. Adv. Opt. Mater. 2019 , 7 , 1801239..

Berry, M. T.; May, P. S.; Xu, H. Temperature dependence of the Eu 3+ 5 D 0 lifetime in europium tris(2,2,6,6-tetramethyl-3,5-heptanedionato). J. Phys. Chem. 1996 , 100 , 9216−9222..

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⁰

Highly Sensitive Thermo-fluorochromic Polymeric Elastomers via Phenanthroline-mediated Dynamic Tb/Sm-Carboxylate Coordination

DOI：10.1007/s10118-026-3811-6

摘要

Abstract

关键词

Keywords

references