Ingenious Engineering of Phosphorus and Nitrogen-enriched Nickel/Iron Bimetallic Phyllosilicates: Forging Multifunctional Epoxy Composites with Excellent Toughness, Self-lubrication, Wear Resistance and Flame Retardancy

Peng Jin; Ji-Nian Yang; Wei-Long Chen; De-Han Chen; Yu-Xuan Xu; Han-Xing Yang; Bing-Yi Li; Shi-Bin Nie

doi:10.1007/s10118-026-3685-7

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Ingenious Engineering of Phosphorus and Nitrogen-enriched Nickel/Iron Bimetallic Phyllosilicates: Forging Multifunctional Epoxy Composites with Excellent Toughness, Self-lubrication, Wear Resistance and Flame Retardancy

RESEARCH ARTICLE | Updated：2026-07-27

- Ingenious Engineering of Phosphorus and Nitrogen-enriched Nickel/Iron Bimetallic Phyllosilicates: Forging Multifunctional Epoxy Composites with Excellent Toughness, Self-lubrication, Wear Resistance and Flame Retardancy
- Chinese Journal of Polymer Science Vol. 44, Issue 8, Pages: 2726-2747(2026)
- Affiliations：
  
  a.School of Materials Science and Engineering, Anhui University of Science & Technology, Huainan 232001, China
  b.School of Construction Management, Jiangsu Vocational Institute of Architectural Technology, Xuzhou 221116, China
  c.School of Public Security and Emergency Management, Anhui University of Science & Technology, Hefei 231131, China
- Author bio：
  
  jnyang@aust.edu.cn (J.N.Y.)
  nieshibin88@163.com (S.B.N.)
- Funds：
- DOI：10.1007/s10118-026-3685-7
  CLC：
- Received：06 February 2026，
  
  Accepted：26 March 2026，
  
  Online First：09 July 2026，
  
  Published：15 August 2026
- Accepted：
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Jin, P.; Yang, J. N.; Chen, W. L.; Chen, D. H.; Xu, Y. X.; Yang, H. X.; Li, B. Y.; Nie, S. B. Ingenious engineering of phosphorus and nitrogen-enriched nickel/iron bimetallic phyllosilicates: forging multifunctional epoxy composites with excellent toughness, self-lubrication, wear resistance and flame retardancy. Chinese J. Polym. Sci. 2026, 44, 2726–2747

Peng Jin, Ji-Nian Yang, Wei-Long Chen, et al. Ingenious Engineering of Phosphorus and Nitrogen-enriched Nickel/Iron Bimetallic Phyllosilicates: Forging Multifunctional Epoxy Composites with Excellent Toughness, Self-lubrication, Wear Resistance and Flame Retardancy[J]. Chinese Journal of Polymer Science, 2026, 44(8): 2726-2747.
Jin, P.; Yang, J. N.; Chen, W. L.; Chen, D. H.; Xu, Y. X.; Yang, H. X.; Li, B. Y.; Nie, S. B. Ingenious engineering of phosphorus and nitrogen-enriched nickel/iron bimetallic phyllosilicates: forging multifunctional epoxy composites with excellent toughness, self-lubrication, wear resistance and flame retardancy. Chinese J. Polym. Sci. 2026, 44, 2726–2747 DOI： 10.1007/s10118-026-3685-7.

Peng Jin, Ji-Nian Yang, Wei-Long Chen, et al. Ingenious Engineering of Phosphorus and Nitrogen-enriched Nickel/Iron Bimetallic Phyllosilicates: Forging Multifunctional Epoxy Composites with Excellent Toughness, Self-lubrication, Wear Resistance and Flame Retardancy[J]. Chinese Journal of Polymer Science, 2026, 44(8): 2726-2747. DOI： 10.1007/s10118-026-3685-7.

摘要

This work ingeniously designed and synthesized rice-like hierarchical PN-NiFePS derived from NiFe-MOF

which integrates

in situ

grown inorganic nanosheets and covalently grafted P/N-containing organic chains

significantly enhancing the comprehensive properties and providing a novel strategy for multifunctional EP composites.

Abstract

Epoxy resin (EP) is one of the most promising thermosetting resins used in engineering applications; however

its intrinsic drawbacks of poor abrasion resistance and flame retardancy limit its long-term application in harsh environments. In this study

to improve the comprehensive properties of EP

a prospective four-in-one strategy was proposed to prepare composites by rationally introducing multifunctional nanofillers. First

phosphorus- and nitrogen-enriched nickel/iron bimetallic phyllosilicates (PN-NiFePS) were facilely synthesized and subsequently incorporated into EP to prepare high-performance composites. The results indicate that PN-NiFePS nanoparticles display unique rice-grain-shaped morphologies with rough surfaces

as numerous PN-NiFePS nanosheets were vertically grown on the crystalline surface of the metal-organic framework. The chemically grafted P/N-containing pendant chains enabled well-bonded polymer-filler interfaces and homogeneous dispersion

significantly enhancing the mechanical properties. With the increase filler concentration

the wear rate exhibits a trend of initial decrease followed by subsequent increase

reaching a minimum of 1.19×10

-6

/(N·m) by adding 1% PN-NiFePS

which is 72% lower than pure EP. The incorporated PN-NiFePS endowed the composites with improved flame retardancy

leading to a steady increase in the limiting oxygen index and excellent self-extinguishing during combustion. This study provides an ingenious engineering strategy for constructing cross-function-integrated polymer composites su

itable for harsh environments.

关键词

Keywords

references

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